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The available enthalpy is an early form of the modern thermodynamic concept of exergy, which is the generic name for the amount of work obtainable when some matter is brought to a state of equilibrium with its surroundings by means of…

Atmospheric and Oceanic Physics · Physics 2014-02-21 Pascal Marquet

Thermodynamics imposes restrictions on what state transformations are possible. In the macroscopic limit of asymptotically many independent copies of a state---as for instance in the case of an ideal gas---the possible transformations…

Quantum Physics · Physics 2019-11-14 Philippe Faist , Mario Berta , Fernando Brandão

A goal of physics is to understand the greatest possible breadth of natural phenomena in terms of the most economical set of basic concepts. However, as the understanding of physics has developed historically, its pedagogy and language have…

General Physics · Physics 2020-10-21 B. C. Regan

In classical thermodynamic processes the unavoidable presence of irreversibility, quantified by the entropy production, carries two energetic footprints: the reduction of extractable work from the optimal, reversible case, and the…

Quantum Physics · Physics 2020-05-20 M. H. Mohammady , A. Aufféves , J. Anders

Universal properties of efficiency at maximum power are investigated in a general setting. In particular, it is demonstrated how successive symmetries placed upon the dynamics manifest themselves at the macroscopic level. A general…

Statistical Mechanics · Physics 2015-03-10 Bart Cleuren , Bob Rutten , Christian Van den Broeck

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines,…

Quantum Physics · Physics 2016-11-23 R. Gallego , J. Eisert , H. Wilming

We review and investigate the general theory of thermodynamics of computation, and derive the fundamental inequalities that set the lower bounds of the work requirement and the heat emission during a computation. These inequalities…

Statistical Mechanics · Physics 2015-06-17 Takahiro Sagawa

Physical systems that power motion and create structure in a fixed amount of time dissipate energy and produce entropy. Whether living or synthetic, systems performing these dynamic functions must balance dissipation and speed. Here, we…

Statistical Mechanics · Physics 2020-12-18 Schuyler B. Nicholson , Luis Pedro Garcia-Pintos , Adolfo del Campo , Jason R. Green

The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…

Statistical Mechanics · Physics 2020-08-21 Gil Ariel , Haim Diamant

First, Second and Combined Laws of Thermodynamics are revised in terms of entropy change, partial entropy, partial volume, and chemical potential.

Statistical Mechanics · Physics 2025-06-03 Zi-Kui Liu

When the difference between changes in energy and entropy at a given temperature is correlated with the ratio between the same changes in energy and entropy at zero average free energy of an ensemble of similar but distinct molecule-sized…

General Physics · Physics 2009-06-17 Petr Zimak , Silvia Terenzi , Peter Strazewski

The universal concept of complexity by the dynamic redundance paradigm and the ensuing concept of extended dynamic fractality (physics/9806002) are applied here to higher levels of complexity corresponding to living systems. After recalling…

General Physics · Physics 2007-05-23 Andrei P. Kirilyuk

The entropy production is commonly interpreted as measuring the distance from equilibrium. However, this explanation lacks a rigorous description due to the absence of a natural equilibrium measure. The present analysis formalizes this…

Statistical Mechanics · Physics 2025-10-23 David Andrieux

Entropic-force cosmology provides, in contrast with dark energy descriptions, a concrete physical understanding of the accelerated expansion of the universe. The acceleration appears to be a consequence of the entropy associated with the…

General Relativity and Quantum Cosmology · Physics 2022-08-15 D. J. Zamora , C. Tsallis

Entropy production characterizes irreversibility. This viewpoint allows us to consider the thermodynamic uncertainty relation, which states that a higher precision can be achieved at the cost of higher entropy production, as a relation…

Statistical Mechanics · Physics 2021-12-09 Yoshihiko Hasegawa

This is a review on entropy in various fields of mathematics and science. Its scope is to convey a unified vision of the classical as well as some newer entropy notions to a broad audience with an intermediate background in dynamical…

Dynamical Systems · Mathematics 2022-02-08 José M. Amigó , Karsten Keller , Valentina Unakafova

Considering the isentropic Euler equations of compressible fluid dynamics with geometric effects included, we establish the existence of entropy solutions for a large class of initial data. We cover fluid flows in a nozzle or in spherical…

Analysis of PDEs · Mathematics 2008-12-16 Philippe G. LeFloch , Michael Westdickenberg

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from…

Quantum Physics · Physics 2019-08-22 Philipp Strasberg

A common hope of many physics educators and researchers is that students leave the course with a stronger sense that physics is relevant to them than when they entered the course. Multiple survey measures have attempted to measure shifts in…

Physics Education · Physics 2018-08-31 Abhilash Nair , Vashti Sawtelle

Entropy production quantifies the amount of irreversibility of a physical process, leading to fundamental bounds for thermodynamic quantities. It captures the inability to run a physical system forward and then backward, bringing it to the…

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