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We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

The decay of correlations in ionic fluids is a classical problem in soft matter physics that underpins applications ranging from controlling colloidal self-assembly to batteries and supercapacitors. The conventional wisdom, based on…

Statistical Mechanics · Physics 2018-08-22 Fabian Coupette , Alpha A. Lee , Andreas Härtel

We study the role of charge density-wave fluctuations on the temperature dependence of Seebeck coefficient in quasi-one dimensional conductors with a Peierls instability. The description of low-dimensional incommensurate charge density-wave…

Strongly Correlated Electrons · Physics 2020-03-25 M. Mbodji , C. Bourbonnais

A number of basic scientific questions relating to ion conduction in homogeneously disordered solids are discussed. The questions deal with how to define the mobile ion density, what can be learned from electrode effects, what is the ion…

Disordered Systems and Neural Networks · Physics 2009-11-13 Jeppe C. Dyre , Philipp Maass , Bernhard Roling , David L. Sidebottom

An alternative derivation of Brownian motion is presented. Instead of supplementing the linearized Navier-Stokes equation with a fluctuating force, we directly assume a Gaussian action functional for solvent velocity fluctuations. Solvating…

Statistical Mechanics · Physics 2013-07-24 Thomas Speck

We investigated the pressure dependence of gas flow and field ion intensity of a coaxial ion source operating at room temperature over a wide pressure range, testing various gases and ionisation voltages. Flow conductance measurements…

The ion-induced long-range orientational order between water molecules recently observed in second harmonic scattering experiments and illustrated with large scale molecular dynamics simulations is quantitatively explained using the…

Chemical Physics · Physics 2018-03-29 Luc Belloni , Daniel Borgis , Maximilien Levesque

Studies about the constructive aspects of noise and fluctuations in different non-linear systems have shown that the addition of external noise to systems with an intrinsic noise may result in a less noisy response. Recently, the…

Materials Science · Physics 2009-11-13 D. Persano Adorno , N. Pizzolato , B. Spagnolo

The transient behaviour of organic electrochemical transistors (OECT) is complex due to mixed ionic-electronic properties that play a central role in bioelectronics, sensing and neuromorphic applications. We investigate the impedance…

Materials Science · Physics 2024-08-06 Juan Bisquert , Scott T. Keene

We have analyzed data on the free ion yield observed in liquid isooctane irradiated by Co60 gamma rays within the framework of the Onsager theory about initial recombination. Several distribution functions describing the electron…

Instrumentation and Detectors · Physics 2007-05-23 J. Pardo , F. Gomez , A. Iglesias , R. Lobato , J. Mosquera , A. Pazos , J. Pena , M. Pombar , A. Rodriguez , J. Sendon

I review recent measurements of a large set of flow observables associated with event-shape fluctuations and collective expansion in heavy ion collisions. First, these flow observables are classified and experiment methods are introduced.…

Nuclear Experiment · Physics 2015-06-22 Jiangyong Jia

We consider entropy generating flows for fluids that achieve a steady state in the presence of a driving electric field. Having chosen one among the space of stationarity constraints that define such flows we show how energy and momentum…

Statistical Mechanics · Physics 2025-01-24 Andrea Amoretti , Daniel K. Brattan , Luca Martinoia , Jonas Rongen

We develop the theory of hydrodynamic electron transport in a long-range disorder potential for conductors in which the underlying electron liquid lacks Galilean invariance. For weak disorder, we express the transport coefficients of the…

Mesoscale and Nanoscale Physics · Physics 2020-08-19 Songci Li , Alex Levchenko , A. V. Andreev

We present a stochastic approach for charge transport in transistors. In this approach, the electron and hole densities are governed by diffusion-reaction stochastic differential equations satisfying local detailed balance and the electric…

Statistical Mechanics · Physics 2021-02-08 Jiayin Gu , Pierre Gaspard

We formulate the non-linear field theory for a fluctuating counter-ion distribution in the presence of a fixed, arbitrary charge distribution. The Poisson-Boltzmann equation is obtained as the saddle-point, and the effects of fluctuations…

Soft Condensed Matter · Physics 2015-06-25 Roland R. Netz , Henri Orland

We study the fluctuations of a stochastic Maxwell-Lorentz particle model driven by an external field to determine the extent to which fluctuation relations are related to large deviations. Focusing on the total entropy production of this…

Statistical Mechanics · Physics 2013-08-02 Giacomo Gradenigo , Alessandro Sarracino , Andrea Puglisi , Hugo Touchette

The correlated motion of electrons in a one dimensional system with an externally applied longitudinal electric field is discussed. Within the tight binding model we show that in addition to the well known Bloch oscillations the…

Condensed Matter · Physics 2009-11-10 F. Claro , J. F. Weisz , S. Curilef

The increasing number of experimental observations on highly concentrated electrolytes and ionic liquids show qualitative features that are distinct from dilute or moderately concentrated electrolytes, such as self-assembly, multiple-time…

Chemical Physics · Physics 2018-02-08 Nir Gavish , Doron Elad , Arik Yochelis

We study the linear response in different models of driven granular gases. In some situations, even if the the velocity statistics can be strongly non-Gaussian, we do not observe appreciable violations of the Einstein formula for diffusion…

Statistical Mechanics · Physics 2009-11-13 A. Puglisi , A. Baldassarri , A. Vulpiani

{\em Voyager 1} and {\em 2} data reveals that magnetic field fluctuations are compressive and exhibit a Gaussian distribution in the compressed heliosheath plasma, whereas they follow a lognormal distribution in a nearly incompressible…

Space Physics · Physics 2015-05-18 Dastgeer Shaikh
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