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Droplet coalescence is an important process in nature and various technologies (e.g. inkjet printing). Here, we unveil the surfactant mass-transport mechanism and report on several major differences in the coalescence of surfactant-laden…

We study spreading of a droplet, with insoluble surfactant covering its capillary surface, on a textured substrate. In this process, the surfactant-dependent surface tension dominates the behaviors of the whole dynamics, particularly the…

Fluid Dynamics · Physics 2022-11-08 Yuan Gao , Jian-Guo Liu

We investigate the coalescence of surfactant-laden water droplets by using several different surfactant types and a wide range of concentrations by means of a coarse-grained model obtained by the statistical associating fluid theory. Our…

Soft Condensed Matter · Physics 2023-11-07 Soheil Arbabi , Piotr Deuar , Mateusz Denys , Rachid Bennacer , Zhizhao Che , Panagiotis E. Theodorakis

The spreading dynamics of surfactant molecules on a thin fluid layer is of both fundamental and practical interest. A mathematical model formulated by Gaver and Grotberg 1990 describing the spreading of a single layer of insoluble…

Fluid Dynamics · Physics 2013-06-21 Ellen R. Swanson , Stephen L. Strickland , Michael Shearer , Karen E. Daniels

Surfactant transport is central to a diverse range of natural phenomena, and for many practical applications in physics and engineering. Surprisingly, this process remains relatively poorly understood at the molecular scale. This study…

Soft Condensed Matter · Physics 2025-04-16 Muhammad Rizwanur Rahman , James P. Ewen , Li Shen , D. M. Heyes , Daniele Dini , E. R. Smith

This fluid dynamics video shows how an oil-in-water emulsion stabilized by an ionic surfactant spreads on the free surface of a layer of pure water. The spreading shows two intriguing features: a transparent area surrounding the source of…

Fluid Dynamics · Physics 2010-10-18 Matthieu Roche , Zhenzhen Li , Ian Griffiths , Arnaud Saint-Jalmes , Howard A. Stone

The motion of a viscous deformable droplet suspended in an unbounded Poiseuille flow in the presence of bulk-insoluble surfactants is studied analytically. Assuming the convective transport of fluid and heat to be negligible, we perform a…

Fluid Dynamics · Physics 2017-09-13 Sayan Das , Shubhadeep Mandal , Suman Chakraborty

We present a study of the spreading of liquid droplets on a solid substrate at very small scales. We focus on the regime where effective wetting energy (binding potential) and surface tension effects significantly influence steady and…

Fluid Dynamics · Physics 2017-02-15 Hanyu Yin , David N. Sibley , Uwe Thiele , Andrew J. Archer

Certain trisiloxane surfactants have the remarkable property of being able to superspread: Small volumes of water rapidly wet large areas of hydrophobic surfaces. The molecular properties of the surfactants which govern this technologically…

Hypothesis: Surrounding fluids affect critically drop wetting dynamics in many applications involving viscous environments. Although macroscopic effects of outer fluid viscosity on contact line motion have been documented, the extent to…

Fluid Dynamics · Physics 2025-12-15 Yingjie Fei , Qindan Zhang , Youguang Ma , Huai-Zhi Li

The dynamics of wetting and dewetting is largely determined by the velocity field near the contact lines. For water drops it has been observed that adding surfactant decreases the dynamic receding contact angle even at a concentration much…

With most of the focus to date having been on the coalescence of freely suspended droplets, much less is known about the coalescence of sessile droplets, especially in the case of droplets laden with surfactant. Here, we employ large-scale…

Soft Condensed Matter · Physics 2024-03-19 S. Arbabi , P. Deuar , R. Bennacer , Z. Che , P. E. Theodorakis

We study the collision dynamics of surfactant-laden droplets and compare it with that of pure water droplets, with a focus on the bridge growth rate, energy balance, and disk dynamics, distinguishing the cases of head-on and off-centre…

Soft Condensed Matter · Physics 2025-08-15 Soheil Arbabi , Piotr Deuar , Rachid Bennacer , Zhizhao Che , Panagiotis E. Theodorakis

The complicated dynamics of the contact line of a moving droplet on a solid substrate often hamper the efficient modeling of microfluidic systems. In particular, the selection of the effective boundary conditions, specifying the contact…

In this work, we propose a novel transport model for soluble surfactants in two-phase flows. In a two-phase flow, the soluble surfactants can adsorb/desorb from/into the bulk of any of the phases to the interface and can modify the…

Fluid Dynamics · Physics 2025-10-14 Suhas S. Jain

Droplet impacts are common in many applications such as coating, spraying, or printing; understanding how droplets spread after impact is thus of utmost importance. Such impacts may occur with different velocities on a variety of…

Fluid Dynamics · Physics 2024-11-05 Benjamin Gorin , Hamid Kellay , Daniel Bonn

Spraying is a widely used method to produce a liquid sheet that break up into droplets of a certain size distribution. When spraying simple liquids, it is known which experimental parameters determine the droplet size distribution. For many…

Fluid Dynamics · Physics 2021-11-16 R. Sijs , S. Kooij , D. Bonn

The physico-chemistry of surfactants (amphiphilic surface active agents) is often used to control the dynamics of viscous drops and bubbles. Surfactant sorption kinetics has been shown to play a critical role in the deformation of drops in…

Fluid Dynamics · Physics 2021-07-07 H. Nganguia , W. -F. Hu , M. -C. Lai , Y. -N. Young

Atmospheric aerosols can consist of inorganic and organic substances, including surfactants at a significant concentration. Importantly, the latter can reduce the surface tension at the liquid-vapor surfaces, where they preferentially…

Fluid Dynamics · Physics 2022-10-21 Mateusz Denys , Piotr Deuar , Zhizhao Che , Panagiotis E. Theodorakis

In the present study, the role of surfactants on the cross-stream migration of droplets is investigated both experimentally and theoretically. For experimental analysis, sunflower oil is used as the carrier phase and DI water as the…

Fluid Dynamics · Physics 2018-03-22 Somnath Santra , Sayan Das , Sankha Shuvra Das , Suman Chakraborty
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