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The convergence property of a stochastic algorithm for the self-consistent field (SCF) calculations of electron structures is studied. The algorithm is formulated by rewriting the electron charges as a trace/diagonal of a matrix function,…

Numerical Analysis · Mathematics 2023-04-20 Taehee Ko , Xiantao Li

In [Phys. Rev. Lett. 128, 013001 (2022)] a novel ground state method was proposed. It has been suggested that this $i$-DMFT would be a method within one-particle reduced density matrix functional theory (DMFT), capable of describing…

Quantum Physics · Physics 2022-02-14 Lexin Ding , Julia Liebert , Christian Schilling

A quantum-field approach to studying the Bose systems at finite temperatures and in states with spontaneously broken symmetry, in particular in a superfluid state, is proposed. A generalized model of a self-consistent field (SCF) for…

Statistical Mechanics · Physics 2013-06-11 Yu. M. Poluektov

Conformal field theories (CFTs) with cubic global symmetry in 3D are relevant in a variety of condensed matter systems and have been studied extensively with the use of perturbative methods like the $\varepsilon$ expansion. In an earlier…

High Energy Physics - Theory · Physics 2020-06-10 Stefanos R. Kousvos , Andreas Stergiou

We provide a pedagogical review of the main ideas and results in non-equilibrium conformal field theory and connected subjects. These concern the understanding of quantum transport and its statistics at and near critical points. Starting…

Statistical Mechanics · Physics 2016-12-20 Denis Bernard , Benjamin Doyon

A rich variety of amorphous solids are found in nature and technology, including ones formed via the vulcanization of long, flexible molecules. A special class -- those featuring a wide gap between the long timescales over which constraints…

Soft Condensed Matter · Physics 2025-05-22 Paul M. Goldbart

A particle method for reproducing the phase space of collisionless stellar systems is described. The key idea originates in Liouville's theorem which states that the distribution function (DF) at time t can be derived from tracing necessary…

Astrophysics · Physics 2009-10-30 Shunsuke Hozumi

We propose a new self-consistent field (SCF) algorithm based on an iterative, partially stochastic \textit{``Divide \& Conquer''}-type approach. This new SCF algorithm is a simple variant of the usual SCF procedure and can be easily…

Chemical Physics · Physics 2021-08-04 Pierre-François Loos , Jean-Louis Rivail , Xavier Assfeld

Topological defects play a fundamental role in the investigation of symmetries in quantum field theories. For conformal field theories in two space-time dimensions, it is possible to construct these defects using lattice models allowing…

High Energy Physics - Theory · Physics 2026-04-30 Madhav Sinha , Thiago Silva Tavares , Hubert Saleur , Ananda Roy

The self-consistent field theory (SCFT) is a powerful framework for the study of the phase behavior and structural properties of many-body systems. In particular, polymeric SCFT has been successfully applied to inhomogeneous polymeric…

Soft Condensed Matter · Physics 2019-01-31 An-Chang Shi

We present a lattice formulation of a dynamic self-consistent field (DSCF) theory that is capable of resolving interfacial structure, dynamics and rheology in inhomogeneous, compressible melts and blends of unentangled homopolymer chains.…

Soft Condensed Matter · Physics 2009-11-10 Maja Mihajlovic , Tak Shing Lo , Yitzhak Shnidman

Three-dimensional conformal field theories (CFTs) of deconfined gauge fields coupled to gapless flavors of fermionic and bosonic matter describe quantum critical points of condensed matter systems in two spatial dimensions. An important…

High Energy Physics - Theory · Physics 2012-05-15 Igor R. Klebanov , Silviu S. Pufu , Subir Sachdev , Benjamin R. Safdi

We present the implementation of a quadratically convergent Self-consistent field (QCSCF) algorithm based on an adaptive trust-radius optimization scheme for restricted open-shell Hartree-Fock (ROHF), restricted Hartree-Fock (RHF), and…

Chemical Physics · Physics 2022-01-12 Tommaso Nottoli , Jürgen Gauss , Filippo Lipparini

A relativistic version of the coupled-cluster single-double (CCSD) method is developed for atoms with a single valence electron. In earlier work, a linearized version of the CCSD method (with extensions to include a dominant class of triple…

Atomic Physics · Physics 2009-11-13 Rupsi Pal , M. S. Safronova , W. R. Johnson , Andrei Derevianko , Sergey G. Porsev

Multireference systems are usually challenging to investigate using ab initio methods as they require an accurate description of static electron correlation. The urgency of developing similar approaches is even more pressing when molecules…

Chemical Physics · Physics 2025-06-11 Riccardo Alessandro , Matteo Castagnola , Henrik Koch , Enrico Ronca

We present an implementation of a time-dependent multiconfiguration self-consistent-field (TD-MCSCF) method [R. Anzaki et al., Phys. Chem. Chem. Phys. 19, 22008 (2017)] with the full configuration interaction expansion for coupled…

Atomic Physics · Physics 2021-10-08 Yang Li , Takeshi Sato , Kenichi L. Ishikawa

This is a set of introductory lecture notes on conformal field theory. Unlike most existing reviews on the subject, CFT is presented here from the perspective of a unitary quantum field theory in Minkowski space-time. It begins with a…

High Energy Physics - Theory · Physics 2023-05-04 Marc Gillioz

A multiscale model based on the coupling of the multiconfigurational self-consistent field (MCSCF) method and the classical atomistic polarizable Fluctuating Charges (FQ) force field is presented. The resulting MCSCF/FQ approach is…

A sharp stability analysis of atomistic-to-continuum coupling methods is essential for evaluating their capabilities for predicting the formation and motion of lattice defects. We formulate a simple one-dimensional model problem and give a…

Numerical Analysis · Mathematics 2010-07-19 Matthew Dobson , Mitchell Luskin , Christoph Ortner

We introduce a method for the estimation of uncertainties in density-functional-theory (DFT) calculations for atomistic systems. The method is based on the construction of an uncertainty-aware functional distribution (UAFD) in a space…

Materials Science · Physics 2025-07-14 Teitur Hansen , Jens Jørgen Mortensen , Thomas Bligaard , Karsten Wedel Jacobsen