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Unravelling two-electron correlation is a long-standing challenge at the heart of few-body quantum physics, underlying correlated phenomena across atomic, molecular and condensed-matter science. In prototypical three-body Coulomb systems,…

We describe numerically the ionization process induced by linearly and circularly polarized XUV attosecond laser pulses on an aligned atomic target, specifically, the excited state…

Atomic Physics · Physics 2021-05-26 Juan J. Omiste , Lars Bojer Madsen

The attosecond, time-resolved X-ray double-quantum-coherence (XDQC) four wave mixing signals of formamide at the nitrogen and oxygen K-edges are simulated using restricted excitation window time-dependent density functional theory…

Atomic Physics · Physics 2015-06-15 Yu Zhang , Daniel Healion , Jason D. Biggs , Shaul Mukamel

When an electromagnetic field in a coherent or quasiclassical (e.g., squeezed) state is used to simultaneously drive an ensemble of two-level atoms, the quantum nature of the field will, in general, cause the final state of the atoms to…

Quantum Physics · Physics 2025-08-12 Hunter Lindemann , Shanon Vuglar , Julio Gea-Banacloche

We present the formulation and implementation of triples correction scheme to the relativistic equation-of-motion coupled-cluster method for ionization potential. Both full and partial triples correction schemes are implemented using the…

Chemical Physics · Physics 2026-03-31 Mrinal Thapa , Achinyta Kumar Dutta

The circular dichroism (CD) of photoelectrons generated by near-infrared (NIR) laser pulses using multiphoton ionization of excited He$^+$ ions in the 3p(m=+1) state. The ions were prepared by circularly polarized extreme ultraviolet (XUV)…

In this paper, we report on the implementation of the EOM spin-flip (SF), ionization-potential (IP) and electron-affinity (EA) coupled cluster singles doubles (CCSD) methods for atoms and molecules in strong magnetic fields for energies as…

Chemical Physics · Physics 2025-10-08 Marios-Petros Kitsaras , Florian Hampe , Lena Reimund , Stella Stopkowicz

Electron-initiated chemistry with chemically relevant electron energies (10-200 eV) is at the heart of several high-energy processes and phenomena. To probe these dissociation and fragmentation reactions with femtosecond resolution requires…

We report on a theoretical study of a Cs$_2$ molecule illuminated by two lasers and show how it can result in novel quantum dynamics. We reveal that these interactions facilitate the bypass of the non-crossing rule, forming Light-Induced…

Chemical Physics · Physics 2024-05-21 Edgar Barriga , Luis E. F. Foa Torres , Carlos Cárdenas

An ab initio analysis of strong-field three-electron ionization in a restricted-dimensionality model reveals the dynamics of the ionization process and the dominant channels for double (DI) and triple ionization (TI). Simulations using wave…

We present electric dipole polarizabilities ($\alpha_d$) of the alkali-metal negative ions, from H$^-$ to Fr$^-$, by employing four-component relativistic many-body methods. Differences in the results are shown by considering Dirac-Coulomb…

Atomic Physics · Physics 2021-01-07 B. K. Sahoo

We report the general implementation of the relativistic equation-of-motion coupled-cluster method to calculate double ionization spectra (DI-EOMCC) of atomic and molecular systems. As a first application, this method is employed to…

Atomic Physics · Physics 2014-08-25 Himadri Pathak , Aryya Ghosh , B. K. Sahoo , B. P. Das , Nayana Vaval , Sourav Pal

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Magnetization processes and phase transitions in a geometrically frustrated triangular lattice Ising antiferromagnet in the presence of an external magnetic field and a random site dilution are studied by the use of an effective-field…

Statistical Mechanics · Physics 2012-12-24 M. Žukovič , M. Borovský , A. Bobák

It was recently shown that the exact potential driving the electron's dynamics in enhanced ionization of H$_2^+$ can have large contributions arising from dynamical electron-nuclear correlation, going beyond what any electrostatics-based…

Atomic and Molecular Clusters · Physics 2017-06-07 E. Khosravi , A. Abedi , A. Rubio , N. T. Maitra

We study double ionization of He driven by a near-single-cycle laser pulse at low intensities at 400 nm. Using a three-dimensional semiclassical model, we identify the pathways that prevail non-sequential double ionization (NSDI). We focus…

Atomic Physics · Physics 2020-02-12 Georgios Petros Katsoulis , Agapi Emmanouilidou

Dielectric laser acceleration of electrons close to a fused-silica grating has recently been observed (Peralta et al., Nature 503, 91 (2013); Breuer, Hommelhoff, PRL 111, 134803 (2013)). Here we present the theoretical description of the…

Accelerator Physics · Physics 2015-06-22 John Breuer , Joshua McNeur , Peter Hommelhoff

We explore the laser-induced ionization dynamics of N2 and CO2 molecules subjected to a few-cycle, linearly polarized, 800\,nm laser pulse using effective two-dimensional single active electron time-dependent quantum simulations. We show…

Atomic Physics · Physics 2012-10-02 Michel Peters , Tung Nguyen-Dang , Eric Charron , Arne Keller , Osman Atabek

The dynamics of molecular electron excitation and ionisation is studied in real-time for ultra-short IR laser pulses of intensity I>10^{13} W/cm^{2}. The multi-electron molecule is modeled by a system of two active electrons moving in a…

Optics · Physics 2015-06-26 A. I. Pegarkov

There are major discrepancies between recent ICFT (Intermediate Coupling Frame Transformation) and DARC (Dirac Atomic R-matrix Code) calculations (Fern\'andez-Menchero et al. 2014, Astron. Astroph. 566 A104, Aggarwal et al. 2016 Mon. Not. R…

Atomic Physics · Physics 2017-03-10 L. Fernández-Menchero , O. Zatsarinny , K. Bartschat
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