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Chemical reactions on metal surfaces are important in various processes such as heterogeneous catalysis and nanostructure growth. At moderate or lower temperatures, these reactions generally follow the minimum energy path and temperature…

Chemical Physics · Physics 2022-01-19 Pai Li , Xiongzhi Zeng , Zhenyu Li

In this manuscript we present a computational study on the photoluminescence properties of several heteroleptic [Ru(H)(CO)(N^N)(tpp)2]+ complexes (tpp = triphenylphosphine). A special focus is set on disentangling the temperature-dependent…

Chemical Physics · Physics 2019-01-07 Denis Jacquemin , Daniel Escudero

We investigate plasmon resonances in gold nanoparticles to enhance the quantum yield of upconverting materials. For this purpose, we use a rate equation model that describes the upconversion of trivalent erbium based upconverters. Changes…

Significant photovoltages are observed in permalloy grating-like structures in response to pulsed laser light illumination. Electric signals are enhanced at plasmon resonance conditions and show a clear dependence on the magnetic field with…

Aerosol particles experience significant photophoretic forces at low pressure. Previous work assumed the average particle temperature to be very close to the gas temperature. This might not always be the case. If the particle temperature or…

Statistical Mechanics · Physics 2016-09-09 C. Loesche , G. Wurm , T. Jankowski , M. Kuepper

This paper is devoted to the modelization of the photoacoustic effect generated by the electromagnetic heating of metallic nanoparticles embedded in a biological tissue. We first derive an asymptotic models for the plasmonic resonances and…

Mathematical Physics · Physics 2017-01-24 Faouzi Triki , Margaux Vauthrin

Theoretical description of oscillations of electron liquid in large metallic nanospheres (with radius of few tens nm) is formulated within random-phase-approximation semiclassical scheme. Spectrum of plasmons is determined including both…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 W. Jacak , J. Krasnyj , J. Jacak , R. Gonczarek , A. Chepok , L. Jacak , D. Z. Hu , D. Schaadt

We analyze the mathematical model that describes the heat generated by electromagnetic nanoparticles. We use the known optical properties of the nanoparticles to control the support and amount of the heat needed around a nanoparticle.…

Analysis of PDEs · Mathematics 2022-06-10 Arpan Mukherjee , Mourad Sini

In a recent paper~[Nature Catalysis 3, 573 (2020)], Robatjazi {\em et al.} demonstrate hydrodefluorination on Al nanocrystals decorated by Pd islands under illumination and under external heating. They conclude that photocatalysis…

Chemical Physics · Physics 2021-05-14 Yonatan Dubi , Ieng Wai Un , Joshua H. Baraban , Yonatan Sivan

Interaction between plasmonic nanostructures and molecules is modeled based on the concept of quantized optical cavity for surface enhanced Raman scattering process. We have found that the background emission from plasmonic nanostructures…

Optics · Physics 2017-03-22 Yuqing Cheng , Jingyi Zhao , Te Wen , Guantao Li , Jianning Xu , Qihuang Gong , Guowei Lu

A novel theoretical approach to the dynamics analysis of excitation of plasmon modes in nanoparticles is presented. This approach is based on the biorthogonal plasmon mode expansion and it leads to the predictions of time-dynamics of…

Materials Science · Physics 2007-05-23 Isaak D. Mayergoyz , Zhenyu Zhang , Giovanni Miano

Electrically connected and plasmonically enhanced molecular junctions combine the optical functionalities of high field confinement and enhancement (cavity function), and of high radiative efficiency (antenna function) with the electrical…

Photoexcited hot carriers in solids can drive processes, such as photocatalytic reactions on the surface, beyond those available in thermal equilibrium. Hot-electron-mediated reaction pathways are limited by the thermalization of the…

Materials Science · Physics 2026-04-13 Christopher Seibel , Tobias Held , Markus Uehlein , Baerbel Rethfeld

The process of nuclear excitation by electron capture in plasma environments generated by the interaction of ultra-strong optical lasers with solid-state samples is investigated theoretically. With the help of a plasma model we perform a…

Plasma Physics · Physics 2018-06-20 Jonas Gunst , Yuanbin Wu , Christoph H. Keitel , Adriana Pálffy

Plasmas in which there is a threshold for a dominant reaction to take place (such as recombination or attachment) will have particle distributions that evolve as the reaction progresses. The form of the Boltzmann collision term in such a…

Plasma Physics · Physics 2008-10-13 D A Diver , L F A Teodoro , C S MacLachlan , H E Potts

We study the natural excitation of molecular systems, applicable to, for example, photosynthetic light-harvesting complexes, by natural incoherent light. In contrast with the conventional classical models, we show that the light need not…

Chemical Physics · Physics 2022-01-11 Aurélia Chenu , Paul Brumer

The interaction between electrons and plasmons in trilayer graphene is investigated within the Overhauser approach resulting in the 'plasmaron' quasi-particle. This interaction is cast into a field theoretical problem, nd its effect on the…

Mesoscale and Nanoscale Physics · Physics 2014-01-07 P. M. Krstajić , B. Van Duppen , F. M. Peeters

Thermally activated phenomena in physics and chemistry, such as conformational changes in biomolecules, liquid film rupture, or ferromagnetic field reversal, are often associated with exponentially long transition times described by…

Statistical Mechanics · Physics 2024-09-20 Jingbang Liu , James E. Sprittles , Tobias Grafke

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

Strong coupling between plasmons and excitons gives rise to new hybrid polariton states with various fields of potential applications. Despite a plethora of research on plasmon--exciton systems, their transient behaviour is not yet fully…

Optics · Physics 2023-06-13 Felix Stete , Matias Bargheer , Wouter Koopman
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