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Related papers: Dissociative recombination of cold HeH$^+$ ions

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The LiH$^{+}$ molecule is prototypical of the indirect dissociative recombination (DR) process, in which a colliding electron destroys the molecule through Rydberg capture pathways. This Letter develops the first quantitative test of the…

Chemical Physics · Physics 2016-08-17 R. Čurík , Chris H. Greene

Theoretical investigation of the dissociative recombination (DR) of NeH+ with low-energy electrons in the regime where the process occurs without direct potential energy curve crossings is presented. The calculations are performed using…

Atomic and Molecular Clusters · Physics 2025-09-09 Riyad Hassaine , Janos Zsolt Mezei , Dahbia Talbi , Jonathan Tennyson , Ioan F. Schneider

We have experimentally studied dissociative recombination (DR) of electronically and vibrationally relaxed ArH$^+$ in its lowest rotational levels, using an electron--ion merged-beams setup at the Cryogenic Storage Ring. We report…

The theoretical approach developed here treats uniformly the direct and indirect mechanisms of dissociative recombination (DR) in a diatomic ion. The present theory is based on electron scattering calculations performed at several…

This work presents our theoretical study of the dissociative recombination (DR) of the closed-shell diatomic system CF$^+$ based on an approach recently applied to the CH$^+$ molecule. Our extended treatment uses the UK R-matrix theory and…

Dissociative recombination of N$_2$H$^+$ is explored in a two-step theoretical study. In a first step, a diatomic (1D) rough model with frozen NN bond and frozen angles is adopted, in the framework of the multichannel quantum defect theory…

Instrumentation and Methods for Astrophysics · Physics 2023-08-16 J. Zs Mezei , M. A. Ayouz , A. Orbán , A. Abdoulanziz , D. Talbi , D. O. Kashinski , E. Bron , V. Kokoouline , I. F. Schneider

The HeH$^+$ cation undergoes dissociative recombination with a free electron to produce neutral He and H fragments. We present calculations using ab initio quantum defects and Fano's rovibrational frame transformation technique, along with…

Chemical Physics · Physics 2009-11-13 Daniel J. Haxton , Chris H. Greene

Cross sections are presented for dissociative recombination and electron-impact vibrational excitation of the ArH+ molecular ion at electron energies appropriate for the interstellar environment. The R-matrix method is employed to determine…

Astrophysics of Galaxies · Physics 2018-08-21 A. Abdoulanziz , F. Colboc , D. A. Little , Y. Moulane , J. Zs. Mezei , E. Roueff , J. Tennyson , I. F. Schneider , V. Laporta

Inelastic low-energy (0--1 eV) collisions of electrons with HeH$^+$ cations are treated theoretically, with a focus on the rovibrational excitation and dissociative recombination (DR) channels. In an application of {\it ab initio}…

Chemical Physics · Physics 2017-10-30 Roman Čurík , Chris H. Greene

We present a simple two-dimensional model of the indirect dissociative recombination process. The model has one electronic and one nuclear degree of freedom and it can be solved to high precision, without making any physically motivated…

We present the results of calculations determining the cross sections for indirect dissociative recombination of LiH$_2^+$ + $e^-$. These calculations employ multichannel quantum defect theory and Fano's rovibrational frame transformation…

Chemical Physics · Physics 2009-11-13 Daniel J. Haxton , Chris H. Greene

Cross sections and rate coefficients for the Dissociative Recombination (DR) of the NS+ ion induced by collisions with low-energy electrons are reported for temperatures between 10 and 1000 K, relevant to a large range of interstellar cloud…

Instrumentation and Methods for Astrophysics · Physics 2024-03-08 R. Hassaine , F. Gauchet , F. Iacob , J. Zs Mezei , E. Roueff , J. Tennyson , I. F. Schneider

This paper reports results from an experimental investigation of the dissociative recombination (DR) of the helium dimer ions at the heavy-ion Test Storage Ring (TSR) in Heidelberg, observing neutral products from electron-ion collisions in…

We used the multichannel quantum defect theory to compute cross sections and rate coefficients for the dissociative recombination of CH$^+$ initially in its lowest vibrational level $v_i^+ = 0$ with electrons of incident energy bellow $0.2$…

Instrumentation and Methods for Astrophysics · Physics 2022-03-08 J. Zs. Mezei , M. D. Epée Epée , O. Motapon , I. F. Schneider

The reactive collisions of the CH$^+$ molecular ion with electrons is studied in the framework of the multichannel quantum defect theory, taking into account the contribution of the core-excited Rydberg states. In addition to the…

Instrumentation and Methods for Astrophysics · Physics 2024-05-01 K. Chakrabarti , J. Zs Mezei , O. Motapon , A. Faure , O. Dulieu , K. Hassouni , I. F. Schneider

A quantitative theoretical study of the dissociative recombination of SH$^+$ with electrons has been carried out. Multireference, configuration interaction calculations were used to determine accurate potential energy curves for SH$^+$ and…

Instrumentation and Methods for Astrophysics · Physics 2024-05-31 D. O. Kashinski , D. Talbi , A. P. Hickman , O. E. Di Nallo , F. Colboc , K. Chakrabarti , I. F. Schneider , J. Zs Mezei

Direct dissociative recombination and resonant ion-pair formation reactions of $\mathrm{HeH^+}$ are theoretically studied using time-dependant wave-packets methods. The wave packets are propagated on potential energy curves that are in…

Chemical Physics · Physics 2023-01-11 Sifiso M. Nkambule , Malibongwe Tsabedze , Oscar N. Mabuza , Mbuso K. Matfunjwa

An alternative method is introduced to solve a simple two-dimensional models describing vibrational excitation and dissociation processes during the electron-molecule collisions. The model works with one electronic and one nuclear degree of…

Chemical Physics · Physics 2018-12-19 Roman Čurík , Dávid Hvizdoš , Chris H. Greene

We have investigated dissociative recombination (DR) of NH$^+$ with electrons using a merged beams configuration at the TSR heavy-ion storage ring located at the Max Planck Institute for Nuclear Physics in Heidelberg, Germany. We present…

Instrumentation and Methods for Astrophysics · Physics 2014-08-28 O. Novotný , M. Berg , D. Bing , H. Buhr , W. Geppert , M. Grieser , F. Grussie , C. Krantz , M. B. Mendes , C. Nordhorn , R. Repnow , D. Schwalm , B. Yang , A. Wolf , D. W. Savin

Observations of OH$^+$ are used to infer the interstellar cosmic ray ionization rate in diffuse atomic clouds, thereby constraining the propagation of cosmic rays through and the shielding by interstellar clouds, as well as the low energy…

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