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The solid electrolyte interphase (SEI) is regarded as the most complex but the least understood constituent in secondary batteries using liquid and solid electrolytes. The nanostructures of SEIs were recently reported to be equally…

Samples of Y0.4Pr0.6Ba2-xSrxCu3O7 have been synthesized by a solid- state reaction route. The samples with x = 0.60 crystallize in an orthorhombic structure (with orthorhombic distortion decreasing with increasing x), while the samples with…

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

Li$_xTM$O$_2$ (TM={Ni, Co, Mn}) are promising cathodes for Li-ion batteries, whose electrochemical cycling performance is strongly governed by crystal structure and phase stability as a function of Li content at the atomistic scale. Here,…

Use of electrode materials that show phase change behavior and hence drastic changes in electrochemical activity during operation, have not been explored for Li-ion batteries. Here we demonstrate the vanadium oxide (VO2) cathode that…

This article presents a novel empirical study for the estimation of the State of Charge (SOC) of a lithium-ion (Li-ion) battery which uses a deep learning model with three hidden layers. We model a series of ten vehicle drive cycles that…

Signal Processing · Electrical Eng. & Systems 2020-11-20 Alexandre Barbosa de Lima , Maurício B. C. Salles , José Roberto Cardoso

We report the synthesis and initial characterization of Ba6Y2Rh2Ti2O17-{\delta}, a previously unreported material with a hexagonal symmetry structure. Face-sharing RhO6 octahedra form triangular planes of Rh2O9 dimers that are widely…

Strongly Correlated Electrons · Physics 2021-04-07 Loi T. Nguyen , Daniel B. Straus , Q. Zhang , R. J. Cava

EuTiO3, a band insulator, and LaTiO3, a Mott insulator, are both antiferromagnetic with transition temperatures ~ 5.5 K and ~ 160 K, respectively. Here, we report the synthesis of Eu1-xLaxTiO3 thin films with x = 0 to 1 by oxide molecular…

Strongly Correlated Electrons · Physics 2020-06-24 Hyungki Shin , Chong Liu , Fengmiao Li , Ronny Sutarto , Bruce A. Davidson , Ke Zou

Mixing heterogeneous Li-ion conductive materials is one of potential ways to enhance the Li-ion conductivity more than that of the parent materials. However, the development of the mixtures had not exhibited significant progress because it…

Materials Science · Physics 2019-12-02 Kenji Homma , Yu Liu , Masato Sumita , Ryo Tamura , Naoki Fushimi , Junichi Iwata , Koji Tsuda , Chioko Kaneta

The surface coating of cathodes using insulator films has proven to be a promising method for high-voltage cathode stabilization in Li-ion batteries. However, there is still substantial uncertainty about how these films function,…

We introduce a simple and efficient model to describe the potential energy surface of lithium diffusing in a solid-state ionic conductor. First, we assume that the Li atoms are fully ionized and we neglect the weak dependence of the…

Materials Science · Physics 2019-02-07 Leonid Kahle , Aris Marcolongo , Nicola Marzari

We study the effect of laser driving on a minimal model for a hexagonal two-dimensional material with broken inversion symmetry. Through the application of circularly polarised light and coupling to a thermal free electron bath, the system…

Strongly Correlated Electrons · Physics 2019-09-04 Oliver Hart , Garry Goldstein , Claudio Chamon , Claudio Castelnovo

The phenomenally large enhancement in conductivity observed when Li-doped MgO crystals are oxidized at elevated temperatures was investigated by dc and ac electrical measurements in the temperature interval 250-673 K. The concentration of…

Materials Science · Physics 2009-11-07 M. M. Tardio , R. Ramirez , R. Gonzalez , Y. Chen

We demonstrate that for polycrystalline LiNi0.33Mn0.33Co0.33O2 c-axis textured thin film cathodes of rechargeable lithium-ion batteries, the kinetics of Li storage and release including maximum specific capacity is determined by Li…

Materials Science · Physics 2025-09-11 Erwin Hüger , Harald Schmidt

Electrical resistivity and magnetic susceptibility measurements under high pressure were performed on an iron-based superconductor LaFePO. A steep increase in superconducting transition temperature (Tc) of LaFePO with dTc/dP > 4 K/GPa to a…

Superconductivity · Physics 2009-11-13 K. Igawa , H. Okada , K. Arii , H. Takahashi , Y. Kamihara , M. Hirano , H. Hosono , S. Nakano , T. Kikegawa

We provide a first-principles description of the crystalline and oxygen-deficient Ta2O5 using refined computational methods and models. By performing calculations on a number of candidate structures, we determined the low-temperature phase…

Materials Science · Physics 2012-11-05 Yong Yang , Ho-Hyun Nahm , Osamu Sugino , Takahisa Ohno

Blend solid polymer electrolyte based on PEO, PVP complexed with lithium LiBOB were synthesized by solution cast technique and impact of LiBOB on the morphology, structure, and electrochemical properties is examined. The XRD and FESEM…

Materials Science · Physics 2018-07-05 Anil Arya , Mohd Sadiq , A. L. Sharma

Electro-osmosis (EO) is a powerful tool to manipulate liquids in micro and nanofluidic systems. While EO has been studied extensively at liquid-solid interfaces, the case of liquid-vapor interfaces, found e.g. in foam films and bubbles,…

Soft Condensed Matter · Physics 2021-11-23 Alexia Barbosa de Lima , Laurent Joly

The two-dimensional electron gas (2DEG) found in KTaO3-based interfaces has garnered attention due to its remarkable electronic properties. In this study, we investigated the conducting system embedded at the Si3N4/Al//KTO(110)…

The Li$_2$S-P$_2$S$_5$ pseudo-binary system has been a valuable source of promising superionic conductors, with $\alpha$-Li$_3$PS$_4$, $\beta$-Li$_3$PS$_4$, HT-Li$_7$PS$_6$, and Li$_7$P$_3$S$_{11}$ having excellent room temperature Li-ion…

Materials Science · Physics 2023-07-04 Ronald L. Kam , KyuJung Jun , Luis Barroso-Luque , Julia H. Yang , Fengyu Xie , Gerbrand Ceder