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We explore long lived electronic coherences in molecules using shaped ultrafast laser pulses to launch and probe entangled nuclear-electronic wave packets. We find that under certain conditions, the electronic phase remains well defined…

Quantum Physics · Physics 2023-11-20 Brian Kaufman , Philipp Marquetand , Tamas Rozgonyi , Thomas Weinacht

Coherent optical control schemes exploit the coherence of laser pulses to change the phases of interfering dynamical pathways in order to manipulate dynamical processes. These active control methods are closely related to dynamical…

Other Condensed Matter · Physics 2015-05-18 Luis G. C. Rego , L. F. Santos , V. S. Batista

The high-order harmonic generation (HHG), if phase matched, opens a unique way to produce coherent ultrafast extreme-UV (XUV) or soft x-ray light sources. Here we describe a robust and tunable method for scaling and narrowing the bandwidth…

Optics · Physics 2017-10-03 L. Mashhadi , G. Shayeganrad

A setup for extreme-ultraviolet time-resolved photoelectron spectroscopy (XUV-TRPES) of liquids is described based on a gas-dynamic flat jet formed by a microfluidic chip device. In comparison to a cylindrical jet that has a typical…

Chemical Physics · Physics 2025-03-24 Masafumi Koga , Do Hyung Kang , Zachary N. Heim , Neal Haldar , Daniel M. Neumark

Tunable polarization over a wide spectral range is a required feature of light sources employed to investigate the properties of local symmetry in both condensed and low-density matter. Among new-generation sources, free-electron lasers…

Laser assisted photoemission by a chirped subfemtosecond extreme ultraviolet (XUV) pulse is considered within an exactly solvable quantum-mechanical model. Special emphasis is given to the energy dependence of photoexcitation cross-section.…

Atomic Physics · Physics 2015-05-13 E. E. Krasovskii , M. Bonitz

We present a new mechanism of attosecond extreme-ultraviolet (XUV) pulses generation from a relativistic laser-driven overdense plasma surfaces in the wavebreaking regime. Through particle-in-cell simulations and analysis, we demonstrate…

Plasma Physics · Physics 2016-08-18 Zi-Yu Chen , Mykyta Cherednychek , Alexander Pukhov

We combine multi-channel electronic structure theory with quantum optimal control to derive Raman pulse sequences that coherently populate a valence excited state. For a neon atom, Raman target populations of up to 13% are obtained.…

Quantum Physics · Physics 2015-07-23 Loren Greenman , Christiane P. Koch , K. Birgitta Whaley

High-brightness femtosecond-to-attosecond pulses are indispensable for probing electron dynamics on their fundamental temporal scales. X-ray free-electron lasers (XFELs) at high repetition rates will facilitate high-statistics measurements…

Accelerator Physics · Physics 2026-05-01 Junhao Liu , Zhen Wang , Lanpeng Ni , Yujie Lu , Chao Feng , Zhentang Zhao

Ionization with ultrashort pulses in the extreme ultraviolet (XUV) regime can be used to prepare an ion in a superposition of spin--orbit substates. In this work, we study the coherence properties of such a superposition, created by…

Development of the optical frequency comb has revolutionised metrology and precision spectroscopy due to its ability to provide a precise and direct link between microwave and optical frequencies. A novel application of frequency comb…

Controlling nonequilibrium responses in optically driven quantum materials is essential for advancing applications in energy conversion, ultrafast electronics, and quantum computation. Nonlinear optical spectroscopy serves as a powerful…

Ultrafast laser excitation can create coherent superpositions of electronic states in molecules and trigger ultrafast flow of electron density on few- to sub-femtosecond time scales. While recent attosecond experiments have addressed…

Chemical Physics · Physics 2020-11-18 Yuki Kobayashi , Daniel M. Neumark , Stephen R. Leone

Semiconductor quantum dot molecules are considered as promising candidates for quantum technological applications due to their wide tunability of optical properties and coverage of different energy scales associated with charge and spin…

Highly intense, sub-picosecond terahertz (THz) pulses can be used to induce ultrafast temperature jumps (T-jumps) in liquid water. A supercritical state of gas-like water with liquid density is established, and the accompanying structural…

Chemical Physics · Physics 2019-01-24 Caroline Arnold , Ludger Inhester , Sergio Carbajo , Ralph Welsch , Robin Santra

Non-collinear four-wave mixing (FWM) techniques at near-infrared (NIR), visible, and ultraviolet frequencies have been widely used to map vibrational and electronic couplings, typically in complex molecules. However, correlations between…

Nonstationary molecular states which contain electronic coherences can be impulsively created and manipulated by using recently-developed ultrashort optical and X-ray pulses via photoexcitation, photoionization and Auger processes. We…

Chemical Physics · Physics 2015-09-02 Konstantin E. Dorfman , Kochise Bennett , Shaul Mukamel

We review the current state of tabletop extreme ultraviolet (XUV) sources based on high harmonic generation (HHG) in femtosecond enhancement cavities (fsEC). Recent developments have enabled generation of high photon flux (1014 photons/sec)…

Optics · Physics 2015-06-05 Arthur K Mills , TJ Hammond , Matthew HC Lam , David J Jones

We theoretically study how time- and angle-resolved photoemission spectroscopy can be applied for imaging coherent electron dynamics in molecules. We consider a process in which a pump pulse triggers coherent electronic dynamics in a…

Optics · Physics 2018-12-11 Daria Popova-Gorelova , Jochen Küpper , Robin Santra

We present a novel time- and phase-resolved, background-free scheme to study the extreme ultraviolet dipole emission of a bound electronic wavepacket, without the use of any extreme ultraviolet exciting pulse. Using multiphoton transitions,…

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