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Even though irreversibility is one of the major hallmarks of any real life process, an actual understanding of irreversible processes remains still mostly semiempirical. In this paper we formulate a thermodynamic uncertainty principle for…

Statistical Mechanics · Physics 2021-03-17 Rudolf Hanel , Petr Jizba

The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible…

Statistical Mechanics · Physics 2021-11-09 Umberto Lucia , Emin Açıkkalp

Heat engines constitute the major building blocks of modern technologies. However, conventional heat engines with higher power yield lesser efficiency and vice versa and respect various power-efficiency trade-off relations. This is also…

Quantum Physics · Physics 2022-03-04 Mohit Lal Bera , Sergi Julià-Farré , Maciej Lewenstein , Manabendra Nath Bera

One of the fundamental questions in quantum thermodynamics concerns the decomposition of energetic changes into heat and work. Contrary to classical engines, the entropy change of the piston cannot be neglected in the quantum domain. As a…

Quantum Physics · Physics 2019-10-15 Wolfgang Niedenzu , Marcus Huber , Erez Boukobza

Power and efficiency are fundamental criteria for evaluating the performance of thermodynamic cycles. However, it is generally impossible to maximize both simultaneously. In particular, achieving maximum efficiency inevitably leads to…

Statistical Mechanics · Physics 2026-01-28 R. X. Zhai , Xin Yue , C. P. Sun

We consider a class of quantum heat engines consisting of two subsystems interacting via a unitary transformation and coupled to two separate baths at different temperatures $T_h > T_c$. The purpose of the engine is to extract work due to…

Statistical Mechanics · Physics 2009-11-13 Armen E. Allahverdyan , Ramandeep S. Johal , Guenter Mahler

The Carnot engine sets an upper limit to the efficiency of a practical heat engine. An arbitrary irreversible engine is sometimes believed to behave closely as the Curzon-Ahlborn engine. Efficiency of the latter is obtained commonly by…

Chemical Physics · Physics 2016-06-17 Kamal Bhattacharyya

Thermodynamic uncertainty relation, quantifying a trade-off among average current, the associated fluctuation (precision), and entropy production (cost), has been formulated in nonequilibrium steady state and various stochastic systems.…

Mesoscale and Nanoscale Physics · Physics 2022-03-31 Jincheng Lu , Zi Wang , Jiebin Peng , Chen Wang , Jian-Hua Jiang , Jie Ren

The optimal efficiency of quantum (or classical) heat engines whose heat baths are $n$-particle systems is given by the information geometry and the strong large deviation. We give the optimal work extraction process as a concrete…

Quantum Physics · Physics 2017-07-19 Hiroyasu Tajima , Masahito Hayashi

The performance of quantum heat engines is generally based on the analysis of a single cycle. We challenge this approach by showing that the total work performed by a quantum engine need not be proportional to the number of cycles.…

Statistical Mechanics · Physics 2017-02-08 Gentaro Watanabe , B. Prasanna Venkatesh , Peter Talkner , Adolfo del Campo

The derivation of general performance benchmarks is important in the design of highly optimized heat engines and refrigerators. To obtain them, one may model phenomenologically the leading sources of irreversibility ending up with results…

Quantum Physics · Physics 2015-01-06 Luis A. Correa , José P. Palao , Gerardo Adesso , Daniel Alonso

Developments in the thermodynamics of small quantum systems envisage non-classical thermal machines. In this scenario, energy fluctuations play a relevant role in the description of irreversibility. We experimentally implement a quantum…

We present a detailed thermodynamic analysis of a three-level quantum heat engine coupled continuously to hot and cold reservoirs. The system is driven by an oscillating external field and is described by the Markovian quantum master…

Quantum Physics · Physics 2021-10-07 Pablo Bayona-Pena , Kazutaka Takahashi

A long standing open problem whether a heat engine with finite power achieves the Carnot efficiency is investigated. We rigorously prove a general trade-off inequality on thermodynamic efficiency and time interval of a cyclic process with…

Statistical Mechanics · Physics 2017-08-18 Naoto Shiraishi , Hiroyasu Tajima

We derive a bound on the efficiency of thermal engines that can be sharper than Carnot's limit. It is a function of statistical correlations between the engine internal state and Hamiltonian, can be saturated even in finite-time cycles, and…

Quantum Physics · Physics 2026-04-14 Anna Gabetti , Fabrizio Dolcini , Davide Girolami

We study the stochastic energetic exchanges in quantum heat engines. Due to microreversibility, these obey a fluctuation relation, called the heat engine fluctuation relation, which implies the Carnot bound: no machine can have an…

Quantum Physics · Physics 2015-03-24 Michele Campisi , Jukka Pekola , Rosario Fazio

Given a quantum heat engine that operates in a cycle that reaches maximal efficiency for a time-dependent Hamiltonian H(t) of the working substance, with overall controllable driving H(t) = g(t) H, we study the deviation of the efficiency…

Giving a universal upper bound on the power output of heat engines is a long-standing open problem. We tackle this problem for generic quantum machines in self-contained formulation by carefully including the switching process of the…

Quantum Physics · Physics 2018-01-03 Kosuke Ito , Takayuki Miyadera

In a quantum Stirling heat engine, the heat exchanged with two thermal baths is partly utilized for performing work by redistributing the energy levels of the working substance. We analyze the thermodynamics of a quantum Stirling engine…

Quantum Physics · Physics 2023-08-01 Debmalya Das , George Thomas , Andrew N. Jordan

We study the maximum efficiency of a Carnot cycle heat engine based on a small system. It is revealed that due to the finiteness of the system, irreversibility may arise when the working substance contacts with a heat bath. As a result,…

Statistical Mechanics · Physics 2014-02-05 H. T. Quan