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We investigate the quality of hydrogen plasma defined graphene edges by Raman spectroscopy, atomic resolution AFM and low temperature electronic transport measurements. The exposure of graphite samples to a remote hydrogen plasma leads to…

Electronic and magnetic properties of ribbon-shaped nanographite systems with zigzag and armchair edges in a magnetic field are investigated by using a tight binding model. One of the most remarkable features of these systems is the…

Materials Science · Physics 2016-08-31 Katsunori Wakabayashi , Mitsutaka Fujita , Hiroshi Ajiki , Manfred Sigrist

Graphene is attracting vast interest due to its superior electronic and mechanical properties. However, structure and electronic properties of its edge are often neglected, although they are important for nanoscale devices because the edge…

Mesoscale and Nanoscale Physics · Physics 2022-08-25 Takamoto Yokosawa , Masahiro Kamada , Taisuke Ochi , Yuki Koga , Rin Takehara , Masahiro Hara , Tomohiro Matsui

Catalytic hydrogenation of graphite has recently attracted renewed attention, as a route for nano-patterning of graphene and to produce graphene nano-ribbons. These reports show that metallic nanoparticles etch surface layers of graphite,…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Maya Lukas , Velimir Meded , Aravind Vijayaraghavan , Li Song , Pulickel M. Ajayan , Karin Fink , Wolfgang Wenzel , Ralph Krupke

We investigate the etching of a pure hydrogen plasma on graphite samples and graphene flakes on SiO$_2$ and hexagonal Boron-Nitride (hBN) substrates. The pressure and distance dependence of the graphite exposure experiments reveals the…

Zigzag edges of graphene nanostructures host localized electronic states that are predicted to be spin-polarized. However, these edge states are highly susceptible to edge roughness and interaction with a supporting substrate, complicating…

The presence of structure-dependent edge states of graphite is revealed by both ambient- and ultra-highvacuum- (UHV) scanning tunneling microscopy (STM) / scanning tunneling spectroscopy (STS) observations. On a hydrogenated zigzag…

Materials Science · Physics 2009-11-11 Yousuke Kobayashi , Ken-ichi Fukui , Toshiaki Enoki , Koichi Kusakabe , Yutaka Kaburagi

The edges of graphene nanoribbons (GNRs) have attracted much interest due to their potentially strong influence on GNR electronic and magnetic properties. Here we report the ability to engineer the microscopic edge termination of high…

Single layer graphene islands with a typical diameter of several nanometers were grown on a Pt (111) substrate. Scanning tunneling microscopy (STM) analysis showed most of islands are hexagonally shaped and the zigzag-type edge predominates…

Mesoscale and Nanoscale Physics · Physics 2011-01-21 Mayu Yamamoto , Seiji Obata , Koichiro Saiki

The edge states that emerge at hydrogen-terminated zigzag edges embedded in dominant armchair edges of graphite are carefully investigated by ultrahigh-vacuum scanning tunneling microscopy (STM) measurements. The edge states at the zigzag…

Materials Science · Physics 2009-11-11 Yousuke Kobayashi , Ken-ichi Fukui , Toshiaki Enoki , Koichi Kusakabe

Graphene-based nanostructures exhibit a vast range of exciting electronic properties that are absent in extended graphene. For example, quantum confinement in carbon nanotubes and armchair graphene nanoribbons (AGNRs) leads to the opening…

Effects of electron-electron and spin-orbit interactions on the ground-state magnetic configuration and on the corresponding thermoelectric and spin thermoelectric properties in zigzag nanoribbons of two-dimensional hexagonal crystals are…

Mesoscale and Nanoscale Physics · Physics 2015-12-09 Michal Wierzbicki , Jozef Barnas , Renata Swirkowicz

The electric-field effect on the electronic and magnetic properties of triangular and hexagonal graphene quantum rings with zigzag edge termination is investigated by means of the single-band tight-binding Hamiltonian and the mean-field…

Mesoscale and Nanoscale Physics · Physics 2014-08-29 R. Farghadan , A. Saffarzadeh

Edge engineering is important for both fundamental research and applications as the device size decreases to nanometer scale. This is especially the case for graphene because a graphene edge shows totally different electronic properties…

Mesoscale and Nanoscale Physics · Physics 2022-12-14 Taisuke Ochi , Masahiro Kamada , Takamoto Yokosawa , Kozo Mukai , Jun Yoshinobu , Tomohiro Matsui

Electronic band structures in hydrogenated graphene are theoretically investigated by means of first-principle calculations and an effective tight-binding model. It is shown that regularly designed hydrogenation to graphene gives rise to a…

Mesoscale and Nanoscale Physics · Physics 2024-08-05 Yong-Cheng Jiang , Toshikaze Kariyado , Xiao Hu

We explore possible ways to manipulate the intrinsic edge magnetism in hexagonal graphene nanoflake with zigzag edges, using density functional theory supplemented with on-site Coulomb interaction. The effect of carrier doping, chemical…

Mesoscale and Nanoscale Physics · Physics 2014-07-08 Mukul Kabir , T. Saha-Dasgupta

Zigzag edges of graphene have long been predicted to exhibit magnetic electronic state near the Fermi level, which can cause spin-related phenomena and offer unique potentials for graphene-based spintronics. However, the magnetic conduction…

We examine the electronic structure of recently fabricated in-plane heterojunctions of zigzag graphene nanoribbons embedded in hexagonal boron nitride. We focus on hitherto unexplored interface configurations in which both edges of the…

Mesoscale and Nanoscale Physics · Physics 2024-06-03 Michele Pizzochero , Nikita V. Tepliakov , Johannes Lischner , Arash A. Mostofi , Efthimios Kaxiras

Edge states are ubiquitous for many condensed matter systems with multicomponent wave functions. For example, edge states play a crucial role in transport in zigzag graphene nanoribbons. Here, we report microscopic calculations of quantum…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 Thomas Christensen , Weihua Wang , Antti-Pekka Jauho , Martijn Wubs , N. Asger Mortensen

We demonstrate anisotropic etching of single-layer graphene by thermally-activated nickel nanoparticles. Using this technique, we obtain sub-10nm nanoribbons and other graphene nanostructures with edges aligned along a single…

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