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Understanding the ultra-fast transport properties of hot charge carriers is of significant importance both fundamentally and technically in applications like solar cells and transistors. However, direct measurement of charge transport at…

Chemical Physics · Physics 2022-08-10 Peter A. Sloan , Kristina R. Rusimova

The junction of a scanning tunneling microscope (STM) operating in the tunneling regime was irradiated with femtosecond laser pulses. A photo-excited hot electron in the STM tip resonantly tunnels into an excited state of a single molecule…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Shiwei Wu , Wilson Ho

In a low-temperature study with a scanning tunneling microscope (STM), the irreducible lateral motion of a CO molecule adsorbed on a Si(001) surface showed a hyperlinear dependence on the tunneling current. This dependence implies that the…

We explore theoretically the electroluminescence of single molecules. We adopt a local-electrode framework that is appropriate for scanning tunneling microscopy (STM) experiments where electroluminescence originates from individual…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 John Buker , George Kirczenow

Ultraviolet and visible radiation is observed from the contacts of a scanning tunneling microscope with Si(100) and (111) wafers. This luminescence relies on the presence of hot electrons in silicon, which are supplied, at positive bias on…

Materials Science · Physics 2009-11-13 Patrick Schmidt , Richard Berndt , Mikhail I. Vexler

The strong coupling between intense laser fields and valence electrons in molecules causes a distortion of the potential energy hypersurfaces which determine the motion of nuclei in a molecule and influences possible reaction pathways. The…

Photoemission electron microscopy was used to image the electrons photoemitted from specially tailored Ag nanoparticles deposited on a Si substrate (with its native oxide SiO$_{x}$). Photoemission was induced by illumination with a Hg…

Energy and charge transfer between molecules and metal surfaces underpin heterogeneous catalysis, surface-enhanced spectroscopies and plasmon-driven chemistry, yet the microscopic origins of vibrational excitation at metal interfaces remain…

Mesoscale and Nanoscale Physics · Physics 2026-01-26 Bing Gao , Jameel Damoah , Wassie M. Takele , Terefe G. Habteyes

Tip-enhanced photoluminescence (TEPL) measurements are performed with sub-nanometer spatial resolution on individual molecules decoupled from a metallic substrate by a thin NaCl layer. TEPL spectra reveal progressive fluorescence quenching…

Mesoscale and Nanoscale Physics · Physics 2024-03-18 Katharina Kaiser , Michelangelo Romeo , Fabrice Scheurer , Guillaume Schull , Anna Rosławska

A scanning tunneling microscope (STM) can do more than atomic imaging and manipulation. Its tunneling current can also be used for the excitation of light, converting electron energy to photon energy. STM based single-molecule…

Optics · Physics 2019-01-01 Yao Zhang , Yang Zhang , Zhenchao Dong

The scanning-tunneling-microscope-induced luminescence emerges recently as an incisive tool to measure the molecular properties down to the single-molecule level. The rapid experimental progress is far ahead of the theoretical effort to…

Mesoscale and Nanoscale Physics · Physics 2020-11-24 Guohui Dong , Yining You , Hui Dong

The plasmonic tip of a scanning tunnelling microscope (STM) is functionalized with a single fluorescent molecule and is scanned on a plasmonic substrate. The tunneling current flowing through the tip-molecule-substrate junction generates a…

We attempt to provide physical interpretations of light-induced desorption phenomena that have recently been observed for alkali atoms on glass surfaces of alkali vapor cells used in atomic physics experiments. We find that the observed…

Other Condensed Matter · Physics 2007-05-23 Atsushi Hatakeyama , Markus Wilde , Katsuyuki Fukutani

Measurements of light emission from a scanning tunneling microscope probing a Na overlayer on the (111) surface of Cu are reported along with results of a model calculation that essentially agree with the experimental ones. The observed…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Peter Johansson , Germar Hoffmann , Richard Berndt

Effects of coupling between an molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using nonequilibrium Green's function method.…

Materials Science · Physics 2013-11-12 Kuniyuki Miwa , Mamoru Sakaue , Hideaki Kasai

Understanding tunneling from an atomically sharp tip to a metallic surface requires to account for interactions on a nanoscopic scale. Inelastic tunneling of electrons generates emission of photons, whose energies intuitively should be…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 F. Xu , C. Holmqvist , W. Belzig

Controlling electrically-stimulated quantum light sources (QLS) is key for developing integrated and low-scale quantum devices. The mechanisms leading to quantum emission are complex, as a large number of electronic states of the system…

Mesoscale and Nanoscale Physics · Physics 2024-02-28 Katharina Kaiser , Anna Rosławska , Michelangelo Romeo , Fabrice Scheurer , Tomáš Neuman , Guillaume Schull

Electronic excitations near the surface of water ice lead to the desorption of adsorbed molecules, through a so far debated mechanism. A systematic study of photon-induced indirect desorption, revealed by the spectral dependence of the…

We study the light emission from a Ag(111) surface when the bias voltage on a scanning tunneling microscope (STM) junction is ramped into the field emission regime. Above the vacuum level, scanning tunneling spectroscopy (STS) shows a…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Jesús Martínez-Blanco , Stefan Fölsch

Photoionization by high-energy photons creates nonthermal electrons with a broad range of energies that heat and chemically transform the atmospheres of planets. The specifics of the interactions are notably different when the gas is atomic…

Earth and Planetary Astrophysics · Physics 2025-06-17 Antonio García Muñoz , Ewan Bataille
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