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We study orientation and two-center interference effects in attosecond time-resolved photoionization of the H$_2$ molecule. Time resolution of XUV ionization of H$_2$ is gained through the phase retrieval capability of attosecond angular…

Atomic Physics · Physics 2026-03-03 Vladislav V. Serov , Anatoli S. Kheifets

We measure the photoionization cross-section of vibrationally excited levels in the S2 state of azulene by femtosecond pump-probe spectroscopy. At the wavelengths studied (349-265 nm in the pump) the transient signals exhibit two distinct…

We present a theory of time-resolved photoionisation in the presence of a vortex beam. In a pump-probe setup, an extreme ultraviolet or an x-ray pump pulse triggers ionization, which is probed by a synchronized infrared pulse with non-zero…

Atomic Physics · Physics 2020-04-01 Sucharita Giri , Misha Ivanov , Gopal Dixit

Attosecond photoelectron interferometry based on the combination of an attosecond pulse train and a synchronized infrared field is a fundamental technique for the temporal characterization of attosecond waveforms and for the investigation…

The exact delay-zero calibration in an attosecond pump-probe experiment is important for the correct interpretation of experimental data. In attosecond transient absorption spectroscopy the determination of the delay-zero exclusively from…

Attosecond pump-probe ionization process can be used to prepare atomic ions in the coherent superposition of states with opposite parity. The multiphoton shake-up ionization of Helium, in particular, generates ions with same principal…

Atomic Physics · Physics 2019-12-12 Saad Mehmood , Eva Lindroth , Luca Argenti

The implementation of attosecond photoelectron-photoion coincidence spectroscopy for the investigation of atomic and molecular dynamics calls for a high-repetition-rate driving source combined with experimental setups characterized by…

We investigate ionization of neon atoms by an isolated attosecond pump pulse in the presence of two coherent extreme ultraviolet or x-ray probe fields. The probe fields are tuned to a core-valence transition in the residual ion and induce…

Atomic Physics · Physics 2016-03-30 Jhih-An You , Nina Rohringer , Jan Marcus Dahlström

We analyze the electronic correlation contribution to the time delay in the photo-ionization of the excited ortho- and para-Helium states. A simple estimation, based on the ionization probability amplitudes, shows that the different form of…

Atomic Physics · Physics 2024-03-21 Pedro Sancho

Shape resonances in photoionization of atoms and molecules arise from a particular geometry of the ionic potential which traps the receding photoelectron in a quasi-bound state in a particular partial wave. This mechanism allows us to…

Atomic Physics · Physics 2026-03-03 Anatoli S. Kheifets , Stephen Catsamas

Quantum path interferences occur whenever multiple equivalent and coherent transitions result in a common final state. Such interferences strongly modify the probability of a particle to be found in that final state, a key concept of…

For a molecule, the two-center interference and the molecular scattering phase of the electron are important for almost all the processes that may occur in a laser field. In this study, we investigate their effects in the transfer of linear…

Atomic Physics · Physics 2018-12-19 Hao Liang , Mu-Xue Wang , Xiang-Ru Xiao , Qihuang Gong , Liang-You Peng

We predict that attosecond spectroscopy could be used to observe time delay for electron emission {in the C$^{1+}$ ion} from a few step processes {that include electron impact excitation}. The results reveal that the photon energy…

Atomic Physics · Physics 2018-10-01 Valdas Jonauskas , Šarūnas Masys

Realistic attosecond wave packets have complex profiles that, in dispersive conditions, rapidly broaden or split into multiple components. Such behaviors are encoded in sharp features of the wave packet spectral phase. Here, we exploit the…

Several recent attoclock experiments have investigated the fundamental question of a quantum mechanically induced time delay in tunneling ionization via extremely precise photoelectron momentum spectroscopy. The interpretations of those…

We analyze two-center interference effects in the yields of ionization of a dissociating hydrogen molecular ion by an ultrashort VUV laser pulse. To this end, we performed numerical simulations of the time-dependent Schr\"odinger equation…

Quantum Physics · Physics 2015-05-27 A. Picón , A. Bahabad , H. C. Kapteyn , M. M. Murnane , A. Becker

Photon exchange due to nuclear bremsstrahlung during nuclear collisions can cause Coulomb excitation in the projectile and the target nuclei. The corresponding process originated in nuclear timescales can also be observed in atomic…

Determination and interpretation of Wigner-like photoionisation delays is one of the most active fields of attosecond science. Previous results have suggested that large photoionisation delays are associated with structured continua, but a…

Atomic Physics · Physics 2024-10-14 Jia-Bao Ji , Anatoli S. Kheifets , Meng Han , Kiyoshi Ueda , Hans Jakob Wörner

Tunnelling, one of the key features of quantum mechanics, ignited an ongoing debate about the value, meaning and interpretation of 'tunnelling time'. Until recently the debate was purely theoretical, with the process considered to be…

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