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A method is proposed to pin down an unambiguous proof for single molecule surface enhanced Raman spectroscopy (SERS). The simultaneous use of two analyte molecules enables a clear confirmation of the single (or few) molecule nature of the…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , M. Meyer , P. G. Etchegoin

Here we show how surface-enhanced Raman spectroscopy (SERS) features can be fine-tuned in optically active substrates made of layered materials. To demonstrate this, we used DNA-assisted lithography (DALI) to create substrates with silver…

The present approach to SERS does not rely on a hihj electrical conductivity substrate or admixture to enable the SERS process. The novelty of our method is to create an artificial periodic electron distribution on a surface by illumination…

Materials Science · Physics 2007-10-22 Martin S. Piltch , Perry C. Gray , Michael Manley

Raman-based technologies have enabled many ground-breaking scientific discoveries related to surface science, single molecule chemistry and biology. For example, researchers have identified surface bound molecules by their Raman vibrational…

Optics · Physics 2020-03-12 Xiaoqin Shen , Hyungwoo Choi , Dongyu Chen , Wei Zhao , Andrea M. Armani

The experimental limitations in the signal enhancement and spatial resolution in spectroscopic imaging have been always a challenging task in the application of near-field spectroscopy for nanostructured materials in the sub-diffraction…

Materials Science · Physics 2018-06-11 A. K. Sivadasan , Avinash Patsha , Achyut Maity , Tapas Kumar Chini , Sandip Dhara

A periodic arrangement of chains of gold discs shows pronounced plasmonic grating resonances. These have a clear impact on the Surface Enhanced Raman Scattering (SERS)-signal from 4-methylbenzenethiol molecules which form self-assembled…

Single-molecule detection with chemical specificity is a powerful and much desired tool for biology, chemistry, physics, and sensing technologies. Surface-enhanced spectroscopies enable single molecule studies, yet reliable substrates of…

Mesoscale and Nanoscale Physics · Physics 2008-02-22 D. R. Ward , N. K. Grady , C. S. Levin , N. J. Halas , Y. Wu , P. Nordlander , D. Natelson

We present a general model study of surface-enhanced resonant Raman scattering and fluorescence focusing on the interplay between electromagnetic effects and the molecular dynamics. Our model molecule is placed close to two Ag…

Other Condensed Matter · Physics 2007-05-23 Hongxing Xu , Xue-Hua Wang , Martin P. Persson , H. Q. Xu , Mikael Kall , Peter Johansson

By means of rigorous numerical simulation calculations based on the Green's theorem integral equation formulation, we study the near EM field in the vicinity of very rough, one-dimensional self-affine fractal surfaces of Ag, Au, and Cu (for…

Disordered Systems and Neural Networks · Physics 2009-10-31 J. A. Sanchez-Gil , J. V. Garcia-Ramos , E. R. Mendez

We investigate multiple scattering of scalar waves by an ensemble of $N$ resonant point scatterers in three dimensions. For up to $N = 21$ scatterers, we numerically optimize the positions of the individual scatterers, such as to maximize…

Quantum Physics · Physics 2017-11-22 Frank Schäfer , Felix Eckert , Thomas Wellens

We explored the surface enhanced Raman scattering (SERS) activity of the InN nanostructures, possessing surface electron accumulation (SEA), using the Rhodamine 6G (R6G) molecules. SERS enhancement is observed for the InN nanostructures…

Materials Science · Physics 2018-08-14 Kishore K. Madapu , Sandip Dhara

Electromagnetic scattering bounds on subwavelength structures play an important role in estimating performances of antennas, RFID tags, and other wireless communication devices. An appealing approach to increase a scattering cross-section…

Raman spectroscopy, a photonic modality based on the inelastic backscattering of coherent light, is a valuable asset to the intraoperative sensing space, offering non-ionizing potential and highly-specific molecular fingerprint-like…

Image and Video Processing · Electrical Eng. & Systems 2024-01-18 Ashutosh Raman , Ren A. Odion , Kent K. Yamamoto , Weston Ross , Tuan Vo-Dinh , Patrick J. Codd

Raman scattering is the inelastic process where photons bounce off molecules, losing energy and becoming red-shifted. This weak effect is unique to each molecular species, making it an essential tool in e.g. spectroscopy and label-free…

Stimulated Raman scattering (SRS) represents a powerful tool for accessing the vibrational properties of molecular compounds or solid state systems. From a spectroscopic perspective, SRS is able to capture Raman spectra free from incoherent…

Raman scattering signal can be enhanced through localization of incident field into sub-wavelength hot-spots through plasmonic nano-structures (Surface-enhanced Raman scattering-SERS). Recently, further enhancement of SERS signal via…

Tip enhanced Raman scattering (TERS) amplifies the intensity of vibrational Raman scattering by employing the tip of a probe interacting, in ultra close proximity, with a surface. Although a general understanding of the TERS process is…

Stimulated Raman scattering (SRS) microscopy has emerged as a powerful technique for probing the spatiotemporal dynamics of molecular bonds with exceptional sensitivity, resolution, and speed. However, classically, its performance remains…

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

We show that topology optimization (TO) of metallic resonators can lead to $\sim 10^2\times$ improvement in surface-enhanced Raman scattering (SERS) efficiency compared to traditional resonant structures such as bowtie antennas. TO inverse…