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Strong light-matter coupling in chiral cavities has been proposed as an effective way to selectively interact with an enantiomer that shares the same handedness as the cavity's chiral mode. We show that surface plasmons supported by a…

Single-loop cyclic three-level ($\Delta$-type) configuration of chiral molecules was used for enantio-separation in many theoretical works. Considering the effect of molecular rotation, this simple single-loop configuration is generally…

Quantum Physics · Physics 2018-12-12 Chong Ye , Quansheng Zhang , Yong Li

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

Quantum Physics · Physics 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch

We propose a method for enantio-detection of chiral molecules based on a cavity-molecule system, where the left- and right-handed molecules are coupled with a cavity and two classical light fields to form cyclic three-level models. Via the…

Quantum Physics · Physics 2021-10-25 Yu-Yuan Chen , Chong Ye , Yong Li

Chiral discrimination of enantiomeric biomolecules is vital in chemistry, biology, and medicine. Conventional methods, relying on circularly polarized light, face weak chiroptical signals and potential photodamage. Despite extensive efforts…

Quantum Physics · Physics 2026-01-21 Yiquan Yang , Xiaolong Hu , Wei Du , Shuhe Wu , Peiyu Yang , Guzhi Bao , Weiping Zhang

State-selective enantiomeric excess is realized using microwave-driven coherent population transfer. The method selectively promotes either R or S molecules to a higher rotational state by phase-controlled microwave pulses that drive…

Chemical Physics · Physics 2017-03-23 Sandra Eibenberger , John Doyle , David Patterson

The development of efficient techniques to distinguish mirror images of chiral molecules (enantiomers) is very important in both chemistry and physics. Enantiomers share most molecular properties except, for instance, the absorption of…

Chemical Physics · Physics 2023-07-11 Rosario R. Riso , Laura Grazioli , Enrico Ronca , Tommaso Giovannini , Henrik Koch

Inspired by a sea creature, we identify a robust chiral optical force that pushes the opposite enantiomers of a chiral molecule towards regions of orthogonal linear polarization in an optical field via electric dipole interactions. Our…

Enantio-conversion with the help of electromagnetic fields is an essential issue due to the chirality-dependence of many chemical, biological, and pharmaceutical processes. Here, we propose a method for this issue based on a five-level…

Quantum Physics · Physics 2021-03-03 Chong Ye , Bo Liu , Yu-Yuan Chen , Yong Li

We show that the position of the exceptional points (EPs) in the parameter space of a chiral molecule coupled to the photoionization continuum by a three-color field is enantiosensitive. Using a minimal model of a three-level system driven…

Quantum Physics · Physics 2023-07-11 Nicola Mayer , Nimrod Moiseyev , Olga Smirnova

We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…

Quantum Physics · Physics 2015-05-28 W. Z. Jia , L. F. Wei

We propose an accurate and convenient method to achieve 100\% discrimination of chiral molecules with Lewis-Riesenfeld invariant. By reversely designing the pulse scheme of handed resolution, we obtain the parameters of the three-level…

Quantum Physics · Physics 2023-05-24 Hang Xu , Xue-Ke Song , Dong Wang , Liu Ye

We study the enantio-specific state transfer in a four-level model for symmetric-top chiral molecules. Such a model is formed by coupling the electric-dipole transitions among four appropriate working states with three electromagnetic…

Quantum Physics · Physics 2022-04-27 Bo Liu , Chong Ye , C. P. Sun , Yong Li

We investigate enantiodetection for both a single cyclic three-level chiral molecule and finite ensembles of such molecules by monitoring the steady-state intracavity photon number in a cavity-QED platform. Our scheme exploits the intrinsic…

Quantum Physics · Physics 2025-11-14 Xiang Guo , Xiaojun Zhang , Yong Li , Zhihai Wang

Distinguishing between the left- and right-handed versions of a chiral molecule (enantiomers) is vital, but also inherently difficult. Traditional optical methods using elliptically or circularly polarized light rely on weak linear effects…

Optics · Physics 2022-06-08 Laura Rego , David Ayuso

We explore the spatial enantioseparation of gaseous chiral molecules for the cyclic three-level systems coupled with three electromagnetic fields. Due to molecular rotations, the specific requirements of the polarization directions of the…

Atomic Physics · Physics 2021-11-16 Bo Liu , Chong Ye , C. P. Sun , Yong Li

Electrostatic hexapoles are revealed as a powerful tool in the rotational state-selection and alignment of molecules to be utilized in beam experiments on collisional and photoinitiated processes. In the paper, we report results on the…

Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…

Chemical Physics · Physics 2025-03-07 Andrés Ordóñez , Patricia Vindel-Zandbergen , David Ayuso

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

An interesting class of molecules is that in which the molecules do not possess a stereogenic center but can become chiral due to their spatial arrangement. These molecules can be seen as chiral conformers, whose two non-superimposable…

Chemical Physics · Physics 2021-06-11 Cristóbal Pérez , Amanda L. Steber , Anna Krin , Melanie Schnell