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The construction of meta generalized gradient approximations based on the density matrix expansion (DME) is considered as one of the most accurate technique to design semilocal exchange energy functionals in two-dimensional density…

Materials Science · Physics 2018-05-09 Abhilash Patra , Subrata Jana , Prasanjit Samal

Exchange interactions are a manifestation of the quantum mechanical nature of the electrons and play a key role in predicting the properties of materials from first principles. In density functional theory (DFT), a widely used approximation…

Materials Science · Physics 2020-03-27 Marco Bernardi

We propose a systematic and constructive way to determine the exchange-correlation potentials of density-functional theories including vector potentials. The approach does not rely on energy or action functionals. Instead it is based on…

Finite temperature density functional theory provides, in principle, an exact description of the thermodynamical equilibrium of many-electron systems. In practical applications, however, the functionals must be approximated. Efficient and…

Statistical Mechanics · Physics 2015-05-19 S. Pittalis , C. R. Proetto , A. Floris , A. Sanna , C. Bersier , K. Burke , E. K. U. Gross

We train a neural network as the universal exchange-correlation functional of density-functional theory that simultaneously reproduces both the exact exchange-correlation energy and potential. This functional is extremely non-local, but…

Computational Physics · Physics 2019-10-10 Jonathan Schmidt , Carlos L. Benavides-Riveros , Miguel A. L. Marques

We consider a system of two-dimensional electrons strongly localized by disorder. Interactions create a gap in the average tunneling density of states $\nu(E)$ at energies, E, close to the Fermi level. We derive a system of self-consistent…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Ya. M. Blanter , M. E. Raikh

We study the energetic properties of finite but internally homogeneous D-dimensional electron droplets in the strict-correlation limit. The indirect Coulomb interaction is found to increase as a function of the electron number, approaching…

Strongly Correlated Electrons · Physics 2011-05-11 E. Rasanen , M. Seidl , P. Gori-Giorgi

Aiming to combine density functional theory (DFT) and wavefunction theory, we study a mapping from the many-body interacting system to an effectively-interacting Kohn-Sham system instead of a non-interacting Kohn-Sham system. Because a…

Chemical Physics · Physics 2020-02-19 Shunsuke A. Sato , Angel Rubio

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

Materials Science · Physics 2009-11-10 Roi Baer , Daniel Neuhauser

We consider the energy spectrum of emitted electrons in $\beta$-decay. Exact Coulomb Dirac wave functions describing the $\beta$-electron in the Coulomb field of the daughter nucleus are used. Further, the improved wave functions which…

Atomic Physics · Physics 2014-09-25 B. Najjari , X. Mougeot , M. -M. Bé , C. Bisch , P. -A. Hervieux , A. Nachab , A. -M. Nourreddine

The Becke-Johnson exchange potential [J. Chem. Phys. 124, 221101 (2006)] has been successfully used in electronic structure calculations within density-functional theory. However, in its original form the potential may dramatically fail in…

Materials Science · Physics 2010-01-28 E. Rasanen , S. Pittalis , C. Proetto

Kohn-Sham Density Functional Theory (KS-DFT) provides the exact ground state energy and electron density of a molecule, contingent on the as-yet-unknown universal exchange-correlation (XC) functional. Recent research has demonstrated that…

We study non-linear adiabatic connection paths in density-functional theory using modified electron-electron interactions that perform a long-range/short-range separation of the Coulomb interaction. These adiabatic connections allows to…

Chemical Physics · Physics 2009-11-11 Julien Toulouse , Francois Colonna , Andreas Savin

The unique property of Coulomb interaction in strict one-dimensional (1D) system is revealed that the Coulomb repulsion energy of paired electrons is divergent. As consequences, electrons in 1D system can not doubly occupy the same spatial…

Strongly Correlated Electrons · Physics 2011-08-23 Yongxi Zhou

A method for calculating the Kohn--Sham exchange-correlation potential, $v_\text{XC}(\mathbf{r})$, from a given electronic wavefunction is devised and implemented. It requires on input one- and two-electron density matrices and involves…

Chemical Physics · Physics 2015-08-19 Ilya G. Ryabinkin , Sviataslau V. Kohut , Viktor N. Staroverov

An approach to achieve nuclear fusion utilizing the formation of high densities of electrons and neutrals is described. The profusion of low energy electrons provides high dynamic electric fields that help reduce the Coulomb barrier in…

Plasma Physics · Physics 2019-08-30 Alfred Y. Wong , Chun-Ching Shih

We introduce a new functional for simulating ground-state and time-dependent electronic systems within density-functional theory. The functional combines an expression for the exact Kohn-Sham (KS) potential in the limit of complete electron…

Mesoscale and Nanoscale Physics · Physics 2021-01-15 M. J. P. Hodgson , J. D. Ramsden , T. R. Durrant , R. W. Godby

In nuclear physics, it is well known that the electromagnetic (Coulomb) interaction between final state products can drastically effect particle reaction rates. Near thresholds, for example, nuclear alpha decay is suppressed while nuclear…

High Energy Physics - Phenomenology · Physics 2007-05-23 G. Castellani , S. Reucroft , Y. N. Srivastava , J. Swain , A. Widom

The large-$Z$ asymptotic expansion of atomic energies has been useful in determining exact conditions for corrections to the local density approximation in density functional theory. The correction for exchange is fit well with a leading $Z…

Chemical Physics · Physics 2023-04-13 Nathan Argaman , Jeremy Redd , Antonio C. Cancio , Kieron Burke

The recently proposed density functional theory for steady-state transport (i-DFT) is extended to include temperature gradients between the leads. Within this framework, a general and exact expression is derived for the linear Seebeck…

Strongly Correlated Electrons · Physics 2019-12-04 Nahual Sobrino , Roberto D'Agosta , Stefan Kurth
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