Related papers: Intershell correlations in endohedral atoms
We demonstrate that in the frame of the random phase approximation with the exchange, which preserves the validity of the precise well known dipole sum rule, the partial contributions for given subshells strongly deviates from the number of…
It is demonstrated that outer and inner electron shells, including that formed by collectivized electrons of the fullerene C60, affects dramatically the cross section of the subvalent ns-subshells of the noble gas endohedral atoms A@C60.…
In this Letter, we investigate the time delay of photoelectrons by fullerenes shell in endohedrals. We present general formulas in the frame of the random phase approximation with exchange (RPAE) applied to endohedrals A@CN that consist of…
We have studied the energy dependence of several first scattering phases with multi-atomic object. As concrete examples representing the general trends endohedrals Neon inside C60 and Argon inside C60 are considered. It appeared that the…
In this Letter, we investigate the non-dipole effects in time delay of photoelectrons emitted by multi-electron atoms, negative ions, and respective endohedrals. We present the necessary general formulas in the frame of the random phase…
We concentrate here on photon absorption as well as electron and positron scattering upon endohedrals that consist of a fullerenes shell and an inner atom A. The aim is to understand the effect of fullerene electron shell in formation of…
We demonstrate strong interference patterns in the photoionization cross-section of the subvalent subshells of noble gas (NG) endohedral atoms NG@F. This interference is a result of common action of three factors: the effect of neighboring…
We demonstrate for the first time that the effect of fullerene shell upon photoionization of the "caged" atom in an endohedral can result in formation of Giant Endohedral Resonances or GER. This is illustrated by the concrete case of Xe@C60…
We discuss the complicated resonance structure of the endohedral atom photoionization cross section. Very strong enhancement and interference patterns in the photoionization cross-section of the valent and subvalent subshells of noble gas…
We calculate the photoionization cross-section of a molecular endohedral. We limit ourselves to two-atomic molecules. The consideration is much more complex than for atomic endohedrals because the system even for almost spherical fullerenes…
We demonstrate rather interesting manifestations of co-existence of resonance features in characteristics of the photoionization of 3d-electrons in Xe, Cs and Ba endohedral atoms. It is shown that for all of the considered atoms the…
It is demonstrated that the fullerene shell affects dramatically the radiative and Auger vacancy decay of an endohedral atom A@C60. The collectivized electrons of the C60 shell add new possibilities for radiative and non-radiative decays…
The interactions between atoms and molecules may be described by a potential energy function of the nuclear coordinates. Non-bonded interactions are dominated by repulsive forces at short range and attractive dispersion forces at long…
The stability of Ne@C$_{60}$ and He@C$_{60}$ is discussed in the context of a spherical model where the carbon atoms are smeared out into a uniform shell. The electronic properties of the sixty $\pi$ electrons together with those of the…
Photoionization of a Xe atom confined inside C$_{60}$ has been studied using the random phase approximation with exchange (RPAE) method. The C$_{60}$ fullerene has been descr ibed by an attractive short range spherical well with potential…
We investigate positron scattering upon endohedrals and compare it with electron-endohedral scattering. We show that the polarization of the fullerene shell considerably alters the polarization potential of an atom, stuffed inside a…
It is demonstrated by the example of the Xe atom stuffed inside the C60 fullerene, that the so-called confinement resonances in 4d subshell strongly affect the photoionization cross-section of outer 5p and subvalent 5s electrons near 4d…
The random-phase approximation with exchange (RPAE) is used with a $B$-spline basis to compute dynamic dipole polarizabilities of noble-gas atoms and several other closed-shell atoms (Be, Mg, Ca, Zn, Sr, Cd, and Ba). From these, values of…
We present here the results of calculations of photoelectrons' angular anisotropy and spin-polarization parameters for a number of semi-filled shell atoms. We consider ionization of outer or in some cases next to the outer electrons in a…
We have calculated photoionization cross-section of endohedral atoms A@CN. We took into account the polarizability of the fullerene electron shell CN that modifies the incoming photon beam and the one-electron wave functions of the caged…