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Nanometer-sized clusters are often targeted due to their potential applications as nanoreactors or storage/delivery devices. One route to assemble and stabilize finite structures consists in imparting directional bonding patterns between…

Soft Condensed Matter · Physics 2024-06-13 Carlo Andrea De Filippo , Sara Del Galdo , Emanuela Bianchi , Cristiano De Michele , Barbara Capone

Building structures with hierarchical order through the self-assembly of smaller blocks is not only a prerogative of nature, but also a strategy to design artificial materials with tailored functions. We explore in simulation the…

Soft Condensed Matter · Physics 2020-02-17 Santi Prestipino , Domenico Gazzillo , Gianmarco Munaò , Dino Costa

Manipulating the way in which colloidal particles self-organise is a central challenge in the design of functional soft materials. Meeting this challenge requires the use of building blocks that interact with one another in a highly…

Soft Condensed Matter · Physics 2021-03-30 Joe G Donaldson , Peter Schall , Laura Rossi

We study the behavior of negatively charged colloids with two positively charged polar caps close to a planar patterned surface. The competition between the different anisotropic components of the particle-particle interaction patterns is…

Soft Condensed Matter · Physics 2018-09-25 Emanuele Locatelli , Emanuela Bianchi

The design of complex materials and the formation of specific patterns often arise from the properties of the individual building blocks. In this respect, colloidal systems offer a unique opportunity because nowadays they can be synthesized…

Soft Condensed Matter · Physics 2022-03-01 Fabrizio Camerin , Emanuela Zaccarelli

Conjugated polymers are complex multi-chromophore systems, with emission properties strongly dependent on the electronic energy transfer through active sub-units. Although the packing of the conjugated chains in the solid state is known to…

In recent years significant attention has been attracted to proposals which utilize DNA for nanotechnological applications. Potential applications of these ideas range from the programmable self-assembly of colloidal crystals, to biosensors…

Soft Condensed Matter · Physics 2008-05-02 Nicholas A. Licata

One of the challenges of self-assembling finite-sized colloidal aggregates with a sought morphology is the necessity of precisely sorting the position of the colloids at the microscopic scale to avoid the formation of off-target structures.…

Soft Condensed Matter · Physics 2020-01-31 Pritam Kumar Jana , Bortolo Matteo Mognetti

In this article, we study the phenomenology of a two dimensional dilute suspension of active amphiphilic Janus particles. We analyze how the morphology of the aggregates emerging from their self-assembly depends on the strength and the…

Soft Condensed Matter · Physics 2021-03-03 S. A. Mallory , F. Alarcon , A. Cacciuto , C. Valeriani

Anisotropy at the level of the inter-particle interaction provides the particles with specific instructions for the self-assembly of target structures. The ability to synthesize non-spherical colloids, together with the possibility of…

Soft Condensed Matter · Physics 2020-01-03 Carina Karner , Christoph Dellago , Emanuela Bianchi

Colloidal molecules are designed to mimic their molecular analogues through their anisotropic shape and interactions. However, current experimental realizations are missing the structural flexibility present in real molecules thereby…

Advances in synthetic methods have spawned an array of nanoparticles and bio-inspired molecules of diverse shapes and interaction geometries. Recent experiments indicate that such anisotropic particles exhibit a variety of 'nonclassical'…

Statistical Mechanics · Physics 2010-05-20 Stephen Whitelam

Colloidal particles are considered ideal building blocks to produce materials with enhanced physical properties. The state-of-the-art techniques for synthesizing these particles provide control over shape, size, and directionality of the…

Soft Condensed Matter · Physics 2016-12-21 N. A. M. Araújo , C. S. Dias , M. M. Telo da Gama

Hypothesis: Colloidal molecules with anisotropic shapes and interactions are powerful model systems for deciphering the behavior of real molecules and building units for creating materials with designed properties. While many strategies for…

Soft Condensed Matter · Physics 2022-07-19 Yogesh Shelke , Susana Marín-Aguilar , Fabrizio Camerin , Marjolein Dijkstra , Daniela J. Kraft

The miniaturization of machines towards the micron and nanoscales requires the development of joint-like elements that enable and constrain motion. We present a facile method to create colloidal joints, that is, anisotropic colloidal…

Soft Condensed Matter · Physics 2016-10-14 Indrani Chakraborty , Vera Meester , Casper van der Wel , Daniela J Kraft

The organization of nano-particles inside grafted polymer layers is governed by the interplay of polymer-induced entropic interactions and the action of externally applied fields. Earlier work had shown that strong external forces can drive…

Soft Condensed Matter · Physics 2016-08-04 Tine Curk , Francisco J. Martinez-Veracoechea , Daan Frenkel , Jure Dobnikar

We perform Brownian Dynamics (BD) simulations to explore the self-assembly of a two-dimensional model system of triblock Janus colloids as an example of "patchy" colloids forming complex structures. Previous experiments and simulation…

Soft Condensed Matter · Physics 2025-04-30 Juri Franz Schubert , Salman Fariz Navas , Sabine H. L. Klapp

Self-assembly of nanoparticles is an important tool in nanotechnology, with numerous applications including thin films, electronics, and drug delivery. We study the deposition of ionic nanoparticles on a glass substrate both experimentally…

Statistical Mechanics · Physics 2014-07-09 L. Jonathan Cook , D. A. Mazilu , I. Mazilu , B. M. Simpson , E. M. Schwen , V. O. Kim , A. M. Seredinski

A multicomponent mixture of Janus colloids with distinct catalytic coats and phoretic mobilities is a promising theoretical system to explore the collective behavior arising from nonreciprocal interactions. An active colloid produces (or…

Soft Condensed Matter · Physics 2024-02-15 Gennaro Tucci , Ramin Golestanian , Suropriya Saha

The self-assembly of binary nanoparticle superlattices from colloidal mixtures is a promising method for the fabrication of complex colloidal co-crystal structures. However, binary mixtures often form amorphous or metastable phases instead…

Soft Condensed Matter · Physics 2022-05-11 R. Allen LaCour , Timothy C. Moore , Sharon C. Glotzer