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The problem of construction of the Wannier functions (WFs) in a restricted Hilbert space of eigenstates of the one-electron Hamiltonian $\hat{H}$ (forming the so-called low-energy part of the spectrum) can be formulated in several different…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev , Z. V. Pchelkina , V. I. Anisimov

We analyze in detail the error that arises from the linearization in linearized augmented-plane-wave (LAPW) basis functions around predetermined energies $E_l$ and show that it can lead to undesirable dependences of the calculated results…

Materials Science · Physics 2013-11-19 Gregor Michalicek , Markus Betzinger , Christoph Friedrich , Stefan Blügel

The existence and construction of exponentially localised Wannier functions for insulators is a well-studied problem. In comparison, the case of metallic systems has been much less explored, even though localised Wannier functions…

Mathematical Physics · Physics 2019-02-04 Horia Cornean , David Gontier , Antoine Levitt , Domenico Monaco

We present a technique for partitioning the total energy from a semi-local density functional theory calculation into contributions from individual electronic states in a localized Wannier basis. We use our technique to reveal the key role…

Materials Science · Physics 2025-10-15 Ethan T. Ritz , Guru Khalsa , Hsin-Yu Ko , Ju-an Zhang , Robert A. DiStasio , Nicole A. Benedek

Localized Wannier functions provide an efficient and intuitive framework to compute electric polarization from first-principles. They can also be used to represent the electronic systems at fixed electric field and to determine dielectric…

Materials Science · Physics 2020-01-28 Pawel Lenarczyk , Mathieu Luisier

The maximally localized Wannier functions play a very important role in the study of chemical bonding, ballistic transport and strongly-correlated system, etc. A significant development in this branch was made in 1997 and conjectured that…

Materials Science · Physics 2014-07-28 Sangryol Ri , Suil Ri

We introduce an automated workflow for generating non-empirical Wannier-localized optimally-tuned screened range-separated hybrid (WOT-SRSH) functionals. WOT-SRSH functionals have been shown to yield highly accurate fundamental band gaps,…

We extend the Intrinsic Atomic Orbital (IAO) method for localisation of molecular orbitals to calculate well-localised generalised Wannier functions in crystals using the Pipek--Mezey locality metric. We furthermore present a one-shot…

Materials Science · Physics 2024-07-02 Andrew Zhu , David P. Tew

We discuss a maximally localized Wannier function approach for constructing lattice models from first-principles electronic structure calculations, where the effective Coulomb interactions are calculated in the constrained…

Strongly Correlated Electrons · Physics 2009-11-13 Takashi Miyake , F. Aryasetiawan

We investigate the interplay of band structure topology and localization properties of Wannier functions. To this end, we extend a recently proposed compressed sensing based paradigm for the search for maximally localized Wannier functions…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 J. C. Budich , J. Eisert , E. J. Bergholtz , S. Diehl , P. Zoller

A new implementation is proposed for including van der Waals interactions in Density Functional Theory using the Maximally-Localized Wannier functions. With respect to the previous DFT/vdW-WF method, the present DFT/vdW-WF2 approach, which…

Strongly Correlated Electrons · Physics 2015-06-03 A. Ambrosetti , P. L. Silvestrelli

A procedure to construct symmetry-adapted Wannier functions in the framework of the maximally-localized Wannier function approach[Marzari and Vanderbilt, Phys. Rev. B \textbf{56}, 12847 (1997); Souza, Marzari, and Vanderbilt, \textit{ibid.}…

Strongly Correlated Electrons · Physics 2015-06-16 R. Sakuma

We use the maximally-localized Wannier function method to study bonding properties in amorphous silicon. This study represents, to our knowledge, the first application of the Wannier-function analysis to a disordered system. Our results…

Materials Science · Physics 2009-10-31 Pier Luigi Silvestrelli , Nicola Marzari , David Vanderbilt , Michele Parrinello

Accurate prediction of electronic and optical excitations in van der Waals (vdW) materials is a long-standing challenge for density functional theory. The recently proposed Wannier-localized optimally-tuned screened range-separated hybrid…

Maximally localized Wannier functions use the gauge freedom of Bloch wavefunctions to define the optimally smooth subspace with matrix elements that depend smoothly on crystal momentum. The associated Wannier functions are real-space…

Materials Science · Physics 2024-10-24 Giulio Volpato , Stefano Mocatti , Giovanni Marini , Matteo Calandra

Accurate prediction of fundamental band gaps of crystalline solid state systems entirely within density functional theory is a long standing challenge. Here, we present a simple and inexpensive method that achieves this by means of…

EPW (Electron-Phonon coupling using Wannier functions) is a program written in FORTRAN90 for calculating the electron-phonon coupling in periodic systems using density-functional perturbation theory and maximally-localized Wannier…

Other Condensed Matter · Physics 2015-05-19 Jesse Noffsinger , Feliciano Giustino , Brad D. Malone , Cheol-Hwan Park , Steven G. Louie , Marvin L. Cohen

We present an approach to parameterize DFT+$U$+$V$ from hybrid-functional calculations using Wannier-function projections. The method constructs a common localized Wannier basis for both semilocal DFT and hybrid-functional calculations,…

Strongly Correlated Electrons · Physics 2026-02-25 Dmitry M. Korotin , Anna A. Anisimova , Vladimir I. Anisimov

We report a $k$-point extension of the second-order co-iterative augmented Hessian (CIAH) algorithm, termed $k$-CIAH, for Pipek-Mezey (PM) localization of Wannier functions (WFs). By exploiting an efficient evaluation of the Hessian-vector…

Chemical Physics · Physics 2026-05-14 Gengzhi Yang , Hong-Zhou Ye

Functionals that strive to correct for such self-interaction errors, such as those obtained by imposing the Perdew-Zunger self-interaction correction or the generalized Koopmans' condition, become orbital dependent or orbital-density…

Materials Science · Physics 2011-08-30 Cheol-Hwan Park , Andrea Ferretti , Ismaila Dabo , Nicolas Poilvert , Nicola Marzari