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We study the dependence of macroscopic polarization on composition and strain in wurtzite III-V nitride ternary alloys using ab initio density-functional techniques. The spontaneous polarization is characterized by a large bowing, strongly…

Materials Science · Physics 2009-11-07 Fabio Bernardini , Vincenzo Fiorentini

Topological polar textures in ferroelectrics have attracted significant interest for their potential for energy-efficient and high-density data storage and processing. Among these, polar merons and antimerons are predicted in strained and…

We report an ultrahigh pyroelectric response in van der Waals bonded layers of two-dimensional (2D) tellurium (Te) nanosheets (thickness, d = 4 to 5 nm) at periodic on-off temperature oscillations. For the first time a large pyroelectric…

Layered materials with non-centrosymmetric stacking order are attracting increasing interest due to the presence of ferroelectric polarization, which is dictated by weak interlayer hybridization of atomic orbitals. Here, we use density…

Mesoscale and Nanoscale Physics · Physics 2025-01-15 Xue Li , James G. McHugh , Vladimir I. Falko

Van der Waals (vdW) polytypes of broken inversion and mirror symmetries were recently shown to exhibit switchable electric polarization even at the ultimate two-layer thin limit. Their out-of-plane polarization was found to accumulate in a…

Solid solution BiFe1-xCoxO3 shows anti-ferromagnetic order and pyroelectric order, simultaneously. It has been known that BiFe1-xCoxO3 exhibits a structural phase transition between monoclinic and tetragonal phases as x increases. This…

Materials Science · Physics 2021-12-15 Hiroshi Katsumoto , Kunihiko Yamauchi , Tamio Oguchi

Many kinds of two-dimensional (2D) van der Waals (vdW) have been demonstrated to exhibit electromechanical coupling effects, which makes them promising candidates for next-generation devices, such as piezotronics and nanogenerators.…

Mesoscale and Nanoscale Physics · Physics 2023-11-13 Qiong Liu , S. S. Nanthakumar , Bin Li , Teresa Cheng , Florian Bittner , Chenxi Ma , Fei Ding , Lei Zheng , Bernhard Roth , Xiaoying Zhuang

We report a more than 10-fold enhancement of the piezoelectric coefficient $d_{33}$ of polycrystalline CH$_3$NH$_3$PbI$_3$ (MAPbI$_3$) films when interfacing them with ferroelectric PbZr$_{0.2}$Ti$_{0.8}$O$_3$ (PZT). Piezo-response force…

Materials Science · Physics 2018-06-12 Jingfeng Song , Zhiyong Xiao , Bo Chen , Spencer Prockish , Xuegang Chen , Jinsong Huang , Xia Hong

The free energy of antiferroelectric liquid crystal which takes into account polar order explicitly is presented. Steric, van der Waals, piezoelectric and flexoelectric interactions to the nearest layers and dipolar electrostatic…

Soft Condensed Matter · Physics 2009-11-07 Mojca Cepic , Bostjan Zeks

Van der Waals (vdW) layered materials have rather weaker interlayer bonding than the intra-layer bonding, therefore the exfoliation along the stacking direction enables the achievement of monolayer or few layers vdW materials with emerging…

Two-dimensional sliding ferroelectrics, with their unique stacking degrees of freedom, offer a different approach to manipulate polarization by interlayer sliding. Bending sliding ferroelectrics inevitably leads to interlayer sliding…

Materials Science · Physics 2024-08-02 Ri He , Hua Wang , Fenglin Deng , Yuxiang Gao , Binwen Zhang , Yubai Shi , Run-Wei Li , Zhicheng Zhong

In purely c-axis oriented PbZr$_{0.2}$Ti$_{0.8}$O$_3$ ferroelectric thin films, a lateral piezoresponse force microscopy signal is observed at the position of 180{\deg}domain walls, where the out-of-plane oriented polarization is reversed.…

Materials Science · Physics 2015-05-19 J. Guyonnet , H. Bea , P. Paruch

Van der Waals (vdW) assembly could efficiently modulate the symmetry of two-dimensional (2D) materials that ultimately governs their physical properties. Of particular interest is the ferroelectric polarization being introduced by proper…

Materials Science · Physics 2024-02-21 Ziyu Niu , Xiang-Long Yu , Dingfu Shao , Xixiang Jing , Defeng Hou , Xuhong Li , Jing Sun , Junqin Shi , Xiaoli Fan , Tengfei Cao

Piezoelectrics are materials that linearly deform in response to an applied electric field. As a fundamental prerequisite, piezoelectric material must possess a non centrosymmetric crystal structure. For more than a century, this remains…

Negative reflection and negative refraction are exotic phenomena that can be achieved by platforms such as double-negative metamaterial, hyperbolic metamaterial, and phase-discontinuity metasurface. Recently, natural biaxial van der Waals…

Optics · Physics 2022-07-27 Tan Zhang , Chunqi Zheng , Zhi Ning Chen , Cheng-Wei Qiu

Bismuth telluride have regained significant attention as a prototype of topological insulator. Thin films of high quality have been investigated as a basic platform for novel spintronic devices. Low mobility of bismuth and high desorption…

van der Waals stacking of two-dimensional (2D) materials offers a powerful platform for engineering material interfaces with tailored electronic and optical properties. While most van der Waals multilayers have featured inorganic…

Using high-throughput first-principles calculations to search for layered van der Waals materials with the largest piezoelectric stress coefficients, we discover NbOI2 to be the one among 2940 monolayers screened. The piezoelectric…

Due to their low surface mass density, two-dimensional materials with a strong piezoelectric response are interesting for nanoelectromechanical systems with high force sensitivity. Unlike graphene, the two sublattices in a monolayer of…

Mesoscale and Nanoscale Physics · Physics 2016-08-05 Matthias Droth , Guido Burkard , Vitor M. Pereira

The nonlinear Hall effect (NLHE) with time-reversal symmetry constitutes the appearance of a transverse voltage quadratic in the applied electric field. It is a second-order electronic transport phenomenon that induces frequency doubling…