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Ultracold polar molecules can be shielded from fast collisional losses using microwaves, but achieving the required polarization purity is technically challenging. Here, we propose a scheme for shielding using microwaves with polarization…

Quantum Physics · Physics 2020-04-15 Tijs Karman

We use microwaves to engineer repulsive long-range interactions between ultracold polar molecules. The resulting shielding suppresses various loss mechanisms and provides large elastic cross sections. Hyperfine interactions limit the…

Atomic Physics · Physics 2018-10-24 Tijs Karman , Jeremy M. Hutson

Harnessing the potential wide-ranging quantum science applications of molecules will require control of their interactions. Here, we use microwave radiation to directly engineer and tune the interaction potentials between ultracold calcium…

We develop double microwave shielding, which has recently enabled evaporative cooling to the first Bose-Einstein condensate of polar molecules [Bigagli et al., Nature 631, 289 (2024)]. Two microwave fields of different frequency and…

Quantum Gases · Physics 2026-03-13 Tijs Karman , Niccolò Bigagli , Weijun Yuan , Siwei Zhang , Ian Stevenson , Sebastian Will

The collisions between linear polar molecules, trapped in a microwave field with circular polarization, are theoretically analyzed. The microwave trap suggested by DeMille \cite{DeMille} seems to be rather advantageous in comparison with…

Atomic Physics · Physics 2015-05-13 Alexander V. Avdeenkov

We discuss the possibility of trapping polar molecules in the standing-wave electromagnetic field of a microwave resonant cavity. Such a trap has several novel features that make it very attractive for the development of ultracold molecule…

Atomic Physics · Physics 2009-11-10 D. DeMille , D. R. Glenn , J. Petricka

We propose and analyze a technique that allows to suppress inelastic collisions and simultaneously enhance elastic interactions between cold polar molecules. The main idea is to cancel the leading dipole-dipole interaction with a suitable…

Statistical Mechanics · Physics 2008-09-29 A. V. Gorshkov , P. Rabl , G. Pupillo , A. Micheli , P. Zoller , M. D. Lukin , H. P. Büchler

Microwave shielding is an important technique that can suppress the losses that arise from collisions of ultracold polar molecules. It has been instrumental in achieving molecular Bose-Einstein condensation (BEC) for NaCs [Bigagli et al.,…

Quantum Gases · Physics 2025-05-07 Joy Dutta , Bijit Mukherjee , Jeremy M. Hutson

The ability to tune interparticle interactions is one of the main advantages of using ultracold quantum gases for quantum simulation of many-body physics. Current experiments with ultracold polar molecules employ shielding with microwave or…

Quantum Gases · Physics 2026-03-24 Christopher J. Ho , Joy Dutta , Bijit Mukherjee , Jeremy M. Hutson , Michael R. Tarbutt

We propose a method to engineer repulsive long-range interactions between ultracold ground-state molecules using optical fields, thus preventing short-range collisional losses. It maps the microwave coupling recently used for collisional…

Ultracold polar molecules with microwave shielding provide a powerful platform for exploring quantum many-body physics with strong, anisotropic interactions. We develop an extended Gross-Pitaevskii framework for bosonic molecules under…

Quantum Gases · Physics 2025-10-20 Tiziano Arnone Cardinale , Thomas Bland , Stephanie M. Reimann

The prospects for shielding ultracold, paramagnetic, dipolar molecules from inelastic and chemical collisions are investigated. Molecules placed in their first rotationally excited states are found to exhibit effective long-range repulsion…

Atomic Physics · Physics 2016-01-20 Goulven Quéméner , John L. Bohn

Ultracold polar molecules offer strong electric dipole moments and rich internal structure, which makes them ideal building blocks to explore exotic quantum matter, implement novel quantum information schemes, or test fundamental symmetries…

Recent years have witnessed tremendous progresses in creating and manipulating ground-state ultracold polar molecules. However, the two-body loss regardless of the chemical reactivities is still a hurdle for many future explorations. Here,…

We investigate the effective potential and scattering length of ultracold polar molecules under different shielding techniques. First, we derive the effective potential for two polar molecules in the presence of an elliptical polarization…

Quantum Gases · Physics 2025-05-29 Peng Xu , Gang Chen

Quantum gases of ultracold polar molecules have novel properties because of the strong dipolar forces between molecules. Current experiments shield the molecules from destructive collisions by engineering long-range repulsive interactions…

Quantum Gases · Physics 2025-09-26 Bijit Mukherjee , Luis Santos , Jeremy M. Hutson

We study collisions of ultracold CaF molecules in strong static electric fields. These fields allow the creation of long-range barriers in the interaction potential, effectively preventing the molecules from reaching the short-range region…

We have demonstrated microwave-assisted coherent control of ultracold $^{85}$Rb$^{133}$Cs molecules with a ladder-type configuration of rotational states. A probe microwave (MW) field is used to couple a lower state $X^1\Sigma^+(v=0, J=1)$…

Atomic Physics · Physics 2021-03-16 Ting Gong , Zhonghua Ji , Jiaqi Du , Yanting Zhao , Liantuan Xiao , Suotang Jia

We calculate the microwave spectra of ultracold KRb alkali metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between…

Chemical Physics · Physics 2015-05-13 J. Aldegunde , Hong Ran , Jeremy M. Hutson

We study anisotropic thermalization in dilute gases of microwave shielded polar molecular fermions. For collision energies above the threshold regime, we find that thermalization is suppressed due to a strong preference for forward…

Quantum Gases · Physics 2023-11-14 Reuben R. W. Wang , John L. Bohn
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