Related papers: Interstellar formamide (NH$_2$CHO), a key prebioti…
The emergence of habitable conditions on the early Earth and on rocky exoplanets requires persistent energy sources that can drive both prebiotic chemistry and climate warming under magnetically active young G to M stars. To quantify the…
The formation of molecules in the interstellar medium (ISM) remains a complex and unresolved question in astrochemistry. A group of molecules of particular interest involves the linkage between a -carboxyl and -amine group, similar to that…
Rocky planets may acquire a primordial atmosphere by outgassing of volatiles from their magma ocean. The distribution of O between H$_2$O, CO and CO$_2$ in chemical equilibrium subsequently changes significantly with decreasing temperature.…
Hydroxylamine (NH$_{2}$OH) and methylamine (CH$_{3}$NH$_{2}$) have both been suggested as precursors to the formation of amino acids and are therefore of interest to prebiotic chemistry. Their presence in interstellar space and formation…
In the interstellar medium, the amide-type molecules play an important role in the formation of the prebiotic molecules in the hot molecular cores or high-mass star formation regions. The complex amide-related molecule cyanamide…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
Complex organic molecules (COMs) are widely detected in protostellar and protoplanetary systems, where they are thought to have been inherited in large part from earlier evolutionary phases. The chemistry of COMs in these earlier phases,…
Planets form and obtain their compositions in disks of gas and dust around young stars. The chemical compositions of these planet-forming disks regulate all aspects of planetary compositions from bulk elemental inventories to access to…
Complex organic molecules (COMs) are detected in many regions of the interstellar medium, including prestellar cores. However, their formation mechanisms in cold (~10 K) cores remain to this date poorly understood. The formyl radical HCO is…
There is mounting evidence that the composition and structure of planetary systems are intimately linked to their birth environments. During the past decade, several spectral surveys probed the chemistry of the earliest stages of star…
Despite the detection of numerous interstellar complex organic molecules (iCOMs) for decades, it is still a matter of debate whether they are synthesized in the gas-phase or on the icy surface of interstellar grains. In the past, molecular…
Formic acid (HCOOH) has been extensively detected in space environments, including interstellar medium (gas and grains), comets and meteorites. Such environments are often subjected to the action of ionizing agents, which may cause changes…
Glycolaldehyde, a sugar-related interstellar prebiotic molecule, has recently been detected in two star-forming regions, Sgr B2(N) and G31.41+0.31. The detection of this new species increased the list of complex organic molecules detected…
N-methylformamide, CH3NHCHO, may be an important molecule for interstellar pre-biotic chemistry because it contains a peptide bond. The rotational spectrum of the most stable trans conformer of CH3NHCHO is complicated by strong…
In recent years, phosphorus monoxide (PO) -- an important molecule for prebiotic chemistry -- has been detected in star-forming regions and in the comet 67P/Churyumov-Gerasimenko. These studies have revealed that, in the interstellar…
Glycolaldehyde (HOCH2CHO) is the most straightforward sugar detected in the Interstellar Medium (ISM) and participates in the formation pathways of molecules fundamental to life, red such as ribose and derivatives. Although detected in…
Observations of comets and asteroids show that the Solar Nebula that spawned our planetary system was rich in water and organic molecules. Bombardment brought these organics to the young Earth's surface, seeding its early chemistry. Unlike…
Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…
Large interstellar organic molecules are potential precursors of prebiotic molecules. Their formation pathways and chemical relationships with one another and simpler molecules are therefore of great interest. In this paper, we address the…
Comets spend most of their lives at large distances from any star, during which time their interior compositions remain relatively unaltered. Cometary observations can therefore provide direct insight into the chemistry that occurred during…