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Targeting specific technological applications requires the control of nanoparticle properties, especially the crystalline polymorph. Freezing a nanodroplet deposited on a solid substrate leads to the formation of crystalline structures. We…

Soft Condensed Matter · Physics 2018-03-02 Julien Lam , James F. Lutsko

Manipulation of intrinsic magnetic and electronic structures of graphene nanoflakes is of technological importance. Here we carry out systematic study of the magnetic and electronic phases, and its manipulation in graphene nanoflakes…

Mesoscale and Nanoscale Physics · Physics 2017-10-05 Shreemoyee Ganguly , Mukul Kabir , Tanusri Saha-Dasgupta

Silicon nanowires grown along the <100>-direction with a bulk Si core are studied with density functional calculations. Two surface reconstructions prevail after exploration of a large fraction of the phase space of nanowire…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. Rurali , N. Lorente

We investigate the crystal structure, magnetic properties, and crystalline-electric field of tetragonal, $I4_1/amd$, NaCeO$_2$. In this compound, Ce$^{3+}$ ions form a tetragonally elongated diamond lattice coupled by antiferromagnetic…

Strongly Correlated Electrons · Physics 2021-01-26 Mitchell M. Bordelon , Joshua D. Bocarsly , Lorenzo Posthuma , Arnab Banerjee , Qiang Zhang , Stephen D. Wilson

This study details the conditions under which strong-coupling perturbation theory can be applied to the molecular crystal model, a fundamental theoretical tool for analysis of the polaron properties. I show that lattice dimensionality and…

Superconductivity · Physics 2009-10-31 marco zoli

The small polaron theory is applied to describe the vibron dynamics in an adsorbed nanowire with a special emphasis onto finite size effects. It is shown that the finite size of the nanowire discriminates between side molecules and core…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Cyril Falvo , Vincent J. C. Pouthier

Tuning the lattice degree of freedom in nanoscale functional crystals is critical to exploit the emerging functionalities such as piezoelectricity, shape-memory effect, or piezomagnetism, which are attributed to the intrinsic lattice-polar…

In contrast to bulk materials, nanoscale crystal growth is critically influenced by size- and shape-dependent properties. However, it is challenging to decipher how stoichiometry, in the realm of mixed-valence elements, can act to control…

Artificial perovskite-oxide nanostructures possess intriguing magnetic properties due to their tailorable electron-electron interactions, which are extremely sensitive to the oxygen coordination environment. To date, perovskite-oxide…

Materials Science · Physics 2022-02-09 Hongguang Wang , Gennadii Laskin , Weiwei He , Hans Boschker , Min Yi , Jochen Mannhart , Peter A. van Aken

Transition metal oxides such as \ce{BiVO4} are promising materials as photoelectrodes in solar-to-fuel conversion applications. However, their performance is limited by the low carrier mobility (especially electron mobility) due to the…

Materials Science · Physics 2019-04-09 Feng Wu , Yuan Ping

The layered structure of 2D metal halide perovskites (MHPs) consisting of an ionic metal halide octahedral layer electronically separated by an organic cation, exhibits strong coupling between high-binding-energy excitons and low-energy…

In this paper we report the structural and property (magnetic and electrical transport) measurements of nanocrystals of half-doped $\mathrm{La_{0.5}Ca_{0.5}MnO_3}$(LCMO) synthesized by chemical route, having particle size down to an average…

Strongly Correlated Electrons · Physics 2009-11-13 Tapati Sarkar , Barnali Ghosh , A. K. Raychaudhuri , Tapan Chatterji

Using optical spectroscopy, we investigated the electrodynamic properties of Nb:SrTiO3/SrTiO3 superlattices. In these superlattices, a large enhancement of the Seebeck coefficient (S) has been reported with decreasing Nb:SrTiO3 layer…

Strongly Correlated Electrons · Physics 2010-07-09 Woo Seok Choi , Hiromichi Ohta , Soon Jae Moon , Yun Sang Lee , Tae Won Noh

The formation of polarons is a pervasive phenomenon in transition metal oxide compounds, with a strong impact on the physical properties and functionalities of the hosting materials. In its original formulation the polaron problem considers…

Materials Science · Physics 2019-02-18 Michele Reticcioli , Ulrike Diebold , Georg Kresse , Cesare Franchini

We investigate the impact of OH- ions incorporation on the lattice strain and spontaneous polarization of BaTiO3 nanorods synthesized under different conditions. It was confirmed that the lattice strain depends directly on Ba…

The realization of multiferroicity in 2D nanomaterials is crucially important for designing advanced nanoelectronic devices such as non-volatile multistate data storage. In this work, the coexistence of ferromagnetism and ferroelectricity…

Materials Science · Physics 2019-11-12 Yanyu Liu , Wei Zhou , Gang Tang , Chao Yang , Xueyun Wang , Jiawang Hong

The electronic structure of Li-doped Ni$_{1-x}$Fe$_x$O has been investigated using photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). The Ni $2p$ core-level PES and XAS spectra were not changed by Li doping. In…

We employ magnetic small-angle neutron scattering to investigate the magnetic interactions in $(Fe_{0.7}Ni_{0.3})_{86}B_{14}$ alloy, a HiB-NANOPERM-type soft magnetic nanocrystalline material, which exhibits an ultrafine microstructure with…

Iron-substitution in hexagonal YMnO3 causes isostructural intra-lattice changes exceeding those of the lattice cell, contrary to the effects of non-magnetic B-site dopants. Magnetization M(T) evidence antiferromagnetic (AFM) ordering of the…

Strongly Correlated Electrons · Physics 2014-09-23 Sonu Namdeo , A. M. Awasthi

Harnessing electronic excitations involving coherent coupling to bosonic modes is essential for the design and control of emergent phenomena in quantum materials [1]. In situations where charge carriers induce a lattice distortion due to…