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Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

We propose a simple and accurate model for the electron static structure factors (and corresponding pair-correlation functions) of the 3D unpolarized homogeneous electron gas. Our spin-resolved pair-correlation function is built up with a…

Condensed Matter · Physics 2009-10-31 Paola Gori-Giorgi , Francesco Sacchetti , Giovanni B. Bachelet

An exchange correlation energy functional involving fractional power of the one-body reduced density matrix [Phys. Rev. B {\bf 78}, 201103 (2008)] is applied to finite systems and to the homogeneous electron gas. The performance of the…

Strongly Correlated Electrons · Physics 2015-05-13 N. N. Lathiotakis , S. Sharma , J. K. Dewhurst , F. Eich , M. A. L. Marques , E. K. U. Gross

In ultrathin wires positioned on high-k dielectric substrates or nearby metallic gates electrons can form strongly correlated one-dimensional fluids already at rather high electron densities. The density-density correlation function, charge…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. M. Fogler

Precise calculations of dynamics in the homogeneous electron gas (jellium model) are of fundamental importance for design and characterization of new materials. We introduce a diagrammatic Monte Carlo technique based on algorithmic…

Strongly Correlated Electrons · Physics 2022-12-21 James P. F. LeBlanc , Kun Chen , Kristjan Haule , Nikolay V. Prokof'ev , Igor S. Tupitsyn

The coupling constant dependence is derived in time-dependent {\em current} density functional theory. The scaling relation can be used to check approximate functionals and in conjunction with the adiabatic connection formula to obtain the…

Materials Science · Physics 2009-11-11 Maxime Dion , Kieron Burke

The correlation energy in density functional theory can be expressed exactly in terms of the change in the probability of finding two electrons at a given distance $r_{12}$ (intracule density) when the electron-electron interaction is…

Other Condensed Matter · Physics 2017-08-23 Paola Gori-Giorgi , Michael Seidl , Andreas Savin

We derive a generalized gradient approximation to the exchange energy to be used in density functional theory calculations of two-dimensional systems. This class of approximations has a long and successful history, but it has not yet been…

Strongly Correlated Electrons · Physics 2009-01-07 S. Pittalis , E. Rasanen , J. G. Vilhena , M. A. L. Marques

The thermoelectric power S is studied within the one-dimensional Hubbard model using the linear response theory and the numerical exact-diagonalization method for small systems. While both the diagonal and off-diagonal dynamical correlation…

Strongly Correlated Electrons · Physics 2009-11-10 M. M. Zemljic , P. Prelovsek

Density matrix quantum Monte Carlo (DMQMC) is used to sample exact-on-average $N$-body density matrices for uniform electron gas systems of up to 10$^{124}$ matrix elements via a stochastic solution of the Bloch equation. The results of…

Strongly Correlated Electrons · Physics 2016-09-14 Fionn D. Malone , N. S. Blunt , Ethan W. Brown , D. K. K. Lee , J. S. Spencer , W. M. C. Foulkes , James J. Shepherd

We obtain the conductance of a system of electrons connected to leads, within time-dependent density-functional theory, using a direct relation between the conductance and the density response function. Corrections to the non-interacting…

Materials Science · Physics 2007-10-04 P. Bokes , J. Jung , R. W. Godby

The exchange-correlation hole and potential of the homogeneous electron gas have been investigated within the random-phase approximation, employing the plasmon-pole approximation for the linear density response function. The angular…

Strongly Correlated Electrons · Physics 2023-04-12 K. Karlsson , F. Aryasetiawan

We develop a theory of thermal transport of weakly interacting electrons in quantum wires. Unlike higher-dimensional systems, a one-dimensional electron gas requires three-particle collisions for energy relaxation. The fastest relaxation is…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Alex Levchenko , Tobias Micklitz , Zoran Ristivojevic , K. A. Matveev

We consider trapped bosons with contact interactions as well as Coulomb repulsion or gravitational attraction in one spatial dimension. The exact ground state energy and wave function are identified in closed form together with a rich phase…

Quantum Gases · Physics 2020-11-26 M. Beau , S. M. Pittman , G. E. Astrakharchik , A. del Campo

The prospect of using light to probe or manipulate quantum materials has become an active area of interest. Here, we investigate a quantum wire -- treated as a finite-sized one-dimensional electron gas -- that is coupled to a single…

Quantum Gases · Physics 2025-06-23 Victor Bradley , Kamal Sharma , Mohammad Hafezi , Wade DeGottardi

We find an unexpected scaling in the correlation energy of artificial atoms, i.e., harmonically confined two-dimensional quantum dots. The scaling relation is found through extensive numerical examinations including Hartree-Fock,…

Mesoscale and Nanoscale Physics · Physics 2015-04-28 Alexander Odriazola , Mikko M Ervasti , Ilja Makkonen , Alain Delgado , Augusto González , Esa Räsänen , Ari Harju

Multi-configurational approaches yield universal wave function parameterizations that can qualitatively well describe electronic structures along reaction pathways. For quantitative results, multi-reference perturbation theory is required…

Chemical Physics · Physics 2016-09-08 Christopher J. Stein , Vera von Burg , Markus Reiher

Quantum correlations can be used as a resource for quantum computing, eg for quantum state manipulation, and for quantum sensing, eg for creating non-classical states which allow to achieve the quantum advantage regime. This review collects…

Quantum Gases · Physics 2023-02-14 Anna Minguzzi , Patrizia Vignolo

We report extensive self-consistent calculations of jellium surface energies, by going beyond the local-density approximation. The density-response function of a bounded free-electron gas is evaluated within the random-phase approximation,…

Materials Science · Physics 2009-10-31 J. M. Pitarke , A. G. Eguiluz

We have calculated the correlation energy of the homogeneous electron gas (HEG) and the dissociation energy curves of molecules with covalent bonds from a novel implementation of the adiabatic connection fluctuation dissipation (ACFD)…

Strongly Correlated Electrons · Physics 2015-06-22 Nicola Colonna , Maria Hellgren , Stefano de Gironcoli