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Nanopores that exhibit ionic current rectification (ICR) behave like diodes, such that they transport ions more efficiently in one direction than the other. Conical nanopores have been shown to rectify ionic current, but only those with at…

Chemical Physics · Physics 2022-06-08 Long Ma , Zhongwu Li , Zhishan Yuan , Chuanzhen Huang , Zuzanna S. Siwy , Yinghua Qiu

Ionic current rectification (ICR) of charged conical nanopores has various applications in fields including nanofluidics, bio-sensing, and energy conversion, whose function is closely related to the dynamic response of nanopores. The…

Chemical Physics · Physics 2024-10-29 Zhe Liu , Long Ma , Hongwen Zhang , Jiakun Zhuang , Jia Man , Zuzanna S. Siwy , Yinghua Qiu

Ionic Current Rectification (ICR) can appear in nanopores, causing a diode-like behavior that originates from different efficiency of ion transport through the pore channel with respect to the applied voltage bias polarity. This effect is…

With controlled ionic current rectification (ICR) achieved through a strategically designed non-uniform surface charge distribution, short unipolar nanopores exhibit promising applications in nanofluidic sensors, ionic circuits, and ion…

Chemical Physics · Physics 2025-12-08 Hongwen Zhang , Long Ma , Di Liu , Tianyi Sui , Zuzanna S. Siwy , Yinghua Qiu

Bipolar nanopores, with asymmetric charge distributions, can induce significant ionic current rectification (ICR) at ultra-short lengths, finding potential applications in nanofluidic devices, energy conversion, and other related fields.…

Chemical Physics · Physics 2024-10-29 Hongwen Zhang , Long Ma , Chao Zhang , Yinghua Qiu

Fluidic devices exhibiting ion current rectification (ICR), or ionic diodes, are of broad interest for applications including desalination, energy harvesting, and sensing, amongst others. For such applications a large conductance is…

Soft Condensed Matter · Physics 2022-10-11 Mark Aarts , Willem Boon , Blaise Cuénod , M. Dijkstra , René van Roij , Esther Alarcon-Llado

We have investigated ion current rectification properties of a recently prepared bipolar nanofluidic diode. This device is based on a single conically shaped nanopore in a polymer film whose pore walls contain a sharp boundary between…

Other Condensed Matter · Physics 2009-11-13 D. Constantin , Z. S. Siwy

The transport of molecules in confined media is subject to entropic barriers. So theoretically, asymmetry of the confinement length may lead to molecular ratchets with entropy as the only driving force for the biased transport. We address…

Soft Condensed Matter · Physics 2016-12-20 D. Lairez , M. -C. Clochard , J. -E. Wegrowe

Ionic current rectification (ICR) induced by electroosmotic flow (EOF) under concentration gradients can find many applications in micro/nanofluidic sensing and ionic circuits. Here, we focused on the cases with micropores of moderate…

Chemical Physics · Physics 2025-10-21 Long Ma , Hongwen Zhang , Bowen Ai , Jiakun Zhuang , Guanghua Du , Yinghua Qiu

Single nanopores have attracted much scientific interest due to their versatile applications. The majority of experiments have been performed with nanopores being in contact with the same electrolyte on both sides of the membrane, while…

Chemical Physics · Physics 2018-12-11 Yinghua Qiu , Zuzanna S. Siwy , Meni Wanunu

Ion transport in biological and synthetic nanochannels is characterized by phenomena such as ion current fluctuations and rectification. Recently, it has been demonstrated that nanofabricated synthetic pores can mimic transport properties…

Classical Physics · Physics 2009-11-13 I. D. Kosińska , I. Goychuk , M. Kostur , G. Schmid , P. Hänggi

Asymmetric current--voltage ($I(V)$) curves, known as the diode or rectification effect, in one--dimensional electronic conductors can have their origin from scattering off a single asymmetric impurity in the system. We investigate this…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Bernd Braunecker , D. E. Feldman , J. B. Marston

Nanopores in solid state membranes are a tool able to probe nanofluidic phenomena or can act as a single molecular sensor. They also have diverse applications in filtration, desalination or osmotic power generation. Many of these…

Soft Condensed Matter · Physics 2020-12-02 Sebastian J. Davis , Michal Macha , Andrey Chernev , David M. Huang , Aleksandra Radenovic , Sanjin Marion

Traditionally, ion-selectivity in nanopores and nanoporous membranes is understood to be a consequence of Debye overlap, in which the Debye screening length is comparable to the nanopore radius somewhere along the length of the nanopore(s).…

Soft Condensed Matter · Physics 2020-08-05 Anthony R. Poggioli , Alessandro Siria , Lyderic Bocquet

The phase offset between surface charge modulation and geometric undulations in a corrugated nanochannel provides a tunable mechanism for rectified, diode-like ion transport under purely pressure-driven conditions: reversing the applied…

Fluid Dynamics · Physics 2026-05-15 Thomas Petersen , Pouya Golchin , Jinwoo Im , Felipe P. J. de Barros

We model and simulate a nanopore sensor that selectively binds analyte ions. This binding leads to the modulation of the local concentrations of the ions of the background electrolyte (KCl), and, thus, to the modulation of the ionic current…

Applied Physics · Physics 2019-11-07 Eszter Mádai , Mónika Valiskó , Dezső Boda

Ionic liquids constrained at interfaces or restricted in subnanometric pores are increasingly employed in modern technologies, including energy applications. Understanding the details of their behavior in these conditions is therefore…

Materials Science · Physics 2018-09-25 Stefano Mossa

In this study, we investigated the ionic current rectification of glass nanopipettes modified with bovine serum albumin - glutaraldehyde (BSA-GA) artificial membrane using solutions with various pHs. Ionic current rectification is a…

Chemical Physics · Physics 2018-02-09 Mustafa Sen

Confinement strongly influences electrochemical systems, where structural control has enabled advances in nanofluidics, sensing, and energy storage. In electric double-layer capacitors (EDLCs), or supercapacitors, energy density is governed…

Chemical Physics · Physics 2026-01-30 Bryce Rives , Filipe Henrique , Pawel Zuk , Ankur Gupta

Mechanosensitive ion nanochannels regulate transport by undergoing conformational changes within nanopores. However, achieving precise control over these conformational states remains a major challenge for both artificial soft or solid…

Chemical Physics · Physics 2026-01-06 Ke Zhou
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