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High stability and oxygen permeability are two prominent requirements for the oxygen transport membrane candidates used as industrialization. Herein, we report several composite membranes based on…

Applied Physics · Physics 2019-07-30 Lei Shi , Shu Wang , Tianni Lu , Yuan He , Dong Yan , Qi Lan , Zhiang Xie , Haoqi Wang , Man-Rong Li , Juergen Caro , Huixia Luo

Developing good performance and low-cost oxygen permeable membranes for CO2 capture based on the oxy-fuel concept is greatly desirable but challenging. Despite tremendous efforts in exploring new CO2-stable dual-phase membranes, its…

Applied Physics · Physics 2020-07-08 Shu Wang , Lei Shi , Mebrouka Boubeche , Xiaopeng Wang , Lingyong Zeng , Haoqi Wang , Zhiang Xie , Wen Tan , Huixia Luo

Ceramic dual-phase oxygen transport membranes with the composition of 60wt.% Ce0.9Pr0.1O2-{\delta}-40wt.%Pr0.6Sr0.4Fe1-xAlxO3-{\delta} (x = 0.05, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8, 1.0) (60CPO-40PSF1-xAxO) based on…

Applied Physics · Physics 2019-07-04 Lei Shi , Shu Wang , Tianni Lu , Yuan He , Dong Yan , Qi Lan , Zhiang Xie , Haoqi Wang , Mebrouka Boubeche , Huixia Luo

Oxygen transport membranes(OTMs)have provided great opportunities in the last decades but are suffering from the trade-off effect between stability and oxygen permeability. Here, we report a group of new planar dual-phase mixed…

Oxygen transport membranes (OTMs), enabling catalytic reaction and gas separation, support crucial chemical engineering processes and decarbonization technologies, but their applications are hindered by limited oxygen permeation fluxes and…

Materials Science · Physics 2026-02-26 Zaichen Xiang , Rui Chen , Shuangyue Wang , Jingjun Qin , Wanyi Zhang , Yucheng Li , Lingyong Zeng , Huixia Luo

The development of efficient and stable intermediate-temperature solid oxide fuel cells (SOFCs) necessitates high-performance cathode materials that are cobalt-free, cost-effective, and compatible with proton-conducting electrolytes. While…

Materials Science · Physics 2026-03-03 Le Zhou , Yanru Yin , Dilshod Nematov , Hailu Dai , Yuyuan Gu , Shoufu Yu , Lei Bi

Enhancing the transport of oxygen anions in the cathode while maintaining surface stability is essential for improving the performance of intermediate-temperature solid oxide fuel cells (IT-SOFCs). This study investigates a novel cathode…

Materials Science · Physics 2025-03-04 Jyotsana Kalaa , Vicky Dhongde , Suddhasatwa Basu , Brajesh Kumar Mani , M. Ali Haider

The trade-off effect of the oxygen permeability and stability of oxygen transport membranes (OTMs) still exists in working atmospheres containing CO2. Herein, we reported a new series of 60…

Materials Science · Physics 2024-11-06 Chao Zhang , Zaichen Xiang , Lingyong Zeng , Peifeng Yu , Kuan Li , Kangwang Wang , Longfu Li , Rui Chen , Huixia Luo

Structures of calcium peroxide (CaO2) are investigated in the pressure range 0-200 GPa using the ab initio random structure searching (AIRSS) method and density functional theory (DFT) calculations. At 0 GPa, there are several CaO2…

Materials Science · Physics 2017-03-01 Joseph R. Nelson , Richard J. Needs , Chris J. Pickard

The prediction of new high entropy oxides (HEOs) remains a profound challenge due to their inherent chemical complexity. In this work, we combine experimental and computational methods to search for new HEOs in the tetravalent $A$O$_2$…

The GdFeO$_{3}$-type perovskite CaCoO$_{3}$ has been successfully synthesized by high-pressure oxygen annealing for the oxygen deficient perovskite. A detailed structural analysis based on synchrotron X-ray diffraction data and a…

Strongly Correlated Electrons · Physics 2017-07-20 T. Osaka , H. Takahashi , H. Sagayama , Y. Yamasaki , S. Ishiwata

We present a comprehensive study of cross-flow ultrafiltration (UF) of charge-stabilized suspensions, under low-salinity conditions of electrostatically strongly repelling colloidal particles. The axially varying permeate flux,…

We describe Na0.67Mn0.625Fe0.25Co0.125O2 (NMFCO), a P2-type sodium-ion battery cathode. Our composition, with significantly less Co than in an earlier study, shows discharge capacity close to 190 mAhg-1 and specific energy density exceeding…

Materials Science · Physics 2024-08-06 William Rexhausen , Christian Parsons , Uma Garg , Deyang Qu , Prasenjit Guptasarma

Water splitting allows the storage of solar energy into chemical bonds (H2+O2) and will help to implement the urgently needed replacement of limited available fossil fuels. Particularly in neutral environment electrochemically initiated…

Solar thermochemical hydrogen generation (STCH) is a promising approach for eco-friendly H2 production, but conventional STCH redox compounds often suffer from thermodynamic and kinetic limitations with limited tunability. Expanding from…

Misfit-layered (ML) cobalt oxides of the general formula of [MmA2Om+2]qCoO2 have been proven to be efficient thermoelectric materials as the structure is capable in accommodating the two seemingly contradictory characteristics of high…

Strongly Correlated Electrons · Physics 2007-05-23 H. Yamauchi , K. Sakai , T. Nagai , Y. Matsui , M. Karppinen

The layers of graphene oxide (GO) are found to be good for permeation of water but not for helium (Science 2012 335 (6067): 442-444) suggesting that the GO layers are dynamic in the formation of permeation route depending on the environment…

Mesoscale and Nanoscale Physics · Physics 2015-10-01 Nallani Raghav , Sudip Chakraborty , Prabal K. Maiti

Using fluorite oxides as an example, this study broadens high-entropy ceramics (HECs) to compositionally-complex ceramics (CCCs) or multi-principal cation ceramics (MPCCs) to include medium-entropy and/or non-equimolar compositions. Nine…

Materials Science · Physics 2020-01-08 Andrew J. Wright , Qingyang Wang , Chuying Huang , Andy Nieto , Renkun Chen , Jian Luo

Understanding the atomic mechanism of low-temperature CO oxidation on a heterogeneous catalyst is challenging. We performed density functional theory (DFT) calculations to identify the surface structure and reaction mechanism responsible…

Chemical Physics · Physics 2019-05-08 Yongeseon Kim , Hosik Lee , Ja Hun Kwak

Nanoporous carbon composite membranes, comprising a layer of porous carbon fiber structures with an average channel width of 30-60 nm grown on a porous ceramic substrate, are found to exhibit robust desalination effect with high freshwater…

Materials Science · Physics 2016-04-27 Wei Chen , Shuyu Chen , Qiang Zhang , Zhongli Fan , Kuo-Wei Huang , Xixiang Zhang , Zhiping Lai , Ping Sheng
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