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Methods of the explicitly correlated F12 approach are applied to the problem of calculating the uncoupled second-order dispersion energy in symmetry-adapted perturbation theory. The accuracy of the new method is tested for noncovalently…

Chemical Physics · Physics 2018-05-15 Michal Przybytek

The Finite Element Method (FEM) is a well-established procedure for computing approximate solutions to deterministic engineering problems described by partial differential equations. FEM produces discrete approximations of the solution with…

The method of sub-iteration, which was previously applied to the higher-order coupled cluster amplitude equations, is extended to the case of the coupled cluster $\Lambda$ equations. The sub-iteration procedure for the $\Lambda$ equations…

Chemical Physics · Physics 2025-03-26 Devin A. Matthews

We derive efficient and reliable goal-oriented error estimations, and devise adaptive mesh procedures for the finite element method that are based on the localization of a posteriori estimates. In our previous work [SIAM J. Sci. Comput.,…

Numerical Analysis · Mathematics 2020-03-23 Bernhard Endtmayer , Ulrich Langer , Thomas Wick

We develop and analyse residual-based a posteriori error estimates for the virtual element discretisation of a nonlinear stress-assisted diffusion problem in two and three dimensions. The model problem involves a two-way coupling between…

Numerical Analysis · Mathematics 2026-02-26 Franco Dassi , Rekha Khot , Andres E. Rubiano , Ricardo Ruiz-Baier

We consider the a posteriori error estimation for convection-diffusion-reaction equations in both diffusion-dominated and convection/reaction-dominated regimes. We present an explicit hybrid estimator, which, in each regime, is proved to be…

Numerical Analysis · Mathematics 2021-07-16 Difeng Cai , Zhiqiang Cai

An a posteriori verification method is proposed for the generalized real-symmetric eigenvalue problem and is applied to densely clustered eigenvalue problems in large-scale electronic state calculations. The proposed method is realized by a…

Computational Physics · Physics 2020-03-13 Takeo Hoshi , Takeshi Ogita , Katsuhisa Ozaki , Takeshi Terao

In this paper we consider a sub-diffusion problem where the fractional time derivative is approximated either by the L1 scheme or by Convolution Quadrature. We propose new interpretations of the numerical schemes which lead to a posteriori…

Numerical Analysis · Mathematics 2022-03-02 Lehel Banjai , Charalambos G. Makridakis

We shall establish the convergence of an adaptive conforming finite element method for the reconstruction of the distributed flux in a diffusion system. The adaptive method is based on a posteriori error estimators for the distributed flux,…

Numerical Analysis · Mathematics 2013-09-10 Yifeng Xu , Jun Zou

The state-of-the art proof of a global inf-sup condition on mixed finite element schemes does not allow for an analysis of truly indefinite, second-order linear elliptic PDEs. This paper, therefore, first analyses a nonconforming finite…

Numerical Analysis · Mathematics 2014-01-21 Carsten Carstensen , Asha K. Dond , Neela Nataraj , Amiya K. Pani

Motivated by problems in contact mechanics, we propose a duality approach for computing approximations and associated a posteriori error bounds to solutions of variational inequalities of the first kind. The proposed approach improves upon…

Numerical Analysis · Mathematics 2014-10-09 Zhenying Zhang , Eduard Bader , Karen Veroy

Chemical accuracy serves as an important metric for assessing the effectiveness of the numerical method in Kohn--Sham density functional theory. It is found that to achieve chemical accuracy, not only the Kohn--Sham wavefunctions but also…

Computational Physics · Physics 2023-10-25 Yang Kuang , Yedan Shen , Guanghui Hu

We derive a posteriori error estimates for the hybridizable discontinuous Galerkin (HDG) methods, including both the primal and mixed formulations, for the approximation of a linear second-order elliptic problem on conforming simplicial…

Numerical Analysis · Mathematics 2017-06-20 Mark Ainsworth , Guosheng Fu

We propose a novel a posteriori error estimator for the N\'ed\'elec finite element discretization of time-harmonic Maxwell's equations. After the approximation of the electric field is computed, we propose a fully localized algorithm to…

Numerical Analysis · Mathematics 2024-02-28 T. Chaumont-Frelet

We derive a reliable a posteriori error estimate for a cell-centered finite volume scheme approximating a cross-diffusion system modeling ion transport through nanopores. To this end, we derive a stability framework that is independent of…

Numerical Analysis · Mathematics 2025-07-28 Arne Berrens , Jan Giesselmann

Defeaturing consists in simplifying geometrical models by removing the geometrical features that are considered not relevant for a given simulation. Feature removal and simplification of computer-aided design models enables faster…

Numerical Analysis · Mathematics 2021-12-01 Annalisa Buffa , Ondine Chanon , Rafael Vázquez

In this work we derive a posteriori error estimates for the convection-diffusion-reaction equation coupled with the Darcy-Forchheimer problem by a nonlinear external source depending on the concentration of the fluid. We introduce the…

Numerical Analysis · Mathematics 2022-12-27 Toni Sayah , Georges Semaan , Faouzi Triki

The estimation of a density profile from experimental data points is a challenging problem, usually tackled by plotting a histogram. Prior assumptions on the nature of the density, from its smoothness to the specification of its form, allow…

Methodology · Statistics 2015-03-13 Alberto Bernacchia , Simone Pigolotti

We investigate the convergence of coupled-cluster correlation energies and related quantities with respect to the employed basis set size for the uniform electron gas to gain a better understanding of the basis set incompleteness error. To…

Materials Science · Physics 2024-02-27 Nikolaos Masios , Felix Hummel , Andreas Grüneis , Andreas Irmler

In this article, we present an interpolative separable density fitting (ISDF) based algorithm to calculate exact exchange in periodic mean field calculations. In the past, decomposing the two-electron integrals into tensor hypercontraction…

Chemical Physics · Physics 2024-04-16 Kori E. Smyser , Alec White , Sandeep Sharma
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