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The electronic structure of Samarium (Sm) was calculated using the density functional theory combined with the single-site dynamical mean-field theory. In this work, we investigated the electronic properties of {\alpha}, \b{eta} and…

Strongly Correlated Electrons · Physics 2026-05-15 Shengsong Xu , Zhenfeng Ouyang , Li Huang , Zhong-Yi Lu

The electronic ground states of the actinide dioxides AnO2 (with An=U, Np, Pu, Am, and Cm) are investigated employing first-principles calculations within the framework of the local density approximation +U (LDA+U) approach, implemented in…

Strongly Correlated Electrons · Physics 2014-10-22 Michi-To Suzuki , Nicola Magnani , Peter M. Oppeneer

We present an orbital-resolved extension of the Hubbard $U$ correction to density-functional theory (DFT). Compared to the conventional shell-averaged approach, the prediction of energetic, electronic and structural properties is strongly…

Materials Science · Physics 2024-09-18 Eric Macke , Iurii Timrov , Nicola Marzari , Lucio Colombi Ciacchi

The Fe$_{n}$GeTe$_{2}$ systems are newly discovered two-dimensional van-der-Waals materials, exhibiting magnetism at room temperature. The sub-systems belonging to Fe$_{n}$GeTe$_{2}$ class are special because they show site-dependent…

Materials Science · Physics 2022-12-19 Sukanya Ghosh , Soheil Ershadrad , Vladislav Borisov , Biplab Sanyal

The ongoing scientific interest in the properties and structure of electric double layers (EDLs) stems from their pivotal role in (super)capacitive energy storage, energy harvesting, and water treatment technologies. Classical density…

Soft Condensed Matter · Physics 2016-04-28 Andreas Härtel , Sela Samin , Rene van Roij

LDA+DMFT is a novel computational technique for ab initio investigations of real materials with strongly correlated electrons, such as transition metals and their oxides. It combines the strength of conventional band structure theory in the…

Strongly Correlated Electrons · Physics 2007-05-23 K. Held , I. A. Nekrasov , G. Keller , V. Eyert , N. Blümer , A. K. McMahan , R. T. Scalettar , T. Pruschke , V. I. Anisimov , D. Vollhardt

Orbital-free density functional theory (OF-DFT) constitutes a computationally highly effective tool for modeling electronic structures of systems ranging from room-temperature materials to warm dense matter. Its accuracy critically depends…

The importance of many-body effects on electronic and magnetic properties and stability of different structural phases was studied in novel iron oxide - Fe$_2$O. It was found that while Hubbard repulsion hardly affects the electronic…

Strongly Correlated Electrons · Physics 2022-06-08 Alexey O. Shorikov , Sergey V. Streltsov

Geometrically frustrated magnetic semiconductor $\textrm{CuMnO}_{2}$ has potential applications as photo-catalyst, in photochemical cells and multi-ferroic devices. Electronic band structure in the antiferromagnetic and ferromagnetic phases…

Materials Science · Physics 2024-06-05 Apurba Sarkar , Joydeep Chatterjee , Arghya Taraphder , Nandan Pakhira

In the realm of quantum chemistry, the accurate prediction of electronic structure and properties of nanostructures remains a formidable challenge. Density Functional Theory (DFT) and Density Matrix Renormalization Group (DMRG) have emerged…

Strongly Correlated Electrons · Physics 2024-02-21 T. Pauletti , M. Sanino , L. Gimenes , I. M. Carvalho , V. V. França

Uranium dioxide which is used as a fuel in light water nuclear reactors, is continually exposed to radiation damage originated from the collision of high-energy particles. Accumulation of the resulting defects gives rise to the evolution in…

Materials Science · Physics 2025-04-14 Mahmoud Payami , Samira Sheykhi , Mohammad-Reza Basaadat

It is believed that the density functional theory (DFT) describes most elements with s, p and d orbitals very well, except some materials that having strongly localized and correlated valence electrons. In this work, we find that the widely…

Materials Science · Physics 2020-03-17 Y. X. Wang , Hua Y. Geng , Q. Wu , Xiang R. Chen

By investigating the crystalline structure of ground-state orthorhombic SrRuO$_3$, we present a benchmark study of some of the most popular density functional theory (DFT) approaches from the local density approximation (LDA),…

Materials Science · Physics 2016-08-03 Š. Masys , V. Jonauskas

We present in full detail a newly developed formalism enabling density functional perturbation theory (DFPT) calculations from a DFT+$U$ ground state. The implementation includes ultrasoft pseudopotentials and is valid for both insulating…

Strongly Correlated Electrons · Physics 2020-02-21 Andrea Floris , Iurii Timrov , Burak Himmetoglu , Nicola Marzari , Stefano de Gironcoli , Matteo Cococcioni

Using first principles calculations within DFT based on the full potential APW+lo method, we calculated the electronic and magnetic structures for the ferromagnetic and antiferromagnetic states of La2MnNiO6 and analyzed the site projected…

Strongly Correlated Electrons · Physics 2007-05-23 S. F. Matar , M. A. Subramanian , V. Eyert , M. Whangbo , A. Villesuzanne

Accurate computational predictions of metal-organic frameworks (MOFs) and their properties is crucial for discovering optimal compositions and applying them in relevant technological areas. This work benchmarks density functional theory…

Materials Science · Physics 2025-03-11 Joshua Edzards , Julia Santana Andreo , Holger-Dietrich Saßnick , Caterina Cocchi

Quantum mechanical methods based on the density functional theory (DFT) offer a realistic possibility of first-principles design of organic donor-acceptor systems and engineered band-gap materials. This promise is contingent upon the…

Chemical Physics · Physics 2013-12-03 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

We present an accurate implementation of total energy calculations into the local density approximation plus dynamical mean-field theory (LDA+DMFT) method. The electronic structure problem is solved through the full potential linear…

Strongly Correlated Electrons · Physics 2009-03-16 I. Di Marco , J. Minár , S. Chadov , M. I. Katsnelson , H. Ebert , A. I. Lichtenstein

Density functional theory (DFT), one of the most widely utilized methods available to computational chemistry, fails to describe systems with statically correlated electrons. To address this shortcoming, in previous work we transformed DFT…

Chemical Physics · Physics 2023-01-02 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

The electronic structures of the cubic and tetragonal $\mathrm{MnV}_2\mathrm{O}_4$ have been studied by using hybrid-exchange density functional theory. The computed electronic structure of the tetragonal phase shows an anti-ferro orbital…

Strongly Correlated Electrons · Physics 2015-05-08 Wei Wu