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We study both the classical and quantum rotational dynamics of an asymmetric top molecule, controlled through three orthogonal electric fields that interact with its dipole moment. The main difficulties in studying the controllability of…

Mathematical Physics · Physics 2021-10-01 Eugenio Pozzoli

The goal of quantum tracking control is to identify shaped fields to steer observable expectation values along designated time-dependent tracks. The fields are determined via an iteration-free procedure, which is based on inverting the…

Quantum Physics · Physics 2024-02-06 Alicia B. Magann , Tak-San Ho , Christian Arenz , Herschel A. Rabitz

The angular momentum of molecules, or, equivalently, their rotation in three-dimensional space, is ideally suited for quantum control. Molecular angular momentum is naturally quantized, time evolution is governed by a well-known Hamiltonian…

Quantum Physics · Physics 2019-10-23 Christiane P. Koch , Mikhail Lemeshko , Dominique Sugny

Optimal control of molecular dynamics is commonly expressed from a quantum mechanical perspective. However, in most contexts the preponderance of molecular dynamics studies utilize classical mechanical models. This paper treats laser-driven…

Chemical Physics · Physics 2015-03-19 Carlee Joe-Wong , Tak-San Ho , Ruixing Long , Herschel Rabitz , Rebing Wu

We study the classical and quantum rotation numbers of the free rotation of asymmetric top molecules. We show numerically that the quantum rotation number converges to its classical analog in the semi-classical limit. Different asymmetric…

Quantum Physics · Physics 2018-04-04 K. Hamraoui , L. Van Damme , P. Mardesic , D. Sugny

We show the approximate rotational controllability of a polar linear molecule by means of three nonresonant linear polarized laser fields. The result is based on a general approximate controllability result for the bilinear Schr\"odinger…

Optimization and Control · Mathematics 2013-02-14 Ugo Boscain , Marco Caponigro , Mario Sigalotti

We present a sufficient condition for approximate controllability of the bilinear discrete-spectrum Schr\"odinger equation exploiting the use of several controls. The controllability result extends to simultaneous controllability,…

Optimization and Control · Mathematics 2013-02-19 Ugo Boscain , Marco Caponigro , Mario Sigalotti

We consider the Schr\"odinger partial differential equation of a rotating symmetric rigid molecule (symmetric rotor) driven by a z-linearly polarized electric field, as prototype of degenerate infinite-dimensional bilinear control system.…

Optimization and Control · Mathematics 2022-02-11 Thomas Chambrion , Eugenio Pozzoli

In a previous paper we proposed a model to describe a gas of pyramidal molecules interacting via dipole-dipole interactions. The interaction modifies the tunneling properties between the classical equilibrium configurations of the single…

Statistical Mechanics · Physics 2007-05-23 Carlo Presilla , Giovanni Jona-Lasinio , Cristina Toninelli

We investigate the full control over the orientation of a non-symmetric molecule by using moderate and weak electric fields. Quantum Optimal Control techniques allow us to orient any axis of 6-chloropyridazine-3-carbonitrile, which is taken…

Quantum Physics · Physics 2023-11-21 Rosario González-Férez , Juan J. Omiste

In this paper, we analyze classical and quantum physical systems from an optimal control perspective. Specifically, we explore whether their associated dynamics can correspond to an open or closed-loop feedback evolution of a control…

Optimization and Control · Mathematics 2020-06-12 Mauricio Contreras G. , Marcelo Villena

We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

The capability to control molecular rotation for field-free orientation, which arranges molecules in specific spatial directions without external fields, is crucial in physics, chemistry, and quantum information science. However,…

Quantum Physics · Physics 2025-12-25 Qian-Qian Hong , Zhe-Jun Zhang , Chuan-Cun Shu , Jun He , Daoyi Dong , Dajun Ding

In Coulomb 3-body problems, configurations of close proximity of the particles are classically unstable. In confined systems they might however exist as excited quantum states. Quantum control of such states by time changing electromagnetic…

Quantum Physics · Physics 2024-11-15 R. Vilela Mendes

We experimentally demonstrate coherent control of a quantum system, whose dynamics is chaotic in the classical limit. Interaction of diatomic molecules with a periodic sequence of ultrashort laser pulses leads to the dynamical localization…

Quantum Physics · Physics 2017-01-25 Martin Bitter , Valery Milner

This analysis is concerned with the controllability of quantum systems in the case where the standard dipolar approximation, involving the permanent dipole moment of the system, is corrected with a polarizability term, involving the field…

Analysis of PDEs · Mathematics 2014-06-17 Nabile Boussaid , Marco Caponigro , Thomas Chambrion

We investigate optimal control strategies for state to state transitions in a model of a quantum dot molecule containing two active strongly interacting electrons. The Schrodinger equation is solved nonperturbatively in conjunction with…

Quantum Physics · Physics 2016-08-14 R. Nepstad , L. Sælen , I. Degani , J. P. Hansen

We experimentally study the optical- and terahertz- induced rotational dynamics of asymmetric molecules in the gas phase. Terahertz and optical fields are identified as two distinct control handles over asymmetric molecules, as they couple…

Chemical Physics · Physics 2016-09-07 Ran Damari , Shimshon Kallush , Sharly Fleischer

Manipulation of infinite dimensional quantum systems is important to controlling complex quantum dynamics with many practical physical and chemical backgrounds. In this paper, a general investigation is casted to the controllability problem…

Quantum Physics · Physics 2009-11-11 Re-Bing Wu , Tzyh-Jong Tarn , Chun-Wen Li

We study a classical multiparticle system (such as Toda lattice) whose dynamics we intend to control by forces applied to few particles of the system. Various problem settings, typical for control theory are posed for this model; among…

Optimization and Control · Mathematics 2008-09-16 Andrey Sarychev
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