Related papers: Boltzmann entropy for quantum field systems
A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…
Boltzmann's principle is used to select the "most probable" realization (macrostate) of an isolated or closed thermodynamic system, containing a small number of particles ($N \llsp \infty$), for both classical and quantum statistics. The…
It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…
Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level…
The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics…
Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a…
In this work we study the evolution of Boltzmann's entropy in the context of free expansion of a one dimensional interacting gas inside a box. Boltzmann's entropy is defined for single microstates and is given by the phase-space volume…
Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…
The paper examines and critiques the expression of entropy as the logarithm of the number of quantum states of a physical system. Boltzmann method of expressing entropy as the logarithm of the number of states of a gas with a given total…
We present a scheme to evaluate thermodynamic variables for a system coupled to a heat bath under a time-dependent external force using the quasi-static Helmholtz energy from the numerically "exact" hierarchical equations of motion (HEOM).…
Boltzmann's entropy is slightly modified to make it suitable for discussing phase transitions in finite systems. As an example it is shown that the pendulum undergoes a second order phase transition when passing from a vibrational to a…
A dynamical estimate is given for the Boltzmann entropy of the Universe, under the simplifying assumptions provided by Newtonian cosmology. We first model the cosmological fluid as the probability fluid of a quantum-mechanical system. Next,…
We construct a complete set of Wannier functions which are localized at both given positions and momenta. This allows us to introduce the quantum phase space, onto which a quantum pure state can be mapped unitarily. Using its probability…
In this paper, we review the concept of entropy in connection with the description of quantum unstable systems. We revise the conventional definition of entropy due to Boltzmann and extend it so as to include the presence of complex-energy…
Experimental and theoretical results about entropy limits for macroscopic and single-particle systems are reviewed. It is clarified when it is possible to speak about a quantum of entropy, given by the Boltzmann constant k, and about a…
A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way…
The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…
The Von Neumann entropy of reduced states is a measure of bipartite entanglement. Despite its name, the entanglement entropy cannot by itself be used as a resource for creating thermodynamic heat flows. In order to extract heat from an…
In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…
The classical thermostatics of equilibrium processes is shown to possess a quantum-mechanical dual theory with a finite-dimensional Hilbert space of quantum states. Specifically, the kernel of a certain Hamiltonian operator becomes the…