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It is generally accepted that the hydrophilic property of graphene can be affected by the underlying substrate. However, the role of intrinsic vs. substrate contributions and the related mechanisms are vividly debated. Here we show that the…

Transmission electron microscopy (TEM) and scanning TEM (STEM) are indispensable tools for materials characterization. However, during a typical (S)TEM experiment, the sample is subject to a number of effects that can change its atomic…

Materials Science · Physics 2020-12-08 Gregor T. Leuthner , Toma Susi , Clemens Mangler , Jannik C. Meyer , Jani Kotakoski

Although iron-based single atom catalysts are regarded as a promising alternative to precious metal catalysts, their precise electronic structures during catalysis still pose challenges for computational descriptions. A particularly urgent…

Materials Science · Physics 2024-11-07 Young-Joon Song , Charlotte Gallenkamp , Genís Lleopart , Vera Krewald , Roser Valentí

Graphene is one of the most important materials in science today due to its unique and remarkable electronic, thermal and mechanical properties. However in its pristine state, graphene is a gapless semiconductor, what limits its use in…

Materials Science · Physics 2014-08-13 P. A. S. Autreto , J. M. de Sousa , D. S. Galvao

We report on a scanning confocal Raman spectroscopy study investigating the strain-uniformity and the overall strain and doping of high-quality chemical vapour deposited (CVD) graphene-based heterostuctures on a large number of different…

A significant advance toward achieving practical applications of graphene as a two-dimensional material in nanoelectronics would be provided by successful synthesis of both n-type and p-type doped graphene. However reliable doping and a…

Mesoscale and Nanoscale Physics · Physics 2013-10-24 Yu-Fen Lu , Shun-Tsung Lo , Jheng-Cyuan Lin , Wenjing Zhang , Jing-Yu Lu , Fan-Hung Liu , Chuan-Ming Tseng , Yi-Hsien Lee , Chi-Te Liang , Lain-Jong Li

Flat bands form in a 3D Hopf-linked graphene crystal or a 3D carbon allotrope named Hopfene, which qualitatively differ from bands of only graphenes. This paper discusses carbon-hexagon deformation on the level shift of a flat band via…

Materials Science · Physics 2020-01-29 Isao Tomita , Shinichi Saito

We demonstrate the growth of graphene nanocrystals by molecular beam methods that employ a solid carbon source, and that can be used on a diverse class of large area dielectric substrates. Characterization by Raman and Near Edge X-ray…

Strain induced band gap deformations of hydrogenated/fluorinated graphene and hexagonal BN sheet have been investigated using first principles density functional calculations. Within harmonic approximation, the deformation is found to be…

Materials Science · Physics 2015-05-27 A. Bhattacharya , S. Bhattacharya , G. P. Das

A new formula for elastic bending modulus of monolayer graphene is derived analytically from an empirical potential for solid-state carbon-carbon bonds. Two physical origins are identified for the non-vanishing bending modulus of the…

Materials Science · Physics 2015-05-13 Qiang Lu , Marino Arroyo , Rui Huang

Molecular dynamics (MD) simulations were performed to study the formation process of nanopores in a suspended graphene sheet irradiated by using energetic ions though a mask. By controlling the ion parameters including mass, energy and…

Mesoscale and Nanoscale Physics · Physics 2016-03-10 Weisen Li , Li Liang , Shijun Zhao , Shuo zhang , Jianming Xue

We study the stability and evolution of various elastic defects in a flat graphene sheet and the electronic properties of the most stable configurations. Two types of dislocations are found to be stable: "glide" dislocations consisting of…

Mesoscale and Nanoscale Physics · Physics 2008-06-19 Ana Carpio , Luis L. Bonilla , Fernando de Juan , María A. H. Vozmediano

The ability of atomic hydrogen to chemisorb on graphene makes the latter a promising material for hydrogen storage. Based on scanning tunneling microscopy techniques, we report on site-selective adsorption of atomic hydrogen on convexly…

We find that the Casimir pressure in peptide films deposited on metallic substrates is always repulsive which makes these films less stable. It is shown that by adding a graphene sheet on top of peptide film one can change the sign of the…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 G. L. Klimchitskaya , V. M. Mostepanenko , V. N. Velichko

The electronic structure of graphene on Cu(111) and Cu(100) single crystals is investigated using low energy electron microscopy, low energy electron diffraction and angle resolved photoemission spectroscopy. On both substrates the graphene…

We show that by using an original method, bulk graphite can be bonded onto borosilicate glass or potentially any insulating substrate with ionic conductivity and then cleaved off to leave single or few layer graphene on the substrate,…

Materials Science · Physics 2009-04-06 Abhay Shukla , Rakesh Kumar , Javed Mazher , Adrian Balan

Two-dimensional atomic crystals can radically change their properties in response to external influences such as substrate orientation or strain, resulting in essentially new materials in terms of the electronic structure. A striking…

The thermodynamics of solid/liquid interfaces under nanoconfinement has tremendous implications for liquid transport properties. Here using molecular dynamics, we investigate graphite nanoslits and study how the water/graphite interfacial…

Fluid Dynamics · Physics 2022-05-17 Zixuan Wei , Mara Chiricotto , Joshua D. Elliott , Fausto Martelli , Paola Carbone

This review on graphene, a one atom thick, two-dimensional sheet of carbon atoms, starts with a general description of the graphene electronic structure as well as a basic experimental toolkit for identifying and handling this material.…

Materials Science · Physics 2010-11-22 Caterina Soldano , Ather Mahmood , Erik Dujardin

We present a comprehensive study of graphene grown by chemical vapor deposition on copper single crystals with exposed (100), (110) and (111) faces. Direct examination of the as-grown graphene by Raman spectroscopy using a range of visible…

Mesoscale and Nanoscale Physics · Physics 2014-02-03 Otakar Frank , Jana Vejpravova , Vaclav Holy , Ladislav Kavan , Martin Kalbac