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We test a hypothesis for the origin of dynamical heterogeneity in slowly relaxing systems, namely that it emerges from soft (Goldstone) modes associated with a broken continuous symmetry under time reparametrizations. We do this by…

Disordered Systems and Neural Networks · Physics 2013-10-30 Karina E. Avila , Horacio E. Castillo , Azita Parsaeian

We review recent results from computer simulation studies of polymer glasses, from chain dynamics around the glass transition temperature Tg to the mechanical behaviour below Tg. These results clearly show that modern computer simulations…

Materials Science · Physics 2010-09-29 Jean-Louis Barrat , Joerg Baschnagel , Alexei Lyulin

We briefly review the basics ideas and results of a recently proposed statistical mechanical approach to granular materials. Using lattice models from standard Statistical Mechanics and results from a mean field replica approach and Monte…

Condensed Matter · Physics 2009-10-31 Antonio Coniglio , Mario Nicodemi

The effect of cooling on the brittleness of glasses in general, and bulk metallic glasses (BMGs) in particular, is usually studied with continuously varying cooling rates; slower cooling rates lead to stiffer, harder, and more brittle…

Materials Science · Physics 2025-01-27 Achraf Atila , Sergey V. Sukhomlinov , Marc J. Honecker , Martin H. Müser

The fundamental aspects of relaxation dynamics in Bi0.9Gd0.1Fe0.9Mn0.1O3 multiferroic system have been reported. The study was carried out employing dielectric relaxation spectroscopy covering eight decades in frequency 0.01 to106 Hz and in…

The process of crystal nucleation can be accelerated or retarded by ultrasonic vibration, which is particularly attractive for the addictive manufacture and thermoplastic forming of metallic glasses, however, the effect and mechanism of…

Materials Science · Physics 2022-12-06 Baoshuang Shang , Noel Jakse , Pengfei Guan , Weihua Wang , Jean-louis Barrat

Dielectric relaxation spectroscopy (1 Hz - 20 GHz) has been performed on supercooled glass-formers from the temperature of glass transition (T_g) up to that of melting. Precise measurements particularly in the frequencies of MHz-order have…

Disordered Systems and Neural Networks · Physics 2009-11-07 Takuya Fujima , Hiroshi Frusawa , Kohzo Ito

We propose a scenario for the glass transition based on the cooperative nature of nucleation processes and entropic effects. The main point is the relation between the off-equilibrium energy dissipation and nucleation processes in…

Soft Condensed Matter · Physics 2009-11-07 A. Crisanti , F. Ritort

Dielectric measurements on molecular liquids just above the glass transition indicate that alpha relaxation is characterized by a generic high-frequency loss varying as $\omega^{-1/2}$, whereas deviations from this come from one or more…

Soft Condensed Matter · Physics 2009-11-11 Jeppe C. Dyre

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

Soft Condensed Matter · Physics 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

Theoretical approaches are formulated to investigate the molecular mobility under various cooling rates of amorphous drugs. We describe the structural relaxation of a tagged molecule as a coupled process of cage-scale dynamics and…

Soft Condensed Matter · Physics 2019-12-10 Anh D. Phan , Katsunori Wakabayashi , Marian Paluch , Vu D. Lam

The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast)…

We provide broadband dielectric loss spectra of glass-forming glycerol with varying additions of LiCl. The measurements covering frequencies up to 10 THz extend well into the region of the fast beta process, commonly ascribed to caged…

Soft Condensed Matter · Physics 2013-08-07 M. Köhler , P. Lunkenheimer , Y. Goncharov , A. Loidl

We have connected the dynamic fragility, namely the rapidity of the relaxation time increase upon temperature reduction, to the excess entropy and heat capacity of a large number of glass-forming polymers. The connection was obtained in a…

Soft Condensed Matter · Physics 2009-11-11 D. Cangialosi , A. Alegria , J. Colmenero

The molecular mobility of glass and supercooled liquid states of nilutamide has been studied with broadband dielectric spectroscopy for a wide range of temperature and frequency. Besides primary $\alpha$-relaxation an excess wing like…

Soft Condensed Matter · Physics 2016-06-21 N. S. K. Kumar , G. Govindaraj , U. Sailaja

The dynamics of structural relaxation in a model polymer glass subject to spatially-homogeneous, time-periodic shear deformation is investigated using molecular dynamics simulations. We study a coarse-grained bead-spring model of short…

Soft Condensed Matter · Physics 2014-01-10 Nikolai V. Priezjev

We propose that there exists a generic class of glass forming systems that have competing states (of crystalline order or not) which are locally close in energy to the ground state (which is typically unique). Upon cooling, such systems…

Statistical Mechanics · Physics 2009-11-13 Valery Ilyin , Itamar Procaccia , Ido Regev , Nurith Schupper

Aging in spin glasses (and in some other systems) reveals astonishing effects of `rejuvenation and memory' upon temperature changes. In this paper, we propose microscopic mechanisms (at the scale of spin-spin interactions) which can be at…

Disordered Systems and Neural Networks · Physics 2009-11-07 S. Miyashita , E. Vincent

Quantum effects in material systems are often pronounced at low energies and become insignificant at high temperatures. We find that, perhaps counterintuitively, certain quantum effects may follow the opposite route and become sharp when…

Statistical Mechanics · Physics 2015-09-08 Z. Nussinov , F. Nogueira , M. Blodgett , K. F. Kelton

We study by light microscopy a soft glass consisting of a compact arrangement of polydisperse elastic spheres. We show that its slow and non-stationary dynamics results from the unavoidable small fluctuations of temperature, which induce…

Soft Condensed Matter · Physics 2009-11-11 Sylvain Mazoyer , Luca Cipelletti , Laurence Ramos