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We identify two metastable excited states in Sm$ ^{10+} $ highly charged ion as candidates for high accuracy optical clocks. Several atomic properties relevant to optical clock development are calculated using relativistic many-body…

High Energy Physics - Phenomenology · Physics 2024-09-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Short coherence times present a primary obstacle in quantum computing and sensing applications. In atomic systems, clock transitions (CTs), formed from avoided crossings in an applied Zeeman field, can substantially increase coherence…

Chemical Physics · Physics 2021-11-22 Sina G. Lewis , Kori E. Smyser , Joel D. Eaves

We have performed ab initio calculations of the frequency shift induced by a static electric field on the cesium clock hyperfine transition. The calculations are used to find the frequency shifts due to blackbody radiation. Our result…

Atomic Physics · Physics 2009-11-11 E. J. Angstmann , V. A. Dzuba , V. V. Flambaum

A sharp resonance line that appears in three-photon transitions between the $^{1}S_{0}$ and $^{3}P_{0}$ states of alkaline earth and Yb atoms is proposed as an optical frequency standard. This proposal permits the use of the even isotopes,…

Optics · Physics 2007-05-23 Tao Hong , Claire Cramer , Warren Nagourney , E. N. Fortson

The response of an atom to external electric and magnetic fields can reveal fundamental atomic properties. It has long been verified that, in a static magnetic field, those atomic energy levels with hyperfine interactions shift according to…

Atomic Physics · Physics 2025-07-14 S. -Z. Wang , S. -B. Wang , Z. -J. Tao , T. Xia , Z. -T. Lu

We optically excite the electronic state $3s3p~^3P_{0}$ in $^{24}$Mg atoms, laser-cooled and trapped in a magic-wavelength lattice. An applied magnetic field enhances the coupling of the light to the otherwise strictly forbidden transition.…

Clock transitions are well known in atomic and solid-state systems, but are largely unexplored in molecular liquids. Here we demonstrate a clock-like, nuclear-spin avoided crossing in [1--$^{13}$C]-fumarate that supports long-lived and…

We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

We report a single-ion optical clock based on the 4S_1/2-3D_5/2 transition of the 40Ca+ ion, operated in a liquid nitrogen cryogenic environment,achieving a total systematic uncertainty of 4.4E-19. We employ a refined temperature evaluation…

We discuss the possibility of measuring nuclear anapole moments in atomic Zeeman transitions and perform the necessary calculations. Advantages of using Zeeman transitions include variable transition frequencies and the possibility of…

Atomic Physics · Physics 2009-11-11 E. J. Angstmann , T. H. Dinh , V. V. Flambaum

Magnetometry is an important tool prevalent in many applications such as fundamental research, material characterization and biological imaging. Atomic magnetometry conventionally makes use of two quantum states, the energy difference of…

Quantum Physics · Physics 2019-10-02 Yotam Shapira , Yehonatan Dallal , Roee Ozeri , Ady Stern

We present an assessment of the (6s^{2})1S0 -> (6s7s)3P0 clock transition frequency in 199Hg with an uncertainty reduction of nearly three orders of magnitude and demonstrate an atomic quality factor, Q, of ~10^(14). The 199Hg atoms are…

Atomic Physics · Physics 2014-12-01 J. J. McFerran , L. Yi , S. Mejri , S. Di Manno , W. Zhang , J. Guéna , Y. Le Coq , S. Bize

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

We measured the $g$-factor of the excited state $^3\text{P}_1$ in $\text{Ca}^{14+}$ ion to be $g = 1.499032(6)$ with a relative uncertainty of $4\times10^{-6}$. The magnetic field magnitude is derived from the Zeeman splitting of a…

The Zeeman effect is an important topic in atomic spectroscopy. The induced change in transition frequencies and amplitudes finds applications in the Earth-field-range magnetometry. At intermediate magnetic field amplitude $B\sim B_0 =…

Atomic Physics · Physics 2023-11-23 Armen Sargsyan , Emmanuel Klinger , Ara Tonoyan , David Sarkisyan

The quadratic Zeeman shift coefficient of 3P0 clock state for strontium is determined in theory and experiment. In theory, we derived the expression of the quadratic Zeeman shift of 3P0 clock state for 88Sr and 87Sr in the…

Atomic Physics · Physics 2022-01-11 Benquan Lu , Xiaotong Lu , Jiguang Li , Hong Chang

Clock transitions (CTs) in spin systems, which occur at avoided level crossings, enhance quantum coherence lifetimes T$_2$ because the transition becomes immune to the decohering effects of magnetic field fluctuations to first order. We…

Materials Science · Physics 2025-02-06 Brendan C. Sheehan , Guanchu Chen , Jonathan R. Friedman

We show that by averaging over transitions to multiple hyperfine levels, quadrupole shifts and dominant Zeeman effects exactly cancel whenever the nuclear spin, I, is at least as large as the total electronic angular momentum, J. The…

Quantum Physics · Physics 2014-11-04 M. D. Barrett

We demonstrate how to realize an optical clock with neutral atoms that is competitive to the currently best single ion optical clocks in accuracy and superior in stability. Using ultracold atoms in a Ca optical frequency standard we show…

Atomic Physics · Physics 2009-11-07 G. Wilpers , T. Binnewies , C. Degenhardt , U. Sterr , J. Helmcke , F. Riehle

We propose that a nuclear clock based on the Th V ion can surpass the accuracy of clocks built with other thorium ions. The Th$^{4+}$ ion has a rigid closed-shell core with zero total electron angular momentum, suppressing frequency shifts…

Atomic Physics · Physics 2025-08-05 V. A. Dzuba , V. V. Flambaum , E. Peik