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We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer…

Statistical Mechanics · Physics 2015-06-16 David T Limmer , David Chandler

The application of amorphous chalcogenide alloys as data-storage media relies on their ability to undergo an extremely fast (10-100 ns) crystallisation once heated at sufficiently high temperature. However, the peculiar features that make…

Disordered Systems and Neural Networks · Physics 2015-06-05 Gabriele C. Sosso , Joerg Behler , Marco Bernasconi

Liquid water has anomalous liquid properties, such as its density maximum at 4\degree C. An attempt at theoretical explanation proposes a liquid-liquid phase transition line in the supercooled liquid state, with coexisting low-density (LDL)…

Soft Condensed Matter · Physics 2019-09-04 Peter Mausbach , Helge-Otmar May , George Ruppeiner

We examine ice crystal growth from water vapor at temperatures near the melting point, when surface premelting creates a quasiliquid layer at the solid/vapor interface. Recent ice growth measurements as a function of vapor supersaturation…

Materials Science · Physics 2014-07-04 Kenneth G. Libbrecht

A basic and inherently simple connection is shown to exist between superconductivity and superfluidity. It is shown here that the author's previously derived general equation which agrees well with the superconducting transition…

Superconductivity · Physics 2015-06-24 Mario Rabinowitz

A number of crystal structures of water have been `superheated' in Monte Carlo simulations. Two well known models for water were considered; namely the TIP4P model and the SPC/E model. By comparing the fluid-solid coexistence temperature to…

Statistical Mechanics · Physics 2009-02-24 Carl McBride , Carlos Vega , Eduardo Sanz , Luis G. MacDowell , Jose L. F. Abascal

By means of Monte Carlo simulations, using finite size scaling and conformal transformations, evidences of a topological phase transition in liquid crystals in two dimensions are reported. A paramagnetic phase appears at high temperature…

Other Condensed Matter · Physics 2010-07-13 V. Ricardo Paredes , Ana I. Fariñas-Sánchez , Bertrand Berche

The earlier paper of this same title demonstrated a collapse of relaxation data of fragile supercooled glass forming liquids [\textit{J. Phys. Chem. B} \textbf{113}, 5563-5567 (2009)]. For temperature $T$ below that of the onset to…

Statistical Mechanics · Physics 2014-07-31 Yael S. Elmatad , David Chandler , Juan P. Garrahan

We study a system of heteronuclear molecules on a triangular lattice and analyze the potential of this system for the experimental realization of a supersolid phase. The ground state phase diagram contains superfluid, solid and supersolid…

Statistical Mechanics · Physics 2015-05-13 L. Pollet , J. D. Picon , H. P. Buechler , M. Troyer

Phase transformations such as freezing typically start with heterogeneous nucleation. Heterogeneous nucleation near a wetting transition, of a crystalline phase is studied. The wetting transition occurs at or near a vapour-liquid transition…

Statistical Mechanics · Physics 2009-11-07 Richard P. Sear

Nucleation phenomena commonly observed in our every day life are of fundamental, technological and societal importance in many areas, but some of their most intimate mechanisms remain however to be unraveled. Crystal nucleation, the early…

Materials Science · Physics 2022-02-09 Sébastien Becker , Emilie Devijver , Rémi Molinier , Noël Jakse

In this paper we present a review on our recent experimental investigations into the phase behavior of the deeply cooled water confined in a nanoporous silica material, MCM-41, with elastic neutron scattering technique. Under such strong…

Soft Condensed Matter · Physics 2016-12-13 Zhe Wang , Kanae Ito , Sow-Hsin Chen

We present a theory of vortex liquid-to-solid transition in homogeneous quasi 2D superconductors. The free energy is written as a functional l of density of zeroes of the fluctuating order parameter. The transition is weakly first-order and…

Condensed Matter · Physics 2009-10-22 Igor Herbut , Zlatko Tesanovic

We make a first principle calculation of the fragility index $m$ of a simple liquid using the structure of the supercooled liquid as an input. Using the density functional theory (DFT) of classical liquids, the configurational entropy…

Statistical Mechanics · Physics 2016-10-12 Leishangthem Premkumar , Shankar P. Das

A large number of water models exists for molecular simulations. They differ in the ability to reproduce specific features of real water instead of others, like the correct temperature for the density maximum or the diffusion coefficient.…

Soft Condensed Matter · Physics 2012-06-04 Roman Shevchuk , Diego Prada-Gracia , Francesco Rao

Hydrogen bond patterns, proton ordering, and phase transitions of monolayer ice in two-dimensional hydrophobic confinement are fundamentally different from those found for bulk ice. To investigate the behavior of quasi-2D ice, we perform…

Chemical Physics · Physics 2019-01-15 Shujuan Li , Burkhard Schmidt

A simplified nonlinear memory function is proposed in the ideal time-convolutionless mode-coupling theory equation to study the dynamics of glass-forming liquids. The numerical solutions are then compared with the simulation results…

Statistical Mechanics · Physics 2020-01-22 Michio Tokuyama

Dynamical heterogeneity, in which transitory local fluctuations occur in the conformation and dynamics of constituent particles, is widely hypothesized to be essential to evolution of supercooled liquids into the structural glass state. Yet…

It is proposed that the rapid observed homogeneous nucleation of ice dust in a cold, weakly-ionized plasma depends on the formation of hydroxide (OH$^-$) by fast electrons impacting water molecules. These OH$^{-}$ ions attract neutral water…

Plasma Physics · Physics 2022-08-31 Paul M. Bellan

We calculate local potential energy minima (inherent structures) for a simple model of orthoterphenyl (OTP), from computer simulations over a wide temperature range. We show that the results are very sensitive to the system size. We locate,…

Soft Condensed Matter · Physics 2009-09-25 Francesco Sciortino , Srikanth Sastry , Piero Tartaglia
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