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This work develops and illustrates a new method of calculating "chemically accurate" electronic wavefunctions (and energies) via a truncated full configuration interaction (CI) procedure which arguably circumvents the large matrix…

Chemical Physics · Physics 2022-12-21 Stephen J. Cotton

Configuration-interaction-type calculations on electronic and vibrational structure are often the method of choice for the reliable approximation of many-particle wave functions and energies. The exponential scaling, however, limits their…

Computational Physics · Physics 2019-05-24 Alberto Baiardi , Christopher J. Stein , Vincenzo Barone , Markus Reiher

The Markov decision process (MDP) formulation used to model many real-world sequential decision making problems does not efficiently capture the setting where the set of available decisions (actions) at each time step is stochastic.…

Machine Learning · Computer Science 2020-01-22 Yash Chandak , Georgios Theocharous , Blossom Metevier , Philip S. Thomas

In this paper we propose a new multiple criteria decision aiding method to deal with sorting problems in which alternatives are evaluated on criteria structured in a hierarchical way and presenting interactions. The underlying preference…

Optimization and Control · Mathematics 2020-03-11 Sally Giuseppe Arcidiacono , Salvatore Corrente , Salvatore Greco

Quantum-mechanical methods are widely used for understanding molecular interactions throughout biology, chemistry, and materials science. Quantum diffusion Monte Carlo (DMC) and coupled cluster with single, double, and perturbative triple…

This paper presents a novel algorithmic study with extensive numerical experiments of distributionally robust multistage convex optimization (DR-MCO). Following the previous work on dual dynamic programming (DDP) algorithmic framework for…

Optimization and Control · Mathematics 2025-11-24 Shixuan Zhang , Xu Andy Sun

In this paper we discuss distributional robustness in the context of stochastic model predictive control (SMPC) for linear time-invariant systems. We derive a simple approximation of the MPC problem under an additive zero-mean i.i.d. noise…

Optimization and Control · Mathematics 2023-03-07 Christoph Mark , Steven Liu

Multifunctionality is ubiquitous in biological neurons. Several studies have translated the concept to artificial neural networks as well. Recently, multifunctionality in reservoir computing (RC) has gained the widespread attention of…

Chaotic Dynamics · Physics 2025-04-18 Swarnendu Mandal , Kazuyuki Aihara

We present a new high-performance configuration interaction code optimally designed for the calculation of the lowest energy eigenstates of a few electrons in semiconductor quantum dots (also called artificial atoms) in the strong…

Strongly Correlated Electrons · Physics 2007-05-23 Massimo Rontani , Carlo Cavazzoni , Devis Bellucci , Guido Goldoni

An adaptive randomized distributed space-time coding (DSTC) scheme and algorithms are proposed for two-hop cooperative MIMO networks. Linear minimum mean square error (MMSE) receivers and an amplify-and-forward (AF) cooperation strategy are…

Information Theory · Computer Science 2013-03-19 T. Peng , R. C. de Lamare , A. Schmeink

This paper proposes an Adaptive Stochastic Model Predictive Control (MPC) strategy for stable linear time-invariant systems in the presence of bounded disturbances. We consider multi-input, multi-output systems that can be expressed by a…

Systems and Control · Electrical Eng. & Systems 2019-12-11 Monimoy Bujarbaruah , Charlott Vallon

Key challenges in the analysis of highly multivariate large-scale spatial stochastic processes, where both the number of components (p) and spatial locations (n) can be large, include achieving maximal sparsity in the joint precision…

Methodology · Statistics 2026-01-27 Xiaoqing Chen , Peter Diggle , James V. Zidek , Gavin Shaddick

Accurate many-body treatments of condensed-phase systems are challenging because correlated solvers such as full configuration interaction (FCI) and the density matrix renormalization group (DMRG) scale exponentially with system size.…

Unbiased stochastic sampling of the one- and two-body reduced density matrices is achieved in full configuration interaction quantum Monte Carlo with the introduction of a second, "replica" ensemble of walkers, whose population evolves in…

Computational Physics · Physics 2015-09-02 Robert E. Thomas , Daniel Opalka , Catherine Overy , Peter J. Knowles , Ali Alavi , George H. Booth

Rate-splitting multiple access (RSMA) has emerged as a promising technique for efficient interference management in next-generation wireless networks. While most existing studies focus on downlink and single-cell designs, the modeling and…

Information Theory · Computer Science 2025-12-25 Xinyi Guo , Li You , Qiong Liu , Xiqi Gao , Xiang-Gen Xia

We use the recently-developed Heat-bath Configuration Interaction (HCI) algorithm as an efficient active-space solver to perform multi-configuration self-consistent field calculations (HCISCF) with large active spaces. We give a detailed…

Chemical Physics · Physics 2018-11-08 James E. T. Smith , Adam A. Holmes , Bastien Mussard , Sandeep Sharma

A reliable and efficient computation of the entire single-particle spectrum of correlated molecules is an outstanding challenge in the field of quantum chemistry, with standard density functional theory approaches often giving an inadequate…

Chemical Physics · Physics 2021-10-08 Oliver J. Backhouse , Alejandro Santana-Bonilla , George H. Booth

The density-matrix renormalization group (DMRG) method, which can deal with a large active space composed of tens of orbitals, is nowadays widely used as an efficient addition to traditional complete active space (CAS)-based approaches. In…

Strongly Correlated Electrons · Physics 2016-11-06 Yingjin Ma , Jing Wen , Haibo Ma

The learning of predictive models for data-driven decision support has been a prevalent topic in many fields. However, construction of models that would capture interactions among input variables is a challenging task. In this paper, we…

Machine Learning · Computer Science 2019-05-22 Jiapeng Liu , Milosz Kadzinski , Xiuwu Liao , Xiaoxin Mao

Information storage, reflecting the capability of a dynamical system to keep predictable information during its evolution over time, is a key element of intrinsic distributed computation, useful for the description of the dynamical…