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We present an implementation and analysis of a stochastic high performance algorithm to calculate the correlation energy of three dimensional periodic systems in second-order M{\o}ller-Plesset perturbation theory (MP2). In particular we…

Chemical Physics · Physics 2018-02-12 Tobias Schäfer , Benjamin Ramberger , Georg Kresse

Neural ordinary differential equations (neural ODEs) have emerged as a novel network architecture that bridges dynamical systems and deep learning. However, the gradient obtained with the continuous adjoint method in the vanilla neural ODE…

Machine Learning · Computer Science 2023-06-12 Hong Zhang , Wenjun Zhao

We present a measurement-cost efficient implementation of Strongly-Contracted $N$-Electron Valence Perturbation Theory (SC-NEVPT2) for use on near-term quantum devices. At the heart of our algorithm we exploit the properties of adaptive…

Quantum Physics · Physics 2024-05-27 Aaron Fitzpatrick , N. Walter Talarico , Roberto Di Remigio Eikås , Stefan Knecht

The amplitude-variation-with-offset inversion techniques are formulated to estimate elastic properties by fitting modeled seismic responses to observed data. Solving inverse seismic problems requires minimizing a target objective function…

Geophysics · Physics 2025-12-16 Wiktor Waldemar Weibull , Nisar Ahmed

We present a unified framework to analyze the global convergence of Langevin dynamics based algorithms for nonconvex finite-sum optimization with $n$ component functions. At the core of our analysis is a direct analysis of the ergodicity of…

Machine Learning · Statistics 2020-10-20 Pan Xu , Jinghui Chen , Difan Zou , Quanquan Gu

We present a stochastic approach to perform strongly contracted n-electron valence state perturbation theory (SC-NEVPT), which only requires one- and two-body reduced density matrices, without introducing approximations. We use this method…

Chemical Physics · Physics 2021-01-05 Nick S. Blunt , Ankit Mahajan , Sandeep Sharma

Several quantities important in condensed matter physics, quantum information, and quantum chemistry, as well as quantities required in meta-optimization of machine learning algorithms, can be expressed as gradients of implicitly defined…

Quantum Physics · Physics 2022-11-28 Shahnawaz Ahmed , Nathan Killoran , Juan Felipe Carrasquilla Álvarez

Stochastic gradient methods (SGMs) have been extensively used for solving stochastic problems or large-scale machine learning problems. Recent works employ various techniques to improve the convergence rate of SGMs for both convex and…

Optimization and Control · Mathematics 2022-05-02 Yangyang Xu , Yibo Xu

A new (algebraic) approximation scheme to find {\sl global} solutions of two point boundary value problems of ordinary differential equations (ODE's) is presented. The method is applicable for both linear and nonlinear (coupled) ODE's whose…

High Energy Physics - Theory · Physics 2008-11-26 Bruno Boisseau , Peter Forgacs , Hector Giacomini

Variance reduction techniques like SVRG provide simple and fast algorithms for optimizing a convex finite-sum objective. For nonconvex objectives, these techniques can also find a first-order stationary point (with small gradient). However,…

Machine Learning · Computer Science 2019-05-03 Rong Ge , Zhize Li , Weiyao Wang , Xiang Wang

We introduce a second-order numerical scheme for compressible atmospheric motions at small to planetary scales. The collocated finite volume method treats the advection of mass, momentum, and mass-weighted potential temperature in…

Numerical Analysis · Mathematics 2020-01-08 Tommaso Benacchio , Rupert Klein

We study stochastic nonconvex optimization under heavy-tailed noise. In this setting, the stochastic gradients only have bounded $p$-th central moment ($p$-BCM) for some $p \in (1,2]$. Building on the foundational work of Arjevani et al.…

Optimization and Control · Mathematics 2026-04-01 Adrien Fradin , Abdurakhmon Sadiev , Laurent Condat , Peter Richtárik

In this paper, we give a sharp analysis for Stochastic Gradient Descent (SGD) and prove that SGD is able to efficiently escape from saddle points and find an $(\epsilon, O(\epsilon^{0.5}))$-approximate second-order stationary point in…

Optimization and Control · Mathematics 2019-06-05 Cong Fang , Zhouchen Lin , Tong Zhang

In this paper, we investigate the problem of stochastic multi-level compositional optimization, where the objective function is a composition of multiple smooth but possibly non-convex functions. Existing methods for solving this problem…

Machine Learning · Computer Science 2022-10-20 Wei Jiang , Bokun Wang , Yibo Wang , Lijun Zhang , Tianbao Yang

In this paper, we study second-order algorithms for solving nonconvex-strongly concave minimax problems, which have attracted much attention in recent years in many fields, especially in machine learning.We propose a gradient norm…

Optimization and Control · Mathematics 2025-06-17 Jun-Lin Wang , Zi Xu

We propose a stochastic gradient descent approach with partitioned-truncated singular value decomposition for large-scale inverse problems of magnetic modulus data. Motivated by a uniqueness theorem in gravity inverse problem and realizing…

Numerical Analysis · Mathematics 2022-06-01 Wenbin Li , Kangzhi Wang , Tingting Fan

In this paper, we propose objective-function-free (OFF) variants of the proximal Newton method for nonconvex composite optimization problems and the regularized Newton method for unconstrained optimization problems, respectively, using…

Optimization and Control · Mathematics 2026-05-19 Hong Zhu

In this paper, we study a class of composite optimization problems whose objective function is given by the summation of a general smooth and nonsmooth component, together with a relatively simple nonsmooth term. While restart strategies…

Optimization and Control · Mathematics 2026-02-05 Xinming Wu , Zi Xu , Huiling Zhang

We consider the nonsmooth convex composition optimization problem where the objective is a composition of two finite-sum functions and analyze stochastic compositional variance reduced gradient (SCVRG) methods for them. SCVRG and its…

Optimization and Control · Mathematics 2019-08-01 Tianyi Lin , Chenyou Fan , Mengdi Wang

This paper deals with composite optimization problems having the objective function formed as the sum of two terms, one has Lipschitz continuous gradient along random subspaces and may be nonconvex and the second term is simple and…

Optimization and Control · Mathematics 2024-01-10 I. Necoara , F. Chorobura