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Wave-function methods have offered a robust, systematically improvable means to study ground-state properties in quantum many-body systems. Theories like coupled cluster and their derivatives provide highly accurate approximations to the…

Strongly Correlated Electrons · Physics 2023-05-10 Gaurav Harsha , Thomas M. Henderson , Gustavo E. Scuseria

We develop the variational-cluster-approximation method based on the thermal-pure-quantum-state approach and apply the method to the calculations of the thermodynamic properties of the Hubbard model, thereby obtaining the temperature…

Strongly Correlated Electrons · Physics 2020-02-19 Hisao Nishida , Ryo Fujiuchi , Koudai Sugimoto , Yukinori Ohta

Thermofield dynamics has proven to be a very useful theory in high-energy physics, particularly since it permits the treatment of both time- and temperature-dependence on an equal footing. We here show that it also has an excellent…

Chemical Physics · Physics 2020-05-14 Gaurav Harsha , Thomas M. Henderson , Gustavo E. Scuseria

Current methods to describe the thermodynamic behavior of many-particle systems are often based on perturbation theory with an unperturbed system consisting of free particles. Therefore, only a few methods are able to describe both strongly…

Strongly Correlated Electrons · Physics 2009-10-30 Holger Koehler , Matthias Vojta , Klaus W. Becker

We extend the coupled-cluster method to correlated quantum dynamics of both closed and open systems at finite temperatures using the thermo-field formalism. The approach expresses the time-dependent density matrix in an exponential ansatz…

Quantum Physics · Physics 2019-10-23 Philip Shushkov , Thomas F. Miller

We develop analytical and numerical methods for the matrix thermofield in the large $N$ limit. Through the double collective representation on the Schwinger-Keldysh contour, it provides thermodynamical properties and finite temperature…

High Energy Physics - Theory · Physics 2025-10-02 Antal Jevicki , Xianlong Liu , Junjie Zheng

We leverage the Keldysh formalism to extend our implementation of finite temperature coupled cluster theory [\textit{J. Chem. Theory Comput.} 2018, \textit{14}, 5690-5700] to thermal systems that have been driven out of equilibrium. The…

Statistical Mechanics · Physics 2019-07-29 Alec F. White , Garnet Kin-Lic Chan

Coupled cluster (CC) has established itself as a powerful theory to study correlated quantum many-body systems. Finite-temperature generalizations of CC theory have attracted considerable interest and have been shown to work as nicely as…

Strongly Correlated Electrons · Physics 2022-02-02 Gaurav Harsha , Yi Xu , Thomas M. Henderson , Gustavo E. Scuseria

We consider a thermofield approach to analyze the evolution of an open quantum system coupled to an environment at finite temperature. In this approach, the finite temperature environment is exactly mapped onto two virtual environments at…

Quantum Physics · Physics 2015-11-25 Ines de Vega , Mari-Carmen Bañuls

The recent advancement of quantum computer hardware offers the potential to simulate quantum many-body systems beyond the capability of its classical counterparts. However, most current works focus on simulating the ground-state properties…

Quantum Physics · Physics 2022-06-14 Chee Kong Lee , Shi-Xin Zhang , Chang-Yu Hsieh , Shengyu Zhang , Liang Shi

At zero temperature coupled cluster theory is widely used to predict total energies, ground state expectation values and even excited states for molecules and extended systems. Generalizations to finite temperature exist, however, they are…

Materials Science · Physics 2019-11-21 Felix Hummel

We discuss the theory and implementation of the finite temperature coupled cluster singles and doubles (FT-CCSD) method including the equations necessary for an efficient implementation of response properties. Numerical aspects of the…

Chemical Physics · Physics 2021-07-07 Alec F. White , Garnet Kin-Lic Chan

We present a time-dependent formulation of coupled cluster theory. This theory allows for direct computation of the free energy of quantum systems at finite temperature by imaginary time integration and is closely related to the thermal…

Chemical Physics · Physics 2019-03-21 Alec F. White , Garnet Chan

The clustering property of an equilibrium bipartite correlation is one of the most general thermodynamic properties in non-critical many-body quantum systems. Herein, we consider the thermalization properties of a system class exhibiting…

Statistical Mechanics · Physics 2020-05-27 Tomotaka Kuwahara , Keiji Saito

The real-time operator formalism for thermal quantum field theories, thermofield dynamics, is formulated in terms of a path-integral approach in non-commutative spaces. As an application, the two-point function for a thermal non-commutative…

High Energy Physics - Theory · Physics 2015-05-18 Marcelo L. Costa , Amilcar R. Queiroz , Ademir E. Santana

The formalism developed in the first paper of the series [arXiv:0901.1060] is applied to two thermodynamic systems: (i) of three global observables (the energy, the total electron number and the spin number), (ii) of one global observable…

Chemical Physics · Physics 2013-10-28 Robert Balawender , Andrzej Holas

A finite-temperature many-body perturbation theory is presented that expands in power series the electronic grand potential, chemical potential, internal energy, and entropy on an equal footing. Sum-over-states and sum-over-orbitals…

Chemical Physics · Physics 2020-07-15 So Hirata , Punit K. Jha

Understanding the thermodynamic properties of many-body quantum systems and their emergence from microscopic laws is a topic of great significance due to its profound fundamental implications and extensive practical applications. Recent…

Quantum Physics · Physics 2024-09-05 Antonio Palamara , Francesco Plastina , Antonello Sindona , Irene D'Amico

We introduce a thermofield-based formulation of the multilayer multiconfigurational time-dependent Hartree (ML-MCTDH) method to study finite temperature effects on non-adiabatic quantum dynamics from a non-stochastic, wave-function…

Chemical Physics · Physics 2021-10-07 Eric W. Fischer , Peter Saalfrank

The preparation of thermal equilibrium states is important for the simulation of condensed-matter and cosmology systems using a quantum computer. We present a method to prepare such mixed states with unitary operators, and demonstrate this…

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