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As the inventory of interstellar molecules continues to grow, the gulf between small species, whose individual rotational lines can be observed with radio telescopes, and large ones, such as polycyclic aromatic hydrocarbons (PAHs) best…

Much like six-membered rings, five-membered rings are ubiquitous in organic chemistry, frequently serving as the building blocks for larger molecules, including many of biochemical importance. From a combination of laboratory rotational…

We have analyzed ALMA Cycle 5 data in Band 4 toward three low-mass young stellar objects (YSOs), IRAS 03235+3004 (hereafter IRAS 03235), IRAS 03245+3002 (IRAS 03245), and IRAS 03271+3013 (IRAS 03271), in the Perseus region. The HC$_{3}$N…

Glycolaldehyde (HOCH$_2$CHO) and ethylene glycol ((CH$_2$OH)$_2$) are two complex organic molecules detected in the hot cores and hot corinos of several star-forming regions. The ethylene glycol/glycolaldehyde abundance ratio seems to show…

Solar and Stellar Astrophysics · Physics 2018-02-07 A. Coutens , S. Viti , J. M. C. Rawlings , M. T. Beltrán , J. Holdship , I. Jiménez-Serra , D. Quénard , V. M. Rivilla

Aims: To investigate the chemical relations between complex organics based on their spatial distributions and excitation conditions in the low-mass young stellar objects IRAS 16293-2422 A and B. Methods: Interferometric observations with…

Astrophysics · Physics 2009-11-13 S. E. Bisschop , J. K. Jorgensen , T. L. Bourke , S. Bottinelli , E. F. van Dishoeck

The observational detection of some metastable isomers in the interstellar medium with abundances comparable to those of the most stable isomer, or even when the stable isomer is not detected, highlights the importance of non-equilibrium…

We report the detection of the oxygen-bearing complex organic molecules propenal (C2H3CHO), vinyl alcohol (C2H3OH), methyl formate (HCOOCH3), and dimethyl ether (CH3OCH3) toward the cyanopolyyne peak of the starless core TMC-1. These…

Astrophysics of Galaxies · Physics 2021-05-05 M. Agundez , N. Marcelino , B. Tercero , C. Cabezas , P. de Vicente , J. Cernicharo

Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…

Astrophysics of Galaxies · Physics 2023-01-04 A. Taillard , V. WakelaM , P. Gratier , E. Dartois , M. Chabot , J. A. Noble , J. V. Keane , A. C. A. Boogert , D. Harsono

In previous warm-up chemical models of the low-mass star-forming region L1527, we investigated the evolution of carbon-chain unsaturated hydrocarbon species when the envelope temperature is slightly elevated to $T\approx 30$ K. These models…

Solar and Stellar Astrophysics · Physics 2015-06-03 George E. Hassel , Nanase Harada , Eric Herbst

The physical and chemical properties of cold and dense molecular clouds are key to understanding how stars form. Using the IRAM 30 m and NRO 45 m telescopes, we carried out a Multiwavelength line-Imaging survey of the 70 $\mu$m dark and…

We found that in regions of high mass star formation the CS emission correlates well with the dust continuum emission and is therefore a good tracer of the total mass while the N$_2$H$^+$ distribution is frequently very different. This is…

It is thought that dicyanopolyynes could be potentially abundant interstellar molecules, although their lack of dipole moment makes it impossible to detect them through radioastronomical techniques. Recently, the simplest member of this…

Astrophysics of Galaxies · Physics 2018-07-25 M. Agundez , N. Marcelino , J. Cernicharo

From observations, column density ratios or integrated intensity ratios between some species exhibit monotonic increase or decrease along with the evolution of high-mass star-forming regions (HMSFRs). Such ratios are defined as chemical…

Astrophysics of Galaxies · Physics 2025-02-27 Yao Wang , Fujun Du , Youxin Wang , Hongchi Wang , Jiangshui Zhang

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

We carried out survey observations of HC$_{3}$N and HC$_{5}$N in the 42$-$45 GHz band toward 17 high-mass starless cores (HMSCs) and 35 high-mass protostellar objects (HMPOs) with the Nobeyama 45 m radio telescope. We have detected…

Astrophysics of Galaxies · Physics 2018-02-28 Kotomi Taniguchi , Masao Saito , T. K. Sridharan , Tetsuhiro Minamidani

Molecular hydrogen (H2) is the main constituent of the gas in the planet-forming disks that surround many PMS stars. H2 can be incorporated in the atmosphere of the giant planets. HD has been detected in a few disks and can be considered…

Astrophysics of Galaxies · Physics 2018-12-18 W. F. Thi , S. Hocuk , I. Kamp , P. Woitke , Ch. Rab , S. Cazaux , P. Caselli

We aim to reveal the chemistry of carbon-chain molecules in high-mass star-forming regions from molecular level to chemical evolution, applying the methods established in low-mass star-forming regions. In this proceeding, we summarize the…

Astrophysics of Galaxies · Physics 2017-01-10 Kotomi Taniguchi , Masao Saito

We investigate the relative efficiencies of low-temperature chemical reactions in the Interstellar medium (ISM) with H$^-$ anion reacting in the gas phase with cyanopolyyne neutral molecules, leading to the formation of anionic C$_x$N$^-$…

Chemical Physics · Physics 2018-07-31 F. A. Gianturco , M. Satta , E. Yurtsever , R. Wester

We selected 90 massive star-forming clumps with strong N2H+, HCO+, HCN, and HNC emission from the Millimetre Astronomy Legacy Team 90 GHz survey. We obtained Herschel data for all 90 sources and NRAO VLA Sky Survey data for 51 of them. We…

Astrophysics of Galaxies · Physics 2019-07-25 Mingyue Li , Jianjun Zhou , Jarken Esimbek , Donghui Quan , Yuxin He , Qiang Li , Chunhua Zhu

We report the detection of the carbon-chain radical HC$_5$O for the first time in the interstellar medium toward the dark cloud TMC-1 using the 100 m Green Bank Telescope. We observe four hyperfine components of this radical in the $J =…

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