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When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…

Statistical Mechanics · Physics 2009-05-12 Andrea Cavagna

We studied the effect of hydrostatic pressure (P) on the structural phase transitions and superconductivity in the ternary and pseudo-ternary iron arsenides CaFe2As2, BaFe2As2, and (Ba0.55K0.45)Fe2As2, by means of measurements of electrical…

Superconductivity · Physics 2015-05-13 M. S. Torikachvili , S. L. Budko , Ni Ni , P. C. Canfield

Studies of the behaviour of solids at ultra-high pressures, those beyond 200 GPa, contribute to our fundamental understanding of materials properties and allow an insight into the processes happening at such extreme conditions relevant for…

Hydrogen exhibits unusual behaviors at megabar pressures, with consequences for planetary science, condensed matter physics and materials science. Experiments at such extreme conditions are challenging, often resulting in hard-to-interpret…

Materials Science · Physics 2022-01-05 Bingqing Cheng , Guglielmo Mazzola , Michele Ceriotti

We study the solid-to-liquid transition in a two-dimensional fully periodic soft-glassy model with an imposed spatially heterogeneous stress. The model we consider consists of droplets of a dispersed phase jammed together in a continuous…

Soft Condensed Matter · Physics 2018-06-06 Matteo Lulli , Roberto Benzi , Mauro Sbragaglia

Low-temperature (below 60K) phase changes of free clusters containing 50, 137, and 229 methane molecules have been observed in isoenergetic Molecular Dynamics computations. Bulk solid methane exhibits structural phase transformation at 20.4…

Atomic and Molecular Clusters · Physics 2007-05-23 E. Daykova , Ana Proykova

We theoretically investigate the temperature dependence of the reversible structural relaxation time and diffusion constant of metallic glasses under pressure. The compression not only changes the glassy dynamics, but also generates a…

Materials Science · Physics 2021-05-28 Nguyen K. Ngan , Anh D. Phan , Alessio Zaccone

We report experimental evidence for pressure instabilities in the model multiferroic BiFeO3 and namely reveal two structural phase transitions around 3 GPa and 10 GPa by using diffraction and far-infrared spectroscopy at a synchrotron…

Materials Science · Physics 2011-07-26 R. Haumont , P. Bouvier , A. Pashkin , K. Rabia , S. Frank , B. Dkhil , W. A. Crichton , C. A. Kuntscher , J. Kreisel

In this paper, we revisit the high-pressure behavior of BaZrO3 by a combination of first-principle calculations, Raman spectroscopy, and x-ray diffraction under high pressure. We confirm experimentally the cubic-to-tetragonal transition at…

We investigated numerically the high-temperature/high-pressure phase diagram of Xenon as modelled through the exp-6 interaction potential, which is thought to provide a reliable description of the thermal behaviour of rare gases under…

Materials Science · Physics 2007-05-23 Franz Saija , Santi Prestipino

By confining water in nano-pores of silica glass, we can bypass the crystallization and study the pressure effect on the dynamical behavior in deeply supercooled state using neutron scattering. We observe a clear evidence of a cusp-like…

Soft Condensed Matter · Physics 2009-11-11 Li Liu , Sow-Hsin Chen , Antonio Faraone , Chun-Wan Yen , Chung-Yuan Mou

Nitrogen oxides are textbook class of molecular compounds, with extensive industrial applications. Nitrogen and oxygen are also among the most abundant elements in the universe. We explore the N-O system at 0 K and up to 500 GPa though ab…

Materials Science · Physics 2015-06-30 Dongxu Li , Artem R. Oganov , Xiao Dong , Xiang-Feng Zhou , Qiang Zhu , Guangrui Qian , Huafeng Dong

We develop a Bose fluid model in a confined potential to consider the new quantum phase due to the localization of Bose-Einstein condensation and disappearance of superfluidity which is recently observed in liquid 4He in porous glass at…

Disordered Systems and Neural Networks · Physics 2009-11-11 Michikazu Kobayashi , Makoto Tsubota

Simple classical thermodynamic approach to the general description of metastable states is presented. It makes possible to calculate the explicit dependence of the Gibbs free energy on temperature, to calculate the heat capacity, the…

Materials Science · Physics 2007-05-23 Yuri Kornyushin

Uranium ditelluride (UTe$_2$) has attracted recent interest due to its unique superconducting properties, which include the potential for a topological odd-parity superconducting state. Recently, ac-calorimetry measurements under pressure…

The crystal structure of the thermoelectric material tin selenide has been investigated with angle-dispersive synchrotron x-ray powder diffraction under hydrostatic pressure up to 27 GPa. With increasing pressure, a continuous evolution of…

Materials Science · Physics 2015-04-03 I Loa , R J Husband , R A Downie , S R Popuri , J-W G Bos

Metallic hydrogen is expected to exhibit remarkable physics. Examples include high-temperature superconductivity and possible novel types of quantum fluids. These could have revolutionary practical applications. The pressures required to…

Materials Science · Physics 2017-05-16 Craig M. Tenney , Keeper L. Sharkey , Jeffrey M. McMahon

The structure of solid oxygen has been studied at pressures from 50 to 140~GPa using static structure search methods and molecular dynamics simulations with density functional theory and a hybrid exchange functional. Several crystalline…

Materials Science · Physics 2023-09-26 Sabri F. Elatresh , V. Askarpour , S. A. Bonev

We report the results of the X-ray diffraction study of B2O3 glass in the pressure interval up to 10 GPa in the 300-700 K temperature range, the results of in-situ volumetric measurements of the glass at pressures up to 9 GPa at room…

Disordered Systems and Neural Networks · Physics 2008-07-19 V. V. Brazhkin , Y. Katayama , K. Trachenko , O. B. Tsiok , A. G. Lyapin , Emilio Artacho , M. Dove , G. Ferlat , Y. Inamura , H. Saitoh

The wide range of applications using metastable noble gas atoms has led to a number of different approaches for producing large metastable state densities. Here we investigate a recently proposed hybrid approach that combines RF discharge…

Optics · Physics 2020-08-26 H. P. Lamsal , J. D. Franson , T. B. Pittman