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Electronic resonances are metastable states with finite lifetimes, encountered in processes such as photodetachment, electron transmission, and Auger decay. Resonances appear in Hermitian quantum mechanics as increased density of states in…

Chemical Physics · Physics 2025-11-10 Cansu Utku , Garrette Pauley Paran , Thomas-C. Jagau

Within the framework of imaginary-time evolution for matrix product states, we introduce a cluster version of the infinite time-evolving block decimation algorithm for simulating quantum many-body systems, addressing the computational…

Strongly Correlated Electrons · Physics 2025-09-01 Tao Yang , Rui Wang , Z. Y. Xie , Baigeng Wang

Quantum chemical methods dealing with challenging systems while retaining low computational costs have attracted attention. In particular, many efforts have been devoted to developing new methods based on the second-order perturbation that…

Chemical Physics · Physics 2023-10-30 Nhan Tri Tran , Hoang Thanh Nguyen , Lan Nguyen Tran

We present a quantum algorithm for simulating a family of Markovian master equations that can be realized through a probabilistic application of unitary channels and state preparation. Our approach employs a second-order product formula for…

Quantum Physics · Physics 2024-07-02 Evan Borras , Milad Marvian

A central roadblock in the realization of variational quantum eigensolvers on quantum hardware is the high overhead associated with measurement repetitions, which hampers the computation of complex problems, such as the simulation of mid-…

Quantum Physics · Physics 2026-05-13 Davide Bincoletto , Jakob S. Kottmann

The Wigner function for one and two-mode quantum systems is explicitely expressed in terms of the marginal distribution for the generic linearly transformed quadratures. Then, also the density operator of those systems is written in terms…

Quantum Physics · Physics 2009-10-30 G. M. D'Ariano , S. Mancini , V. I. Man'ko , P. Tombesi

We propose an orbital optimized method for unitary coupled cluster theory (OO-UCC) within the variational quantum eigensolver (VQE) framework for quantum computers. OO-UCC variationally determines the coupled cluster amplitudes and also…

Strongly Correlated Electrons · Physics 2020-09-23 Wataru Mizukami , Kosuke Mitarai , Yuya O. Nakagawa , Takahiro Yamamoto , Tennin Yan , Yu-ya Ohnishi

We present several improvements to the standard Trotter-Suzuki based algorithms used in the simulation of quantum chemistry on a quantum computer. First, we modify how Jordan-Wigner transformations are implemented to reduce their cost from…

Quantum Physics · Physics 2016-12-15 M. B. Hastings , D. Wecker , B. Bauer , M. Troyer

It is well known that the neutrino flavor in extreme astrophysical environments changes under the effect of three contributions: the vacuum oscillation, the interaction with the surrounding matter, and the collective oscillations due to…

Herein we study the problem of recovering a density operator from a set of compatible marginals, motivated from limitations of physical observations. Given that the set of compatible density operators is not singular, we adopt Jaynes'…

Mathematical Physics · Physics 2021-01-21 Serena Di Giorgio , Paulo Mateus

Estimating expectation values on near-term quantum computers often requires a prohibitively large number of measurements. One widely-used strategy to mitigate this problem has been to partition an operator's Pauli terms into sets of…

Currently available noisy intermediate-scale quantum (NISQ) devices are limited by the number of qubits that can be used for quantum chemistry calculations on molecules. We show herein that the number of qubits required for simulations on a…

In this work, we explore the reuse of terms in the Jastrow factor between systems for use in the transcorrelated method, to reduce the number of optimisable parameters for a given system. In particular, we propose a workflow in which…

The distinguishable cluster approximation applied to coupled cluster doubles equations greatly improves absolute and relative energies. We apply the same approximation to the triples equations and demonstrate that it can also improve…

Chemical Physics · Physics 2019-05-01 Daniel Kats , Andreas Köhn

An efficiency of the Tucker decomposition of amplitude tensors within the single-reference relativistic coupled cluster method with single and double excitations (RCCSD) was studied in a series of benchmark calculations for (AuCl)$_n$…

Computational Physics · Physics 2025-07-29 Alexander V. Oleynichenko , Artem S. Rumiantsev , Andrei Zaitsevskii , Ephraim Eliav

We use the large N_f self consistency formalism to compute the $O(1/N_f)$ critical exponent corresponding to the renormalization of the flavour non-singlet twist two Wilson operators which arise in the operator product expansion of currents…

High Energy Physics - Phenomenology · Physics 2009-10-28 J. A. Gracey

We address the problem of compressing density operators defined on a finite dimensional Hilbert space which assumes a tensor product decomposition. In particular, we look for an efficient procedure for learning the most likely density…

Quantum Physics · Physics 2020-04-21 S. Di Giorgio , P. Mateus , B. Mera

An implementation of a complex solver for the solution of the response equations required to compute the complex response functions of damped response theory is presented for the resolution-of-identity (RI) coupled-cluster singles and…

Chemical Physics · Physics 2022-03-29 Daniil A. Fedotov , Sonia Coriani , Christof Hättig

The quantum Drude oscillator (QDO) is an efficient yet accurate coarse-grained approach that has been widely used to model electronic and optical response properties of atoms and molecules, as well as polarization and dispersion…

A natural counterpart to the Lie-Trotter product formula for norm-continuous one-parameter semigroups is proved, for the class of quasicontractive quantum stochastic operator cocycles whose expectation semigroup is norm continuous. Compared…

Functional Analysis · Mathematics 2018-01-18 J. Martin Lindsay