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Anisotropy at the level of the inter-particle interaction provides the particles with specific instructions for the self-assembly of target structures. The ability to synthesize non-spherical colloids, together with the possibility of…

Soft Condensed Matter · Physics 2020-01-03 Carina Karner , Christoph Dellago , Emanuela Bianchi

We explore the behavior of two-dimensional patchy colloidal particles with 8 or 10 symmetrically arranged patches by employing Monte-Carlo simulations. The particles interact according to an isotropic pair potential that possesses only one…

Soft Condensed Matter · Physics 2019-06-04 Anja Gemeinhardt , Miriam Martinsons , Michael Schmiedeberg

In the realm of functional materials, the production of two-dimensional structures with tuneable porosity is of paramount relevance for many practical applications: surfaces with regular arrays of pores can be used for selective adsorption…

Soft Condensed Matter · Physics 2019-10-23 Carina Karner , Emanuela Bianchi , Christoph Dellago

Inverse patchy colloids are nano- to micro-scale particles with a surface divided into differently charged regions. This class of colloids combines directional, selective bonding with a relatively simple particle design: owing to the…

Soft Condensed Matter · Physics 2021-01-22 Emanuela Bianchi , Peter D. J. van Oostrum , Christos N. Likos , Gerhard Kahl

In recent years, experimental and theoretical investigations have shown that anisotropic colloids can self-organise into ordered porous monolayers, where the interplay of localised bonding sites, so called patches, with the particle's shape…

Soft Condensed Matter · Physics 2024-05-03 Carina Karner , Emanuela Bianchi

Patchy colloids with highly directional interactions are ideal building blocks to control the local arrangements resulting from their spontaneous self-organization. Here we propose their use, combined with substrates and nonequilibrium…

Soft Condensed Matter · Physics 2013-03-21 C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

In this work we characterize the configurational space of a short chain of colloidal particles as function of the range of directional and heterogeneous isotropic interactions. The individual particles forming the chain are colloids…

Soft Condensed Matter · Physics 2015-06-05 Ivan Coluzza , Christoph Dellago

Spherical particles confined to a sphere surface cannot pack densely into a hexagonal lattice without defects. In this study, we use hard particle Monte Carlo simulations to determine the effects of continuously deformable shape anisotropy…

Soft Condensed Matter · Physics 2026-01-01 Gabrielle N. Jones , Philipp W. A. Schönhöfer , Sharon C. Glotzer

Nanoparticles with "sticky patches" have long been proposed as building blocks for the self-assembly of complex structures. The synthetic realizability of such patchy particles, however, greatly lags behind predictions of patterns they…

Soft Condensed Matter · Physics 2013-10-03 Michael Grünwald , Phillip L. Geissler

The rapid progress in precisely designing the surface decoration of patchy colloidal particles offers a new, yet unexperienced freedom to create building entities for larger, more complex structures in soft matter systems. However, it is…

Soft Condensed Matter · Physics 2012-06-14 G. Doppelbauer , E. G. Noya , E. Bianchi , G. Kahl

Patchy particles are a popular paradigm for the design and synthesis of nanoparticles and colloids for self-assembly. In "traditional" patchy particles, anisotropic interactions arising from patterned coatings, functionalized molecules,…

Soft Condensed Matter · Physics 2014-02-18 Greg van Anders , N. Khalid Ahmed , Ross Smith , Michael Engel , Sharon C. Glotzer

Patchy particles are considered to be a good model for protein aggregation. We calculate the equilibrium phase diagram of two-patch colloidal particles undergoing aggregation along with isotropic potential. This investigation demonstrates…

Soft Condensed Matter · Physics 2020-06-24 Isha Malhotra , Sujin B. Babu

Patchy colloids are promising candidates for building blocks in directed self-assembly. To be successful the surface patterns need to both be simple enough to be synthesized, while feature-rich enough to cause the colloids to self-assemble…

Soft Condensed Matter · Physics 2014-05-13 Erik Edlund , Oskar Lindgren , Martin Nilsson Jacobi

We study the structural and thermodynamic properties of patchy particle liquids, with a special focus on the role of "color", i.e. specific interactions between individual patches. A possible experimental realization of such "chromatic"…

Soft Condensed Matter · Physics 2015-07-22 Oleg A. Vasilyev , Boris A. Klumov , Alexei V. Tkachenko

Herein, we describe new methods to produce colloidal particle chains of three stiffness regimes that can be observed on a single-particle level, that is, on the level of the monomers that make up the chain; the chains can even be observed…

The assembly of colloids in nematic liquid crystals via topological defects has been extensively studied for spherical particles, and investigations of other colloid shapes have revealed a wide array of new assembly behaviors. We show,…

Soft Condensed Matter · Physics 2014-12-16 Daniel A. Beller , Mohamed A. Gharbi , Iris B. Liu

We report on the self-assembly of inverse patchy colloids (IPC) using Monte Carlo simulations in two-dimensions. The IPC model considered in this work corresponds to either bipolar colloids or colloids decorated with complementary DNA on…

Soft Condensed Matter · Physics 2017-05-16 Remya Ann Mathews K , Ethayaraja Mani

We study the behavior of negatively charged colloids with two positively charged polar caps close to a planar patterned surface. The competition between the different anisotropic components of the particle-particle interaction patterns is…

Soft Condensed Matter · Physics 2018-09-25 Emanuele Locatelli , Emanuela Bianchi

Patchy particles are a class of colloids with functionalized surfaces. Through surface functionalization, the strength and directionality of the colloidal interactions are tunable allowing control over coordination of the particle.…

Soft Condensed Matter · Physics 2013-10-21 Cristóvão Dias , Nuno Araújo , Margarida Telo da Gama

We study the ordered equilibrium structures of patchy particles where the patches are located on the surface of the colloid such that they form a regular tetrahedron. Using optimization techniques based on ideas of evolutionary algorithms…

Soft Condensed Matter · Physics 2015-06-05 G. Doppelbauer , E. G. Noya , E. Bianchi , G. Kahl
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