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For a given many-electron molecule, it is possible to define a corresponding one-electron Schr\"odinger equation, using potentials derived from simple atomic densities, whose solution predicts fairly accurate molecular orbitals for single-…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

Using classical statistics, Schrodinger equation in quantum mechanics is derived from complex space model. Phase-space probability amplitude, that can be defined on classical point of view, has connections to probability amplitude in…

Quantum Physics · Physics 2007-05-23 Kiyoung Kim

A quantum-mechanical wave function is complex, but all observations are real, expressible through expectation values and transition matrix elements that involve the wave functions. It can be useful to separate at the outset the amplitude…

Quantum Physics · Physics 2025-07-01 A. R. P. Rau

A numerical method of solving the one-dimensional Schrodinger equation for the regular and irregular continuum states using the phase-amplitude representation is presented. Our solution acquires the correct Dirac-delta normalization by…

Quantum Physics · Physics 2025-01-22 Daniel Hadush , Charles Weatherford

A new method of calculation of amplitudes of different processes in quantum electrodynamics is proposed. The method does not use the Feynman technique of trace of product of matrices calculation. The method strongly simplifies calculation…

High Energy Physics - Phenomenology · Physics 2015-06-05 Kostyantyn Karplyuk , Oleksandr Zhmudsky

Describing the Coulomb interactions between electrons in atomic or molecular systems is an important step to help us obtain accurate results for the different observables in the system. One convenient approach is to separate the dynamic…

Chemical Physics · Physics 2025-01-22 Claude Le Sech , Antonio Sarsa

The Schr\"odinger-like equations for the marginal and conditional probability amplitudes resulting from the exact factorization of the wavefunction of a two-component system are derived in a form that is invariant to gauge and coordinate…

Quantum Physics · Physics 2022-07-06 Ryan Requist

For a given many-electron molecule, it is possible to define a corresponding one-electron Schr\"odinger equation, using potentials derived from simple atomic densities, whose solution predicts fairly accurate molecular orbitals for single-…

Chemical Physics · Physics 2022-05-16 Fariba Nazari , Jerry L. Whitten

This paper derives and demonstrates a new, purely density-based ab initio approach for calculation of the energies and properties of many-electron systems. It is based upon the discovery of relationships that govern the "mechanics" of the…

Chemical Physics · Physics 2024-09-04 James C. Ellenbogen

The functional integral method can be used in quantum mechanics to find the scattering amplitude for particles in the external field. We will obtain the potential scattering amplitude form the complete Green function in the corresponding…

Quantum Physics · Physics 2021-04-07 Cao Thi Vi Ba , Do Thu Ha , Nguyen Nhu Xuan

By splitting the Coulomb interaction into long-range and short-range components, we decompose the energy of a quantum electronic system into long-range and short-range contributions. We show that the long-range part of the energy can be…

Chemical Physics · Physics 2009-11-10 Julien Toulouse , Francois Colonna , Andreas Savin

In this work we give a comprehensive derivation of an exact and numerically feasible method to perform ab-initio calculations of quantum particles interacting with a quantized electromagnetic field. We present a hierachy of…

The dimension of the Hilbert space needed for the description of an interacting electron system increases exponentially with electron number $N$. As pointed out by W. Kohn this exponential wall problem (EWP) limits the concept of…

Strongly Correlated Electrons · Physics 2023-12-12 Peter Fulde

We derive a new integral equation that allows the calculation of the scattering or annihilation amplitude of two particles subjected to two potentials when the corresponding amplitude for one potential only is known. We assume that…

High Energy Physics - Phenomenology · Physics 2010-07-20 Luca Visinelli , Paolo Gondolo

A new algorithm to calculate Coulomb wave functions with all of its arguments complex is proposed. For that purpose, standard methods such as continued fractions and power/asymptotic series are combined with direct integrations of the…

Computational Physics · Physics 2009-11-13 N. Michel

Maxwell's equations in the vacuum can be formally cast in the form of Schr\"odinger's equation. Unfortunately, the vector to which this equation directly applies is not a wavefunction: its amplitude squared is not a probability density but…

Quantum Physics · Physics 2025-07-30 Stéphane Virally

Whenever the Breit-Wigner amplitude appears in a calculation,there are many instances (e.g., Fermi's two-level system and the Weisskopf-Wigner approximation) where energy integrations are extended from the scattering spectrum of the…

Quantum Physics · Physics 2010-11-09 R. de la Madrid

It is shown that the Schrodinger equation for a large family of pairs of two-dimensional quantum potentials possess wavefuctions for which the amplitude and the phase are interchangeable, producing two different solutions which are dual to…

Quantum Physics · Physics 2021-02-03 Sergio A. Hojman , Felipe A. Asenjo

Schr\"odinger equation for two center Coulomb plus harmonic oscillator potential is solved by the method of ethalon equation at large intercenter separations. Asymptotical expansions for energy term and wave function are obtained in the…

Quantum Physics · Physics 2009-10-31 D. Matrasulov

A separable $x-y$ model is solved for a specialized vector potential (no magnetic and weak electric fields) penetrating slowly\textbf{,} adiabatically into and across a rectangular box to which an electron is confined. The time-dependent…

Quantum Physics · Physics 2015-05-27 Robert Englman , Asher Yahalom
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