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Understanding CO electro-oxidation is crucial towards designing catalysts for electrochemically oxidizing complex organic molecules. Earth-abundant Copper (Cu) has recently been demonstrated to exhibit high alkaline CO electro-oxidation…

The tetraaza [Co$^\text{II}$N$_4$H]$^{2+}$ complex (\textbf{1}) is remarkable for its ability to selectively reduce CO$_2$ to CO with 45\% Faradaic efficiency and a CO to H$_2$ ratio of 3:2. We employ density functional theory (DFT) to…

Palladium (Pd) catalysts have been extensively studied for the direct synthesis of H2O through the hydrogen oxidation reaction at ambient conditions. This heterogeneous catalytic reaction not only holds considerable practical significance…

Materials Science · Physics 2024-04-23 Yukun Liu , Kunmo Koo , Zugang Mao , Xianbiao Fu , Xiaobing Hu , Vinayak P. Dravid

Copper is a good CO2 electroreduction catalyst as products beyond CO form, but efficiency and selectivity is low. Experiments have shown that admixture of other elements can help, and computational screening studies have pointed out various…

Elucidating the catalytic descriptor that accurately characterizes the structure-activity relationships of typical catalysts for various important heterogeneous catalytic reactions is pivotal for designing high-efficient catalytic systems.…

Chemical Physics · Physics 2025-10-23 Zhen Zhu , Shan Gao , Jing Zhang , Xuxin Kang , Shunfang Li , Xiangmei Duan

The measured capacitance, modulus and strength of carbon nanotube-polyaniline (CNT-PANI) composite electrodes render them promising candidates for structural energy storage devices. Here, CNT-PANI composite electrodes are manufactured with…

Applied Physics · Physics 2021-06-18 Wei Tan , Joe C. Stallard , Changshin Jo , Michael F. L. De Volder , Norman A. Fleck

Developing efficient electrocatalysts for CO$_2$ reduction into value-added products is crucial for the green economy. Inspired by the recent synthesis of Biphenylene (BPH), we have systematically investigated pristine, defective, and…

Materials Science · Physics 2024-10-28 Radha N Somaiya , Muhammad Sajjad , Nirpendra Singh , Aftab Alam

The electrolysis of CO$_2$ in molten carbonate has been introduced as an alternative mechanism to synthesize carbon nanomaterials inexpensively at high yield. Until recently, CO$_2$ was thought to be unreactive, making its removal a…

Materials Science · Physics 2022-01-21 Xinye Liu , Gad Licht , Xirui Wang , Stuart Licht

Facing with grave climate change and enormous energy demand, catalyzer gets more and more important due to its significant effect on reducing fossil fuels consumption. Hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by…

Materials Science · Physics 2023-09-07 Yuan Chang , Panlong Zhai , Jungang Hou , Jijun Zhao , Junfeng Gao

Effective spin mixing conductance (ESMC) across the nonmagnetic metal (NM)/ferromagnet interface, spin Hall conductivity (SHC) and spin diffusion length (SDL) in the NM layer govern the functionality and performance of pure spin current…

Materials Science · Physics 2016-09-02 L. Ma , H. A. Zhou , L. Wang , X. L. Fan , W. J. Fan , D. S. Xue , K. Xia , G. Y. Guo , S. M. Zhou

Two-dimensional (2D) layered nanomaterials heterostructures, arising from the combination of 2D materials with other low-dimensional species, feature large surface area to volume ratio, which provides a high density of active sites for…

Materials Science · Physics 2025-02-19 Mengjiao Wang , Michal Langer , Roberto Altieri , Matteo Crisci , Silvio Osella , Teresa Gatti

Efficient discovery of electrocatalysts for electrochemical energy conversion reactions is of utmost importance to combat climate change. With the example of the oxygen reduction reaction we show that by utilising a data-driven discovery…

The development of ferromagnet/heavy metal thin-film structures, such as CoFeB/Mo, with spin-orbit interaction requires advanced methods for their production and study. Polarized neutron reflectometry (PNR) provides unique insights into the…

Using CoOx thin films supported on Au(111) single crystal surfaces as model catalysts for the CO oxidation reaction we show that three reaction regimes exist in response to chemical and topographic restructuring of the CoOx catalyst as a…

Stable oxygen sites on a PdO film over a Pd(100) thin structures with a (sqrt{5} times sqrt{5}) R27^circ surface-unit cell are determined using the first-principles electronic structure calculations with the generalized gradient…

Materials Science · Physics 2015-05-14 K. Kusakabe , K. Harada , Y. Ikuno , H. Nagara

Electroactive polymers (EAP) are smart materials that can be used as actuators, sensors or energy harvesters in many fields. We had previously studied an ionic metal-polymer composites (IPMC), which consists in an ionic polymer film such as…

Soft Condensed Matter · Physics 2023-05-16 Mireille Tixier , Joël Pouget

Sustainable development and the recent fast growing global demands for energy and functional chemicals urgently call for effective methods for CO2 remediation and efficient metal-free catalysts for selective oxidation of aromatic alcohol.…

Chemical Physics · Physics 2018-12-31 Jiang Gong , Huijuan Lin , Konrad Grygiel , Jiayin Yuan

For decades of catalysis research, the d-band center theory that correlates the d-band center and the adsorbate binding energy has successfully enabled the accelerated discovery of novel catalyst materials. Recent studies indicate that, on…

High-Tc superconductivity with possible $T_{c}\approx 80K$ has been reported in the single crystal of $\text{La}_{3}\text{Ni}_{2}\text{O}_{7}$ under high pressure. Based on the electronic structure given from the density functional theory…

Strongly Correlated Electrons · Physics 2023-11-23 Yang Shen , Mingpu Qin , Guang-Ming Zhang

The formation of a 3D network composed of free standing and interconnected Pt nanowires is achieved by a two-step method, consisting of conformal deposition of Pt by atomic layer deposition (ALD) on a forest of carbon nanotubes and…

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