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This work presents a new class of hybrid density functional theory (DFT) approximations, incorporating nonlocal exact exchange in predefined states such as core atomic orbitals (AOs). These projected hybrid density functionals are a…

Chemical Physics · Physics 2023-05-16 Benjamin G. Janesko

The exact-exchange relativistic density functional theory (Ex-RDFT) of atomic nuclei has been solved in three-dimensional lattice space for the first time. The exchange energy is treated within the framework of the orbital-dependent…

Nuclear Theory · Physics 2024-12-16 Qiang Zhao , Zhengxue Ren , Pengwei Zhao , Kenichi Yoshida

In this paper, we present a first comparison of different Adaptive Optics (AO) concepts to reach a given scientific specification for 3D spectroscopy on Extremely Large Telescope (ELT). We consider that a range of 30%-50% of Ensquarred…

A classical density functional theory (cDFT) based on the PC-SAFT equation of state is proposed for the calculation of adsorption equilibria of pure substances and their mixtures in covalent organic frameworks (COFs). Adsorption isotherms…

Statistical Mechanics · Physics 2021-03-24 Christopher Kessler , Johannes Eller , Joachim Gross , Niels Hansen

Nuclear implementation of the density functional theory (DFT) is at present the only microscopic framework applicable to the whole nuclear landscape. The extension of DFT to superfluid systems in the spirit of the Kohn-Sham approach, the…

Nuclear Theory · Physics 2021-08-24 Shi Jin , Kenneth J. Roche , Ionel Stetcu , Ibrahim Abdurrahman , Aurel Bulgac

Semilocal (SL) density functional approximations (DFAs) are widely applied but have limitations due to their inability to incorporate long-range van der Waals (vdW) interaction. Non-local functionals (vdW-DF, VV10, rVV10) or empirical…

Materials Science · Physics 2024-06-19 Santosh Adhikari , Niraj K. Nepal , Hong Tang , Adrienn Ruzsinszky

To investigate inelastic electron scattering, which is ubiquitous in various fields of study, we carry out ab initio study of the real-time dynamics of a one-dimensional electron wave packet scattered by a hydrogen atom using different…

Atomic Physics · Physics 2020-06-24 Yeonghun Lee , Xiaolong Yao , Massimo V. Fischetti , Kyeongjae Cho

Here we report the optical and x-ray absorption (XAS) spectra of the wide-band-gap oxide MgO using density functional theory (DFT) and many-body perturbation theory (MBPT). Our comprehensive study of the electronic structure shows that…

Other Condensed Matter · Physics 2021-05-19 Vijaya Begum , Markus E. Gruner , Christian Vorwerk , Claudia Draxl , Rossitza Pentcheva

The analysis of the electronic surface properties of transition metal oxides being key materials for future nanoelectronics requires a direct characterization of the conductivity with highest spatial resolution. Using local conductivity…

Mesoscale and Nanoscale Physics · Physics 2021-10-15 C. Rodenbücher , G. Bihlmayer , W. Speier , J. Kubacki , M. Wojtyniak , M. Rogala , D. Wrana , F. Krok , K. Szot

We propose a novel scheme to bring reduced density matrix functional theory (RDMFT) into the realm of density functional theory (DFT) that preserves the accurate density functional description at equilibrium, while incorporating accurately…

Chemical Physics · Physics 2014-11-07 Nektarios N. Lathiotakis , Nicole Helbig , Angel Rubio , Nikitas I. Gidopoulos

The time-dependent density functional theory (TDDFT) has been broadly used to investigate the excited-state properties of various molecular systems. However, the current TDDFT heavily relies on outcomes from the corresponding ground-state…

Chemical Physics · Physics 2020-09-02 Shu-Hao Yeh , Aaditya Manjanath , Yuan-Chung Cheng , Jeng-Da Chai , Chao-Ping Hsu

This chapter presents the development of a density functional theory (DFT)-based method for accurate, reliable treatment of various resonances in atoms. Many of these are known to be notorious for their strong correlation, proximity to more…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy

We have used the Green Bank Telescope (GBT) and Berkeley-Illinois-Maryland Association (BIMA) array to search for redshifted millimetre absorption in a sample of damped Lyman-alpha absorption systems (DLAs). This brings the number of…

Astrophysics · Physics 2009-11-10 S. J. Curran , M. T. Murphy , Y. M. Pihlstroem , J. K. Webb , A. D. Bolatto , G. C. Bower

Optimizing the photovoltaic efficiency of dye-sensitized solar cells (DSSC) based on staggered gap heterojunctions requires a detailed understanding of sub-band gap transitions in the visible from the dye directly to the substrate's…

Materials Science · Physics 2016-06-22 Duncan John Mowbray , Annapaola Migani

Ensemble Density Functional Theory (EDFT) is a promising extension to Density Functional Theory (DFT) for calculating excited states. While Kohn-Sham eigenvalue differences underestimate gaps, EDFT has been shown to provide more accurate…

Materials Science · Physics 2026-02-10 Gregory G. V. Kenning , Remi J. Leano , David A. Strubbe

We present recent advances in Density Functional Theory (DFT) for applications to the field of quantum transport, with particular emphasis on transport through strongly correlated systems. We review the foundations of the popular…

Mesoscale and Nanoscale Physics · Physics 2017-10-11 S. Kurth , G. Stefanucci

Static electric response properties of atoms and molecules are reported within the real-space Cartesian grid implementation of pseudopotential Kohn-Sham (KS) density functional theory (DFT). A detailed systematic investigation is made for a…

Chemical Physics · Physics 2019-04-26 Tanmay Mandal , Abhisek Ghosal , Amlan K. Roy

We present an application of our new theoretical formulation of quantum dynamics, moment propagation theory (MPT) (Boyer et al., J. Chem. Phys. 160, 064113 (2024)), for employing machine-learning techniques to simulate the quantum dynamics…

Chemical Physics · Physics 2024-12-09 Nicholas J. Boyer , Christopher Shepard , Ruiyi Zhou , Jianhang Xu , Yosuke Kanai

Time-dependent electronic structure methods provide an efficient, accurate, and robust alternative to traditional time dependent methods for computing both linear and non-linear optical properties. With this in mind, we have developed the…

Chemical Physics · Physics 2026-01-26 Thomas Knoll , Benjamin G. Levine

We develop an analytical model to describe sub-bandgap optical absorption in two-dimensional semiconducting transition metal dichalcogenide (s-TMD) nanoflakes. The material system represents an array of few-layer molybdenum disulfide…

Mesoscale and Nanoscale Physics · Physics 2016-10-11 Maxim Trushin , Edmund J. R. Kelleher , Tawfique Hasan