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Related papers: UKRmol+: a suite for modelling of electronic proce…

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UKRmol-scripts is a set of Perl scripts to automatically run the UKRmol+ codes, a complex software suite based on the R-matrix method to calculate fixed-nuclei photoionization and electron- and positron-scattering for polyatomic molecules.…

We present a new extension of the UKRmol electron-molecule scattering code suite, which allows one to compute ab initio photoionization and photorecombination amplitudes for complex molecules, resolved both on the molecular alignment…

Chemical Physics · Physics 2014-02-18 Alex G Harvey , Danilo S Brambila , Felipe Morales , Olga Smirnova

Implementation of Effective Core Potentials (ECPs) into the molecular scattering suite UKRmol+ is presented together with a set of calculations for a range of targets relevant for plasma modeling. Continuum description in scattering and…

Transition matrix elements between electronic states where one electron can be in the continuum are required for a wide range of applications of the molecular R-matrix method. These include photoionization, photorecombination and…

Chemical Physics · Physics 2014-01-03 Alex G. Harvey , Danilo S. Brambila , Felipe Morales , Olga Smirnova

Electron-molecule collisions play a central role in both natural processes and modern technological applications, particularly in plasma processing. Conventional computational strategies such as the R-matrix method have been widely adopted…

Quantum Physics · Physics 2026-05-13 Dario Picozzi , Jonathan Tennyson , Vincent Graves , Jimena D. Gorfinkiel

Techniques for producing cold and ultracold molecules are enabling the study of chemical reactions and scattering at the quantum scattering limit, with only a few partial waves contributing to the incident channel, leading to the…

Chemical Physics · Physics 2016-09-21 Jonathan Tennyson , Laura K. McKemmish , Tom Rivlin

The R-matrix method is a fully-quantum time-independent scattering method, used to simulate nuclear, electron-atom, electron-ion, electron-molecule scattering and more. Here, a novel R-matrix method, RmatReact, is presented as applied to…

Chemical Physics · Physics 2019-12-20 T. Rivlin , L. K. McKemmish , K. E. Spinlove , J. Tennyson

The present study presents a comprehensive theoretical investigation of atom and asymmetric top molecule inelastic scattering based on the R-matrix formalism. The proposed methodology establishes a rigorous framework for treating inelastic…

The R-matrix method has been used for theoretical calculation of electron collision with atoms and molecules for long years. The method was also formulated to treat photoionization process, however, its application has been mostly limited…

Chemical Physics · Physics 2010-04-08 Motomichi Tashiro

Links between two well known methods: methods of zero-range and non-overlapped (muffin-tin) potentials are discussed. Some difficulties of the method of zero-range potentials and its possible elimination are discussed. We argue that such…

Quantum Physics · Physics 2009-11-13 Sergey Yalunin , Sergey B. Leble

Calculations are performed for electron collision with the methylene molecular ion CH$_2^+$ in its bent equilibrium geometry, with the goal to obtain cross sections for electron impact excitation and dissociation. The polyatomic version of…

Plasma Physics · Physics 2024-05-22 K. Chakrabarti , J. Zs Mezei , I. F. Schneider , J. Tennyson

A scattering model is developed for ultracold molecular collisions, which allows inelastic processes, chemical reactions, and complex formation to be treated in a unified way. All these scattering processes and various combinations of them…

Atomic Physics · Physics 2020-09-23 James F. E. Croft , John L. Bohn , Goulven Quéméner

Accurately modelling cold and ultracold reactive collisions occuring over deep potential wells, such as \ce{D+ + H2 -> H+ + HD}, requires the development of new theoretical and computational methodologies. One potentially useful framework…

Chemical Physics · Physics 2019-02-08 Laura K. McKemmish , Jonathan Tennyson

Recent developments in deep learning have made remarkable progress in speeding up the prediction of quantum chemical (QC) properties by removing the need for expensive electronic structure calculations like density functional theory.…

Chemical Physics · Physics 2023-07-10 Shuqi Lu , Zhifeng Gao , Di He , Linfeng Zhang , Guolin Ke

Multiple scattering theory is applied to low-energy electron collisions with a complex target formed of two molecular scatterers. The total T-matrix is expressed in terms of the T-matrix for each isolated molecule. We apply the approach to…

Chemical Physics · Physics 2009-11-13 D. Bouchiha , L. G. Caron , J. D. Gorfinkiel , L. Sanche

Advanced computational tools that describe the interaction of electrons with structured nanophotonic materials are crucial for theoretical predictions, specific design tasks, and the interpretation of experimental results. These tools open…

Computational Physics · Physics 2026-02-16 P. Elli Stamatopoulou , Carsten Rockstuhl

The Complex Kohn variational method for electron-polyatomic molecule scattering is formulated using an overset grid representation of the scattering wave function. The overset grid consists of a central grid and multiple dense,…

Chemical Physics · Physics 2017-12-06 Loren Greenman , Robert R. Lucchese , C. William McCurdy

Electromagnetic scattering and absorption by material particles is a fundamental physical problem with a broad range of applications, going from laboratory experiments, biology and material sciences, all the way up to environmental studies…

Instrumentation and Methods for Astrophysics · Physics 2026-02-06 G. La Mura , G. Mulas , G. Aresu , M. A. Iatì , C. Cecchi-Pestellini , S. Rezaei , R. Saija

The multiple scattering method T-matrix (MSTMM) can be used to solve the electromagnetic response of systems consisting of many compact scatterers, retaining a good level of accuracy while using relatively few degrees of freedom, largely…

Optics · Physics 2021-06-16 Marek Nečada , Päivi Törmä

Ring polymer molecular dynamics (RPMD) is used to directly simulate the dynamics of an excess electron in a supercritical fluid over a broad range of densities. The accuracy of the RPMD model is tested against numerically exact path…

Statistical Mechanics · Physics 2011-07-27 Thomas F. Miller
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