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This manuscript presents a data-processing technique which improves the accuracy and precision of absorption-spectroscopy measurements by isolating the molecular absorbance signal from errors in the baseline light intensity (Io) using…

Instrumentation and Detectors · Physics 2020-09-24 Christopher S. Goldenstein , Garrett C. Mathews , Ryan K. Cole , Amanda S. Makowiecki , Gregory B. Rieker

Applicability and accuracy of traditional scanned-wavelength direct absorption spectroscopy (SDAS) diagnostic method is largely affected by combustion state such as temperature and pressure. To resolve this problem, an innovative…

Instrumentation and Detectors · Physics 2021-12-06 Yihong Wang

Spectroscopy has played the key role in revealing, and thereby understanding, the structure of atoms and molecules. A central drive in this field is the pursuit of higher precision and accuracy so that ever more subtle effects might be…

Precision spectroscopy of atomic and molecular ions offers a window to new physics, but is typically limited to species with a cycling transition for laser cooling and detection. Quantum logic spectroscopy has overcome this limitation for…

We demonstrate incoherent broadband cavity enhanced absorption spectroscopy in the mid-infrared wave- length range from 3000 to 3450 nm using an all-fiber based supercontinuum source. Multi-components gas detection is performed and…

Instrumentation and Detectors · Physics 2017-09-13 Caroline Amiot , Antti Aalto , Piotr Ryczkowski , Juha Toivonen , Goëry Genty

We demonstrate a 13-fold speed improvement in broadband cantilever-enhanced photoacoustic spectroscopy (CEPAS) by combining it with phase-controlled Fourier-transform spectroscopy (PC-FTS) instead of traditional Fourier-transform infrared…

Optics · Physics 2022-12-21 Santeri Larnimaa , Mikhail Roiz , Markku Vainio

Fourier transform spectroscopy based on incoherent light sources is a well-established tool in research fields from molecular spectroscopy and atmospheric monitoring to material science and biophysics. It provides broadband molecular…

Broadband precision spectroscopy is indispensable for providing high fidelity molecular parameters for spectroscopic databases. We have recently shown that mechanical Fourier transform spectrometers based on optical frequency combs can…

Instrumentation and Detectors · Physics 2018-05-09 Lucile Rutkowski , Piotr Maslowski , Alexandra C. Johansson , Amir Khodabakhsh , Aleksandra Foltynowicz

We propose a new method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photo-induced fragmentation or…

Quantum Physics · Physics 2008-12-31 Stefan Nimmrichter , Klaus Hornberger , Hendrik Ulbricht , Markus Arndt

Spectroscopy has an illustrious history delivering serendipitous discoveries and providing a stringent testbed for new physical predictions, including applications from trace materials detection, to understanding the atmospheres of stars…

Atomic Physics · Physics 2015-01-05 Gar-Wing Truong , James D. Anstie , Eric F. May , Thomas M. Stace , Andre N. Luiten

X-ray absorption spectroscopy (XAS) is a powerful and well established technique with sensitivity to elemental and chemical composition. Despite these advantages, its implementation has not kept pace with the development of ultrafast pulsed…

Photo-acoustic spectroscopy (PAS) is one of the most sensitive non-destructive analysis techniques for gases, fluids and solids. It can operate background-free at any wavelength and is applicable to microscopic and even non-transparent…

A high sensitivity atom flux sensor based on atomic absorption spectroscopy has been designed and implemented to control electron beam evaporators and effusion cells in a molecular beam epitaxy system. Using a high-resolution spectrometer…

Materials Science · Physics 2015-06-19 Y. Du , T. C. Droubay , A. V. Liyu , G. Li , S. A. Chambers

A theoretical model of the influence of detection bandwidth properties on observed line shapes in laser absorption spectroscopy is described. The model predicts artificial frequency shifts, extra broadenings and line asymmetries which must…

We present broadband cavity-enhanced complex refractive index spectroscopy (CE-CRIS), a technique for calibration-free determination of the complex refractive index of entire molecular bands via direct measurement of transmission modes of a…

Spectroscopy is an important tool for probing the properties of materials, chemicals and biological samples. We design a practical transmitter-receiver system that exploits entanglement to achieve a provable quantum advantage over all…

Quantum Physics · Physics 2020-11-03 Haowei Shi , Zheshen Zhang , Stefano Pirandola , Quntao Zhuang

The most realistic information about the transparent sample such as a live cell can be obtained only using bright-field light microscopy. At high-intensity pulsing LED illumination, we captured a primary 12-bit-per-channel (bpc) response…

Image and Video Processing · Electrical Eng. & Systems 2021-08-18 Ganna Platonova , Dalibor Stys , Pavel Soucek , Kirill Lonhus , Jan Valenta , Renata Rychtarikova

Spectroscopic measurements can show distorted spectral shapes arising from a mixture of absorbing and scattering contributions. These distortions (or baselines) often manifest themselves as non-constant offsets or low-frequency…

Machine Learning · Statistics 2024-02-27 Erik Andries , Ramin Nikzad-Langerodi

Absorption spectroscopy is routinely used to characterise chemical and biological samples. For the state-of-the-art in absorption spectroscopy, precision is theoretically limited by shot-noise due to the fundamental Poisson-distribution of…

Optical frequency-comb-based-high-resolution spectrometers offer enormous potential for spectroscopic applications. Although various implementations have been demonstrated, the lack of suitable mid-infrared comb sources has impeded…

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