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We consider a prototype polyene chain: donor-$\pi$(bridge)-acceptor. The distance between the donor and the acceptor is varied by increasing the number of bridged atoms and rate of electron transfer, k$_{et}$ is studied for a series of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 S. Lakshmi , Ayan Datta , Swapan K. Pati

We study the propagation of $\alpha$-helix polarons in a model describing the non-adiabatic interaction between an electron and a lattice of quantum mechanical oscillators at physiological temperature. We show that when excited by a…

Other Condensed Matter · Physics 2018-07-16 Jingxi Luo , Bernard M. A. G. Piette

We examine, using mixed classical-quantum electron-ion dynamics, electron transfer in a donor-acceptor-like molecular junction system based on polyacetylene. We identify two qualitatively-different transfer regimes: hopping and tunnelling.…

Mesoscale and Nanoscale Physics · Physics 2014-04-25 D. Psiachos

Optical control is achieved on the excited state energy transfer between spatially separated donor and acceptor molecules, both coupled to the same optical mode of a cavity. The energy transfer occurs through the formed hybrid polaritons…

We present a theory of non-equilibrium long range charge transfer between donor and acceptor centers in a model polymer mediated by magnetic exciton (Kondo) bound states. Our model produces electron tunneling lengths easily exceeding…

Strongly Correlated Electrons · Physics 2007-05-23 R. G. Endres , D. L. Cox , R. R. P. Singh , S. K. Pati

Charge transfer is a fundamental process that underlies a multitude of phenomena in chemistry and biology. Recent advances in observing and manipulating charge and heat transport at the nanoscale, and recently developed techniques for…

Mesoscale and Nanoscale Physics · Physics 2016-07-26 Galen T. Craven , Abraham Nitzan

A theory of electrical transport through molecular wires is used to estimate the electronic factor in the intramolecular electron transfer (ET) in porphyrin-nitrobenzene supermolecules, and to analyze its structure. The chosen molecules…

Soft Condensed Matter · Physics 2007-05-23 Natalya Zimbovskaya , Godfrey Gumbs

Intermolecular electron transfer reaction often occurs over long range distances (i.e. up to several tens of angstroms) and plays a key role in various physical, chemical and biological processes. In these reactions the rate constant of…

Chemical Physics · Physics 2017-05-08 Ashish Kumar , Diwaker , Anirudhha Chakraborty

The present work investigates electron transport and heating mechanisms using an (r, z) particle-in-cell (PIC) simulation of a typical rf-driven axisymmetric magnetron discharge with a conducting target. It is shown that for the considered…

Recent experimental evidence shows that the pi-orbitals along the stacking of base pairs can facilitate the long-range charge transfer in DNA. Proton motion in the base pair hydrogen bonds has also been found to affect the transfer rate. To…

Materials Science · Physics 2009-11-10 Chun-Min Chang , A. H. Castro Neto , A. R. Bishop

We demonstrate plasmon assisted energy transfer between fluorophores located at distances up to $7 \, \mu$m on the top of a thin silver film. Thanks to the strong confinement and large propagation length of surface plasmon polaritons, the…

Optics · Physics 2016-01-27 D. Bouchet , D. Cao , R. Carminati , Y. De Wilde , V. Krachmalnicoff

In the paper, we considered a molecular structure that consists of a molecular chain and an additional molecule ("donor"/"acceptor") that can inject (or remove) single excitation (vibron, electron, e.t.c.) onto the molecular chain. We…

Mesoscale and Nanoscale Physics · Physics 2023-08-17 V. Matic , Z. Ivic , Z. Przulj , D. Chevizovich

The electron transfer in different solvents is investigated for systems consisting of donor, bridge and acceptor. It is assumed that vibrational relaxation is much faster than the electron transfer. Electron transfer rates and final…

Soft Condensed Matter · Physics 2016-09-28 D. Kilin , U. Kleinekathoefer , M. Schreiber

We report an ultra long range energy transfer in a layered donor:spacer:acceptor structures, which consist of the typical organic photovoltaic material system of P3HT as the donor and PCBM as the acceptor. By varying the thicknesses of…

Applied Physics · Physics 2021-04-29 Eran Avnon , Ariel Epstein , Olga Solomeshch , Nir Tessler

The separation of photogenerated polaron pairs in organic bulk heterojunction solar cells is the intermediate but crucial step between exciton dissociation and charge transport to the electrodes. In state-of-the-art devices, above 80% of…

Materials Science · Physics 2009-07-16 C. Deibel , T. Strobel , V. Dyakonov

We consider a polaron model where molecular \emph{rotations} are important. Here, the usual hopping between neighboring sites is affected directly by the electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This model…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Wei Zhang , Alexander O. Govorov , Sergio E. Ulloa

We develop a mathematically rigorous theory for the quantum transfer processes in degenerate donor-acceptor dimers in contact with a thermal environment. We calculate explicitly the transfer rates and the acceptor population efficiency. The…

Quantum Physics · Physics 2020-07-15 Marco Merkli , Gennady P. Berman , Avadh Saxena

We study the nature of the energy transfer process within a pair of coupled two-level systems (donor and acceptor) subject to interactions with the surrounding environment. Going beyond a standard weak-coupling approach, we derive a master…

Quantum Physics · Physics 2011-04-05 Dara P. S. McCutcheon , Ahsan Nazir

We study the interplay of intrinsic-electronic and environmental factors on long-range charge transport across molecular chains with up to $N\sim 80$ monomers. We describe the molecular electronic structure of the chain with a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2022-09-21 Francisco Lai Liang , Dvira Segal

The production of electron-positron pairs with the capture of the electron in an atomic orbital is investigated for the conditions of the Relativistic Heavy Ion Collider (RHIC) and the Large Hadron Collider LHC). Dirac wave functions for…

Nuclear Theory · Physics 2009-11-06 C. A. Bertulani , D. S. Dolci
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