Related papers: Defect physics in $Yb^{3+}$-doped $CaF_2$ from fir…
The formation of heterogeneous lanthanide-ion clusters in CaF$_2$ was investigated experimentally and computationally. CaF$_2$ nanoparticles co-doped with 20~mol\% Yb$^{3+}$ and 2~mol\% Ln$^{3+}$ (Ln$^{3+}$ = Ce$^{3+}$, Pr$^{3+}$,…
Lanthanide-doped fluorides are promising materials for advanced photonic and quantum applications due to their wide bandgap, low phonon energy, and chemical stability. In this work, we present a systematic comparative study of ytterbium…
The fast luminescence component of barium fluoride (BaF$_2$) crystals with a subnanosecond decay time can find wide application in particle physics and nuclear physics. However, the slow luminescence component with the 630~ns decay time…
We report studies of the Yb$^{3+}$ site distribution in Er$^{3+}$ co-doped upconverting alkaline earth fluoride nanoparticles using high-resolution absorption measurements. Similar to bulk crystals, Yb$^{3+}$ single ion cubic (O$_h$), and…
We report the scintillation and timing performance of a new developed 200 * 20 mm * 20 mm large size barium fluoride crystal doped with 3at% yttrium (BaF2:Y) to enhance the application for high time resolution. This doping effectively…
We investigate the luminescence properties of 10 nm YAG nanoparticles doped with Ce ions at 0.2%, 4% and 13% that are designed as active probes for Scanning Near field Optical Microscopy. They are produced by a physical method without any…
We report the existence of intervalence charge transfer (IVCT) luminescence in Yb-doped fluorites associated with Yb2+-Yb3+ mixed valence pairs. We show that the very broad band, anomalous emission of Yb2+-doped CaF2 and SrF2, usually…
Understanding the physics of structurally and chemically complex transition-metal oxide and polyanionic materials such as those used for battery electrodes is challenging, even at the level of pristine compounds. Yet these materials are…
CaF$_2$:Yb$^{2+}$ and SrF$_2$:Yb$^{2+}$ crystals have been investigated by a two-color UV + IR transient photoluminescence enhancement technique. The enhancement gives information about both changes in internal energy levels of the excitons…
Building on recent advances of the embedded cluster approach combined with multiconfigurational theory, this work investigates the electronic states in thorium-doped CaF2 crystals. Th:CaF2 is currently establishing as a promising material…
Vacancy-cluster color centers in lithium fluoride have been studied in detail both theoretically and experimentally for over a century, giving rise to various applications in solid-state lasers, broadband photonic devices, and radiation…
The energetics of mixing and defect ordering in solid solutions of fluorite-structured ThO$_{2}$ with oxides of trivalent cations (Sc, In, Y, Nd, La) are investigated by electronic density-functional-theory (DFT). Through DFT calculations…
High-temperature superconductivity in iron pnictides occurs when electrons are doped into their antiferromagnetic (AF) parent compounds. In addition to inducing superconductivity, electron-doping also changes the static commensurate AF…
Radiation defects in barium fluoride single crystals doped with cadmium have been investigated by luminescence and absorption spectroscopy, as well as by electron spin resonance spectroscopy. Three types of Cd$^+$ centers differing by the…
In this supplemental document we explain the details of our ab initio density functional theory calculations and crystal structure searches performed in CaF2 under pressure. Also we report the computed P-dependence of the formation energy…
We demonstrate experimentally that optical wavefront shaping selectively couples light into the fundamental diffusion mode of a scattering medium. The total energy density inside a scattering medium of zinc oxide (ZnO) nanoparticles was…
The luminescence of fifteen representative Eu$^{2+}$-doped phosphors used for white-LED and scintillation applications is studied through a Constrained Density Functional Theory. Transition energies and Stokes shift are deduced from…
In this work, diopside (CaMgSi2O6) was doped with fluoride at a level of 1 mol.%, without the formation of any second phase, by a wet chemical precipitation method. The sintered structure of the synthesized nanopowders was studied by X-ray…
Solar-driven water electrolysis requires high-performance photoelectrodes that exhibit excellent photoabsorption, superior charge transport, and optimized thermal management. In this work, we conducted a first-principles investigation to…
Erbium doped low symmetry Y$_2$SiO$_5$ crystals attract a lot of attention in perspective of quantum information applications. However, only doping of the samples during growth is available up to now, which yields a quite homogeneous doping…