Related papers: Triatomic butterfly molecules
The level structure of negative-ions near the electron detachment limit dictates the low-energy scattering of an electron with the parent neutral atom. We demonstrate that a single ultracold atom bound inside a Rydberg orbit forming an…
We show that the dipole-dipole interaction between three identical Rydberg atoms can give rise to bound trimer states. The microscopic origin of these states is fundamentally different from Efimov physics. Two stable trimer configurations…
H$_3^{2+}$ is a one-electron system with three positive nuclei and is known to be unstable in its electronic ground-state. We examine an analogous one-electron system composed of a $^{87}$Rb Rydberg atom interacting with a pair of cations…
The spectrum of triatomic molecules with close rovibrational opposite parity levels is sensitive to the $\mathcal{P}$,$\mathcal{T}$-odd effects. This makes them a convenient platform for the experimental search of a new physics. Among the…
This Ph.D. tutorial discusses ultra-long-range Rydberg molecules, the exotic bound states of a Rydberg atom and one or more ground state atoms immersed in the Rydberg electron's wave function. This novel chemical bond is distinct from an…
Sufficiently high densities in Bose-Einstein condensates provide favorable conditions for the production of ultralong-range polyatomic molecules consisting of one Rydberg atom and a number of neutral ground state atoms. The chemical binding…
The detection of vibrational excitations of individual molecules on surfaces by scanning tunneling spectroscopy does not obey strict selection rules but rather propensity rules. The experimental verification of these is challenging because…
Rydberg molecule, formed by one or more Rydberg atoms, exhibits remarkable properties, including an exceptionally large spatial extent, rich rovibrational level structures, permanent electric dipole moments, and a pronounced sensitivity to…
This article covers few selected aspects of quantum theory of molecular rotations and vibrations. Triatomic molecules are the simplest systems, which show qualitative characteristics of larger polyatomic molecules. On the minimal example of…
We investigate the interaction between three rubidium atoms in highly excited ($58p$) Rydberg states lying along a common axis and calculate the potential energy surfaces (PES) between the three atoms. We find that three-body long-range…
We consider two identical fermions interacting in the p-wave channel. Each fermion also interacts with another particle in the vicinity of an s-wave resonance. We find that in addition to the Kartavtsev-Malykh universal trimer states…
We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…
Long-range Rydberg molecules are typically bound in wells formed in their oscillatory potential energy curves. In alkaline Rydberg molecules, bound vibrational states exist even when these potential wells are disrupted by level repulsion…
We present a systematic understanding of the rotational structure of a long-range (vibrationally highly-excited) diatomic molecule. For example, we show that depending on a quantum defect, the least-bound vibrational state of a diatomic…
We study ultracold long-range collisions of heteronuclear alkali-metal dimers with a reservoir gas of alkali-metal Rydberg atoms in a two-photon laser excitation scheme. In a low density regime where molecules remain outside the Rydberg…
We propose an experiment to demonstrate a novel blockade mechanism caused by long-range anisotropic interactions in an ultracold dipolar gas composed of the recently observed "butterfly" Rydberg molecules. At the blockade radius, the strong…
We investigate the formation of trimers in an infinite one-dimensional lattice model of hard-core particles with single-particle hopping $t$ and and nearest-neighbour two-body $U$ and three-body $V$ interactions of relevance to Rydberg…
We investigate the impact of combined electric and magnetic fields on the structure of ultralong-range polar Rydberg molecules. Our focus is hereby on the parallel as well as the crossed field configuration taking into account both the…
The quantum mechanics of three interacting particles gives rise to interesting universal phenomena, such as the staircase of Efimov trimers predicted in the context of nuclear physics and observed in ultracold gases. Here, we observe a…
We investigate the three-body properties of two identical "up" fermions and one distinguishable "down" atom interacting in a strongly confined two-dimensional geometry. We compute exactly the atom-dimer scattering properties and the…