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The crystal structure, superconducting properties, and electronic structure of a novel superconducting 122-type antimonide, BaPt$_2$Sb$_2$, have been investigated by measurements of powder X-ray diffraction patterns, electrical resistivity,…

The iron arsenide RbFe_2As_2 with the ThCr_2Si_2-type structure is found to be a bulk superconductor with T_c=2.6 K. The onset of diamagnetism was used to estimate the upper critical field H_c2(T), resulting in dH_c2/dT=-1.4 T/K and an…

Superconductivity · Physics 2011-05-09 Z. Bukowski , S. Weyeneth , R. Puzniak , J. Karpinski , B. Batlogg

Neutron diffraction and high-resolution x-ray diffraction studies find that, similar to the closely related underdoped Ba(Fe[1-x]Cox)2As2 superconducting compounds, Ba(Fe0.961Rh0.039)2As2 shows strong evidence of competition and coexistence…

Single crystals of Ba_{1-x}Rb_{x}Fe_2As_2 with x=0.05-0.1 have been grown from Sn flux and are bulk superconductors with T_c up to 23 K. The crystal structure was determined by X-ray diffraction analysis, and Sn is found to be incorporated…

Superconductivity · Physics 2009-04-07 Z. Bukowski , S. Weyeneth , R. Puzniak , P. Moll , S. Katrych , N. D. Zhigadlo , J. Karpinski , H. Keller , B. Batlogg

Very recently (November, 2010, PRB, 82, 180520R) the first 122-like ternary superconductor KxFe2Se2 with enhanced TC ~ 31K has been discovered. This finding has stimulated much activity in search of related materials and triggered the…

Superconductivity · Physics 2015-05-27 I. R. Shein , A. L. Ivanovskii

The recently discovered LaFe2As2 superconducting compound, member of the 122 family of iron pnictide superconductors, becomes superconducting below Tc=13K, yet its nominal doping apparently places it in the extreme overdoped limit, where…

Superconductivity · Physics 2025-02-18 Ilaria Pallecchi , Akira Iyo , Hiraku Ogino , Marco Affronte , Marina Putti

We report the results of a systematic investigation of the phase diagram of the iron-based superconductor, Ba1-xKxFe2As2, from x = 0 to x = 1.0 using high resolution neutron and x-ray diffraction and magnetization measurements. The…

A new layered iron arsenide oxide (Fe2As2)(Ca4(Mg,Ti)3Oy) was discovered. Its crystal structure is tetragonal with a space group of I4/mmm consisted of the anti-fluorite type FeAs layer and blocking layer of triple perovskite cells and is…

FeSe-derived superconductors show some unique behaviors relative to iron-pnictide superconductors, which are very helpful to understand the mechanism of superconductivity in high-Tc iron-based superconductors. The low-energy electronic…

Superconductivity · Physics 2014-12-17 X. F. Lu , N. Z. Wang , H. Wu , Y. P. Wu , D. Zhao , X. Z. Zeng , X. G. Luo , T. Wu , W. Bao , G. H. Zhang , F. Q. Huang , Q. Z. Huang , X. H. Chen

Iron-based superconductors Ba0.7Rb0.3Fe2As2 and CaFe1.92Co0.08As2 of the '122' family have been investigated by means of the 14.41-keV Moessbauer transition in 57Fe versus temperature ranging from the room temperature till 4.2 K. A…

Superconductivity · Physics 2012-04-24 A. Blachowski , K. Ruebenbauer , J. Zukrowski , Z. Bukowski , M. Matusiak , J. Karpinski

By substituting Fe with the 5d-transition metal Pt in BaFe2As2, we have successfully synthesized the superconductors BaFe2-xPtxAs2. The systematic evolution of the lattice constants indicates that the Fe ions were successfully replaced by…

Superconductivity · Physics 2015-05-18 Xiyu Zhu , Fei Han , Gang Mu , Jun Tang , Jing Ju , Katsumi Tanigaki , Hai-Hu Wen

The transition metal nitride BaHfN$_2$, which consists of weakly bonded neutral slabs of closed shell ions, has structural and chemical similarities to other layered nitrides which have impressive superconducting T$_c$ when electron doped:…

Materials Science · Physics 2010-10-20 Amandeep Kaur , Erik R. Ylvisaker , Yan Li , Giulia Galli , Warren E. Pickett

The hole doped Fe-based superconductors Ba$_{1-x}$A$_x$Fe$_2$As$_2$ (where A=Na or K) show a particular rich phase diagram. It was observed that an intermediate re-entrant tetragonal phase forms within the orthorhombic…

Superconductivity · Physics 2016-03-23 Yan Zheng , Pok Man Tam , Jianqiang Hou , Anna E. Böhmer , Thomas Wolf , Christoph Meingast , Rolf Lortz

High energy electron irradiation is used to controllably introduce atomic-scale point defects into single crystalline Ba(Fe_1-xCo_x)_2As_2, Ba(Fe_1-xNi_x)_2As_2, and BaFe_2(As_1-xP_x)_2. The appearance of the collective pinning contribution…

We report a comprehensive study of the spin ladder compound BaFe$_2$S$_{2.5}$Se$_{0.5}$ using neutron diffraction, inelastic neutron scattering, high pressure synchrotron diffraction, and high pressure transport techniques. We find that…

We explore the structural, electronic, bonding, mechanical, thermodynamic and superconducting properties of two newly discovered isostructural bulk superconductors barium iridium phosphide BaIr2P2 (Tc ~ 2.1 K) and barium iridium arsenide…

Materials Science · Physics 2016-11-22 Md. Zahidur Rahaman , Md. Atikur Rahman

A new compound with a quasi-two-dimensional array of FeSe3O tetrahedra and an orthorombic structure, namely BaFe2Se2O, has been successfully fabricated. Experimental results show that this compound is an insulator and has an…

Strongly Correlated Electrons · Physics 2015-06-05 Fei Han , Xiangang Wan , Bing Shen , Hai-Hu Wen

We measured the static uniform spin susceptibility of Ba(Fe$_{1-x}$Rh$_x$)$_2$As$_2$ iron-based superconductors, over a broad range of doping ($0.041\leq x\leq 0.094$) and magnetic fields. At small fields ($H \le$ 1 kOe) we observed, above…

Superconductivity · Physics 2015-06-17 L. Bossoni , L. Romanò , P. C. Canfield , A. Lascialfari

RbFe2As2 has recently been reported to be a bulk superconductor with Tc = 2.6 K in the undoped state, in contrast to undoped BaFe2As2 with a magnetic ground state. We present here the results of the first-principles calculations of the…

Superconductivity · Physics 2015-05-14 M. Aftabuzzaman , A. K. M. A. Islam

We report an NMR investigation of the superconductivity in BaFe(2)As(2) induced by Co doping (Tc=22K). We demonstrate that Co atoms form an alloy with Fe atoms and donate carriers without creating localized moments. Our finding strongly…

Superconductivity · Physics 2008-10-03 F. L. Ning , K. Ahilan , T. Imai , A. S. Sefat , R. Jin , M. A. McGuire , B. C. Sales , D. Mandrus